Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs
Deoxygenation processes that exploit milder reaction conditions under H2-free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (Ni–...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Royal Society of Chemistry
2020
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| Online Access: | http://psasir.upm.edu.my/id/eprint/87316/ http://psasir.upm.edu.my/id/eprint/87316/1/Production%20of%20green%20diesel%20from%20catalytic.pdf |
| _version_ | 1848860414465540096 |
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| author | Nasharuddin, Nurul Aliana Mijan, Nurul Asikin Alsultan, Abdulkareem Ghassan Saiman, Mohd Izham Alharthi, Fahad A. Ali Alghamdi, Abdulaziz Yap, Taufiq Yun Hin |
| author_facet | Nasharuddin, Nurul Aliana Mijan, Nurul Asikin Alsultan, Abdulkareem Ghassan Saiman, Mohd Izham Alharthi, Fahad A. Ali Alghamdi, Abdulaziz Yap, Taufiq Yun Hin |
| author_sort | Nasharuddin, Nurul Aliana |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Deoxygenation processes that exploit milder reaction conditions under H2-free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (Ni–Mg, Ni–Mn, Ni–Cu, Ni–Ce) supported on multi-walled carbon nanotubes (MWCNTs). The presence of Mg and Mn with Ni afforded greater deoxygenation activity, with hydrocarbon yields of >75% and n-(C15 + C17) selectivity of >81%, indicating that decarboxylation/decarbonylation (deCOx) of CFO is favoured by the existence of high amount of lower strength strong acidic sites along with noticeable strongly basic sites. Based on a series of studies of different Mg and Mn dosages (5–20 wt%), the oxygen free-rich diesel-range hydrocarbons produced efficiently by Ni10–Mg15/MWCNT and Ni10–Mn5/MWCNT catalysts yielded >84% of hydrocarbons, with n-(C15 + C17) selectivity of >85%. The heating value of the green diesel obtained complied with the ultra-low sulphur diesel standard. |
| first_indexed | 2025-11-15T12:44:51Z |
| format | Article |
| id | upm-87316 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T12:44:51Z |
| publishDate | 2020 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-873162022-09-05T04:06:33Z http://psasir.upm.edu.my/id/eprint/87316/ Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs Nasharuddin, Nurul Aliana Mijan, Nurul Asikin Alsultan, Abdulkareem Ghassan Saiman, Mohd Izham Alharthi, Fahad A. Ali Alghamdi, Abdulaziz Yap, Taufiq Yun Hin Deoxygenation processes that exploit milder reaction conditions under H2-free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (Ni–Mg, Ni–Mn, Ni–Cu, Ni–Ce) supported on multi-walled carbon nanotubes (MWCNTs). The presence of Mg and Mn with Ni afforded greater deoxygenation activity, with hydrocarbon yields of >75% and n-(C15 + C17) selectivity of >81%, indicating that decarboxylation/decarbonylation (deCOx) of CFO is favoured by the existence of high amount of lower strength strong acidic sites along with noticeable strongly basic sites. Based on a series of studies of different Mg and Mn dosages (5–20 wt%), the oxygen free-rich diesel-range hydrocarbons produced efficiently by Ni10–Mg15/MWCNT and Ni10–Mn5/MWCNT catalysts yielded >84% of hydrocarbons, with n-(C15 + C17) selectivity of >85%. The heating value of the green diesel obtained complied with the ultra-low sulphur diesel standard. Royal Society of Chemistry 2020-01 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/87316/1/Production%20of%20green%20diesel%20from%20catalytic.pdf Nasharuddin, Nurul Aliana and Mijan, Nurul Asikin and Alsultan, Abdulkareem Ghassan and Saiman, Mohd Izham and Alharthi, Fahad A. and Ali Alghamdi, Abdulaziz and Yap, Taufiq Yun Hin (2020) Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs. RSC Advances, 10 (2). 626 - 642. ISSN 2046-2069 https://pubs.rsc.org/en/journals/journalissues/ra#!issueid=ra010002&type=current&issnonline=2046-2069 10.1039/C9RA08409F |
| spellingShingle | Nasharuddin, Nurul Aliana Mijan, Nurul Asikin Alsultan, Abdulkareem Ghassan Saiman, Mohd Izham Alharthi, Fahad A. Ali Alghamdi, Abdulaziz Yap, Taufiq Yun Hin Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs |
| title | Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs |
| title_full | Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs |
| title_fullStr | Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs |
| title_full_unstemmed | Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs |
| title_short | Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs |
| title_sort | production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported mwcnts |
| url | http://psasir.upm.edu.my/id/eprint/87316/ http://psasir.upm.edu.my/id/eprint/87316/ http://psasir.upm.edu.my/id/eprint/87316/ http://psasir.upm.edu.my/id/eprint/87316/1/Production%20of%20green%20diesel%20from%20catalytic.pdf |