Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system
A new transparent zinc silicate glass-ceramic was derived from the 55ZnO–5B2O3–40SLS glass system via a controlled heat-treatment method. The precursor glass sample was placed through the heat-treatment process at different temperatures to study the progress in phase transformation, optical performa...
| Main Authors: | , , , , , , |
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| Format: | Article |
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Multidisciplinary Digital Publishing Institute
2020
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| Online Access: | http://psasir.upm.edu.my/id/eprint/87144/ |
| _version_ | 1848860371577733120 |
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| author | Mohd Shofri, Muhammad Faris Syazwan Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Fen, Yap Wing Yaakob, Yazid Jaafar, Suhail Huzaifa Wahab, Siti Aisyah Abdul |
| author_facet | Mohd Shofri, Muhammad Faris Syazwan Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Fen, Yap Wing Yaakob, Yazid Jaafar, Suhail Huzaifa Wahab, Siti Aisyah Abdul |
| author_sort | Mohd Shofri, Muhammad Faris Syazwan |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | A new transparent zinc silicate glass-ceramic was derived from the 55ZnO–5B2O3–40SLS glass system via a controlled heat-treatment method. The precursor glass sample was placed through the heat-treatment process at different temperatures to study the progress in phase transformation, optical performance and emission intensity of the zinc silicate glass-ceramics. For this project, material characterization was measured through several tests using densimeter and linear shrinkage measurement, X-ray diffraction (XRD), Fourier transform infrared reflection (FTIR), ultraviolet–visible (UV–Vis) and photoluminescence (PL) spectroscopy. The density and linear shrinkage measurements show that the density of the particular glass-ceramic samples increases with the progression of heating temperature. The XRD analysis displays the result in which the zinc silicate crystal starts to grow after the sample was treated at 700 °C. In addition, the FTIR spectra indicated that the crystallization of the zinc silicate phase occurred with the appearance of SiO4, ZnO4 and Si-O-Zn bands. UV–visible exhibited the small changes when the value for the optical band gap decreased from 3.867 to 3.423 eV, influenced by the temperature applied to the sample. Furthermore, the PL spectroscopy showed an enhancement of broad green emission at 534 nm upon the increased heat-treatment temperature. Thus, it can be concluded there is the progression of crystal growth as the heat-treatment temperature increased; three emission peaks appeared at 529, 570 and 682 nm for the green, yellow and red emissions, respectively. |
| first_indexed | 2025-11-15T12:44:10Z |
| format | Article |
| id | upm-87144 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T12:44:10Z |
| publishDate | 2020 |
| publisher | Multidisciplinary Digital Publishing Institute |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-871442024-05-17T03:52:25Z http://psasir.upm.edu.my/id/eprint/87144/ Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system Mohd Shofri, Muhammad Faris Syazwan Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Fen, Yap Wing Yaakob, Yazid Jaafar, Suhail Huzaifa Wahab, Siti Aisyah Abdul A new transparent zinc silicate glass-ceramic was derived from the 55ZnO–5B2O3–40SLS glass system via a controlled heat-treatment method. The precursor glass sample was placed through the heat-treatment process at different temperatures to study the progress in phase transformation, optical performance and emission intensity of the zinc silicate glass-ceramics. For this project, material characterization was measured through several tests using densimeter and linear shrinkage measurement, X-ray diffraction (XRD), Fourier transform infrared reflection (FTIR), ultraviolet–visible (UV–Vis) and photoluminescence (PL) spectroscopy. The density and linear shrinkage measurements show that the density of the particular glass-ceramic samples increases with the progression of heating temperature. The XRD analysis displays the result in which the zinc silicate crystal starts to grow after the sample was treated at 700 °C. In addition, the FTIR spectra indicated that the crystallization of the zinc silicate phase occurred with the appearance of SiO4, ZnO4 and Si-O-Zn bands. UV–visible exhibited the small changes when the value for the optical band gap decreased from 3.867 to 3.423 eV, influenced by the temperature applied to the sample. Furthermore, the PL spectroscopy showed an enhancement of broad green emission at 534 nm upon the increased heat-treatment temperature. Thus, it can be concluded there is the progression of crystal growth as the heat-treatment temperature increased; three emission peaks appeared at 529, 570 and 682 nm for the green, yellow and red emissions, respectively. Multidisciplinary Digital Publishing Institute 2020 Article PeerReviewed Mohd Shofri, Muhammad Faris Syazwan and Mohd Zaid, Mohd Hafiz and Matori, Khamirul Amin and Fen, Yap Wing and Yaakob, Yazid and Jaafar, Suhail Huzaifa and Wahab, Siti Aisyah Abdul (2020) Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system. Applied Sciences, 10 (14). art. no. 4940. pp. 1-12. ISSN 2076-3417 https://www.mdpi.com/2076-3417/10/14/4940 10.3390/app10144940 |
| spellingShingle | Mohd Shofri, Muhammad Faris Syazwan Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Fen, Yap Wing Yaakob, Yazid Jaafar, Suhail Huzaifa Wahab, Siti Aisyah Abdul Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system |
| title | Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system |
| title_full | Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system |
| title_fullStr | Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system |
| title_full_unstemmed | Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system |
| title_short | Phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the ZnO–B2O3–SLS glass system |
| title_sort | phase transformation, optical and emission performance of zinc silicate glass-ceramics phosphor derived from the zno–b2o3–sls glass system |
| url | http://psasir.upm.edu.my/id/eprint/87144/ http://psasir.upm.edu.my/id/eprint/87144/ http://psasir.upm.edu.my/id/eprint/87144/ |