Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization

This study focused on developing a hydrophilic hybrid polyvinylidene fluoride (PVDF)-polyethylene glycol (PEG) hollow membrane by incorporating Nano-magnesium oxide (NMO) as a potent antifouling mediator. The Nano-hybrid hollow fibers with varied loading of NMO (0 g; 0.25 g; 0.50 g; 0.75 g and 1.25...

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Main Authors: Abdulsalam, Mohammed, Che Man, Hasfalina, Goh, Pei Sean, Yunos, Khairul Faezah, Zainal Abidin, Zurina, Isma M.I., Aida, Ismail, Ahmad Fauzi
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2020
Online Access:http://psasir.upm.edu.my/id/eprint/87125/
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author Abdulsalam, Mohammed
Che Man, Hasfalina
Goh, Pei Sean
Yunos, Khairul Faezah
Zainal Abidin, Zurina
Isma M.I., Aida
Ismail, Ahmad Fauzi
author_facet Abdulsalam, Mohammed
Che Man, Hasfalina
Goh, Pei Sean
Yunos, Khairul Faezah
Zainal Abidin, Zurina
Isma M.I., Aida
Ismail, Ahmad Fauzi
author_sort Abdulsalam, Mohammed
building UPM Institutional Repository
collection Online Access
description This study focused on developing a hydrophilic hybrid polyvinylidene fluoride (PVDF)-polyethylene glycol (PEG) hollow membrane by incorporating Nano-magnesium oxide (NMO) as a potent antifouling mediator. The Nano-hybrid hollow fibers with varied loading of NMO (0 g; 0.25 g; 0.50 g; 0.75 g and 1.25 g) were spun through phase inversion technique. The resultants Nano-hybrid fibers were characterized and compared based on SEM, EDX, contact angle, surface zeta-potential, permeability flux, fouling resistance and color rejection from palm oil mill effluent (POME). Noticeably, the permeability flux, fouling resistance and color rejection improved with the increase in NMO loading. PVDF-PEG with 0.50 g-NMO loading displayed an outstanding performance with 198.35 L/m2·h, 61.33 L/m2·h and 74.65% of water flux, POME flux and color rejection from POME, respectively. More so, a remarkable fouling resistance were obtained such that the flux recovery, reversible fouling percentage and irreversible fouling percentage remains relatively steady at 90.98%, 61.39% and 7.68%, respectively, even after 3 cycles of continuous filtrations for a total period of 9 h. However, at excess loading of 0.75 and 1.25 g-NMO, deterioration in the flux and fouling resistance was observed. This was due to the agglomeration of nanoparticles within the matrix structure at the excessive loading.
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institution Universiti Putra Malaysia
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publishDate 2020
publisher Multidisciplinary Digital Publishing Institute
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spelling upm-871252024-05-17T03:09:56Z http://psasir.upm.edu.my/id/eprint/87125/ Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization Abdulsalam, Mohammed Che Man, Hasfalina Goh, Pei Sean Yunos, Khairul Faezah Zainal Abidin, Zurina Isma M.I., Aida Ismail, Ahmad Fauzi This study focused on developing a hydrophilic hybrid polyvinylidene fluoride (PVDF)-polyethylene glycol (PEG) hollow membrane by incorporating Nano-magnesium oxide (NMO) as a potent antifouling mediator. The Nano-hybrid hollow fibers with varied loading of NMO (0 g; 0.25 g; 0.50 g; 0.75 g and 1.25 g) were spun through phase inversion technique. The resultants Nano-hybrid fibers were characterized and compared based on SEM, EDX, contact angle, surface zeta-potential, permeability flux, fouling resistance and color rejection from palm oil mill effluent (POME). Noticeably, the permeability flux, fouling resistance and color rejection improved with the increase in NMO loading. PVDF-PEG with 0.50 g-NMO loading displayed an outstanding performance with 198.35 L/m2·h, 61.33 L/m2·h and 74.65% of water flux, POME flux and color rejection from POME, respectively. More so, a remarkable fouling resistance were obtained such that the flux recovery, reversible fouling percentage and irreversible fouling percentage remains relatively steady at 90.98%, 61.39% and 7.68%, respectively, even after 3 cycles of continuous filtrations for a total period of 9 h. However, at excess loading of 0.75 and 1.25 g-NMO, deterioration in the flux and fouling resistance was observed. This was due to the agglomeration of nanoparticles within the matrix structure at the excessive loading. Multidisciplinary Digital Publishing Institute 2020 Article PeerReviewed Abdulsalam, Mohammed and Che Man, Hasfalina and Goh, Pei Sean and Yunos, Khairul Faezah and Zainal Abidin, Zurina and Isma M.I., Aida and Ismail, Ahmad Fauzi (2020) Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization. Polymers, 12 (3). art. no. 549. pp. 1-22. ISSN 2073-4360 https://www.mdpi.com/2073-4360/12/3/549 10.3390/polym12030549
spellingShingle Abdulsalam, Mohammed
Che Man, Hasfalina
Goh, Pei Sean
Yunos, Khairul Faezah
Zainal Abidin, Zurina
Isma M.I., Aida
Ismail, Ahmad Fauzi
Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization
title Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization
title_full Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization
title_fullStr Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization
title_full_unstemmed Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization
title_short Permeability and antifouling augmentation of a hybrid PVDF-PEG membrane using Nano-magnesium oxide as a powerful mediator for POME decolorization
title_sort permeability and antifouling augmentation of a hybrid pvdf-peg membrane using nano-magnesium oxide as a powerful mediator for pome decolorization
url http://psasir.upm.edu.my/id/eprint/87125/
http://psasir.upm.edu.my/id/eprint/87125/
http://psasir.upm.edu.my/id/eprint/87125/