One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives

In the current study, a green, one-pot, three-component reaction was performed to prepare novel N-substituted 5-amino-1,3,4-thiadiazole derivatives. The thiadiazoles were obtained from the reaction of a ketene S,S-acetal of Meldrum’s acid or barbituric acid (as key intermediates), hydrazine, and iso...

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Main Authors: Habibi, Azizollah, Khosravi, Sahar, Seyyed, Mohammad Shahcheragh, Abdul Rahman, Mohd Basyaruddin
Format: Article
Language:English
Published: Bentham Science 2020
Online Access:http://psasir.upm.edu.my/id/eprint/86982/
http://psasir.upm.edu.my/id/eprint/86982/1/One-pot%20green%20synthesis.pdf
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author Habibi, Azizollah
Khosravi, Sahar
Seyyed, Mohammad Shahcheragh
Abdul Rahman, Mohd Basyaruddin
author_facet Habibi, Azizollah
Khosravi, Sahar
Seyyed, Mohammad Shahcheragh
Abdul Rahman, Mohd Basyaruddin
author_sort Habibi, Azizollah
building UPM Institutional Repository
collection Online Access
description In the current study, a green, one-pot, three-component reaction was performed to prepare novel N-substituted 5-amino-1,3,4-thiadiazole derivatives. The thiadiazoles were obtained from the reaction of a ketene S,S-acetal of Meldrum’s acid or barbituric acid (as key intermediates), hydrazine, and isothiocyanate. The key advantages of this manner include environmentally safe reactions, high yield, appropriate reaction time, simple reaction conditions, and use of a green reaction solvent. The structure of thiadiazoles was determined based on the spectroscopic data.
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institution Universiti Putra Malaysia
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publishDate 2020
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spelling upm-869822022-01-10T08:12:56Z http://psasir.upm.edu.my/id/eprint/86982/ One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives Habibi, Azizollah Khosravi, Sahar Seyyed, Mohammad Shahcheragh Abdul Rahman, Mohd Basyaruddin In the current study, a green, one-pot, three-component reaction was performed to prepare novel N-substituted 5-amino-1,3,4-thiadiazole derivatives. The thiadiazoles were obtained from the reaction of a ketene S,S-acetal of Meldrum’s acid or barbituric acid (as key intermediates), hydrazine, and isothiocyanate. The key advantages of this manner include environmentally safe reactions, high yield, appropriate reaction time, simple reaction conditions, and use of a green reaction solvent. The structure of thiadiazoles was determined based on the spectroscopic data. Bentham Science 2020-09-25 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/86982/1/One-pot%20green%20synthesis.pdf Habibi, Azizollah and Khosravi, Sahar and Seyyed, Mohammad Shahcheragh and Abdul Rahman, Mohd Basyaruddin (2020) One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives. Letters in Organic Chemistry, 17 (7). 517 - 522. ISSN 1570-1786; ESSN: 1875-6255 https://www.eurekaselect.com/175139/article 10.2174/1570178616666190926105533
spellingShingle Habibi, Azizollah
Khosravi, Sahar
Seyyed, Mohammad Shahcheragh
Abdul Rahman, Mohd Basyaruddin
One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives
title One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives
title_full One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives
title_fullStr One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives
title_full_unstemmed One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives
title_short One-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives
title_sort one-pot green synthesis of some novel n-substituted 5-amino-1,3,4-thiadiazole derivatives
url http://psasir.upm.edu.my/id/eprint/86982/
http://psasir.upm.edu.my/id/eprint/86982/
http://psasir.upm.edu.my/id/eprint/86982/
http://psasir.upm.edu.my/id/eprint/86982/1/One-pot%20green%20synthesis.pdf