Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating

In this study, a series of UV-curable anticorrosive PUA coatings embedded with varying concentrations of inorganic ZnO fillers have been successfully prepared from jatropha-based polyol. The electrochemical impedance spectroscopy (EIS) and Tafel polarisation analysis revealed that increasing fillers...

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Main Authors: Ariffin, Muhammad Mirza, Aung, Min Min, Abdullah, Luqman Chuah, Salleh, Mek Zah
Format: Article
Language:English
Published: Elsevier 2020
Online Access:http://psasir.upm.edu.my/id/eprint/87949/
http://psasir.upm.edu.my/id/eprint/87949/1/ABSTRACT.pdf
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author Ariffin, Muhammad Mirza
Aung, Min Min
Abdullah, Luqman Chuah
Salleh, Mek Zah
author_facet Ariffin, Muhammad Mirza
Aung, Min Min
Abdullah, Luqman Chuah
Salleh, Mek Zah
author_sort Ariffin, Muhammad Mirza
building UPM Institutional Repository
collection Online Access
description In this study, a series of UV-curable anticorrosive PUA coatings embedded with varying concentrations of inorganic ZnO fillers have been successfully prepared from jatropha-based polyol. The electrochemical impedance spectroscopy (EIS) and Tafel polarisation analysis revealed that increasing fillers composition lead to the improvement of the anticorrosive property of the hybrid coatings. Meanwhile, the salt spray test results were found to correlate with the EIS of Cc (F cm−2) was 2.71 × 10−9, Bode plot - 106 Ω cm2 and Tafel polarisation results 7.56 × 10−6 MPY at 3 wt% of ZnO. Physical properties of 3 wt% loading of ZnO fillers in hardness test obtained 6H which was strongly attributed to the low interfacial interaction and poor dispersion of the fillers within the polymer matrix.
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spelling upm-879492022-05-24T08:06:13Z http://psasir.upm.edu.my/id/eprint/87949/ Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating Ariffin, Muhammad Mirza Aung, Min Min Abdullah, Luqman Chuah Salleh, Mek Zah In this study, a series of UV-curable anticorrosive PUA coatings embedded with varying concentrations of inorganic ZnO fillers have been successfully prepared from jatropha-based polyol. The electrochemical impedance spectroscopy (EIS) and Tafel polarisation analysis revealed that increasing fillers composition lead to the improvement of the anticorrosive property of the hybrid coatings. Meanwhile, the salt spray test results were found to correlate with the EIS of Cc (F cm−2) was 2.71 × 10−9, Bode plot - 106 Ω cm2 and Tafel polarisation results 7.56 × 10−6 MPY at 3 wt% of ZnO. Physical properties of 3 wt% loading of ZnO fillers in hardness test obtained 6H which was strongly attributed to the low interfacial interaction and poor dispersion of the fillers within the polymer matrix. Elsevier 2020 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/87949/1/ABSTRACT.pdf Ariffin, Muhammad Mirza and Aung, Min Min and Abdullah, Luqman Chuah and Salleh, Mek Zah (2020) Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating. Polymer Testing, 87. art. no. 106526. pp. 1-9. ISSN 0142-9418 https://www.sciencedirect.com/science/article/pii/S0142941819320598 10.1016/j.polymertesting.2020.106526
spellingShingle Ariffin, Muhammad Mirza
Aung, Min Min
Abdullah, Luqman Chuah
Salleh, Mek Zah
Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating
title Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating
title_full Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating
title_fullStr Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating
title_full_unstemmed Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating
title_short Assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating
title_sort assessment of corrosion protection and performance of bio-based polyurethane acrylate incorporated with nano zinc oxide coating
url http://psasir.upm.edu.my/id/eprint/87949/
http://psasir.upm.edu.my/id/eprint/87949/
http://psasir.upm.edu.my/id/eprint/87949/
http://psasir.upm.edu.my/id/eprint/87949/1/ABSTRACT.pdf