Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes
Activated sericite was used as a solid matrix for control over the size of iron oxide nanoparticles (NPs). The activation of sericite was achieved by undergoing thermal, acid and salt treatments. Different weight ratios (w.r.) of iron oxide to activated sericite were prepared by varying the amount o...
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| Format: | Article |
| Language: | English |
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Elsevier
2020
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| Online Access: | http://psasir.upm.edu.my/id/eprint/86599/ http://psasir.upm.edu.my/id/eprint/86599/1/Low%20cost%20and%20efficient%20synthesis%20.pdf |
| _version_ | 1848860241610932224 |
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| author | Abdullah, Nurul Hidayah Shameli, Kamyar Abdullah, Ezzat Chan Abdullah, Luqman Chuah |
| author_facet | Abdullah, Nurul Hidayah Shameli, Kamyar Abdullah, Ezzat Chan Abdullah, Luqman Chuah |
| author_sort | Abdullah, Nurul Hidayah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Activated sericite was used as a solid matrix for control over the size of iron oxide nanoparticles (NPs). The activation of sericite was achieved by undergoing thermal, acid and salt treatments. Different weight ratios (w.r.) of iron oxide to activated sericite were prepared by varying the amount of iron oxide. X-ray diffraction (XRD) patterns illustrated a decrease in the intensity of sericite peaks by increasing the amount of iron oxide. High resolution-transmission electron microscopy (HR-TEM) analysis showed the formation of highly distributed quasi-spherical iron oxide NPs with average diameter of about 3.56–7.78 nm. The formation of mesoporous iron oxide NPs on the surface and edge of the activated sericite surface were also observed under Field emission scanning electron microscopy (FESEM). Vibration sample magnetometer (VSM) measurement revealed the nanocomposites (NCs) with saturation magnetization of about 2.17–8.12 emu·g−1. Brunauer-Emmett-Teller (BET) surface area analysis revealed the specific surface area of NCs between 79.4 and 161.5 m2·g−1. Fourier transform infrared (FTIR) spectra showed non-bond chemical interaction between the iron oxide and rigid silicate layers. Ultraviolet–visible (UV–vis) diffuse reflectance spectroscopy confirms that the material has band gap energy of about 2.55 eV. The NC with w.r. of 1:3 (iron oxide to activated sericite) showed the best performance with high specific surface area and sufficient magnetization for easy magnetic separation. The selected NC showed maximum removal efficiency over 99% for methylene blue and crystal violet dyes within 20 min. |
| first_indexed | 2025-11-15T12:42:06Z |
| format | Article |
| id | upm-86599 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T12:42:06Z |
| publishDate | 2020 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-865992021-09-29T00:50:01Z http://psasir.upm.edu.my/id/eprint/86599/ Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes Abdullah, Nurul Hidayah Shameli, Kamyar Abdullah, Ezzat Chan Abdullah, Luqman Chuah Activated sericite was used as a solid matrix for control over the size of iron oxide nanoparticles (NPs). The activation of sericite was achieved by undergoing thermal, acid and salt treatments. Different weight ratios (w.r.) of iron oxide to activated sericite were prepared by varying the amount of iron oxide. X-ray diffraction (XRD) patterns illustrated a decrease in the intensity of sericite peaks by increasing the amount of iron oxide. High resolution-transmission electron microscopy (HR-TEM) analysis showed the formation of highly distributed quasi-spherical iron oxide NPs with average diameter of about 3.56–7.78 nm. The formation of mesoporous iron oxide NPs on the surface and edge of the activated sericite surface were also observed under Field emission scanning electron microscopy (FESEM). Vibration sample magnetometer (VSM) measurement revealed the nanocomposites (NCs) with saturation magnetization of about 2.17–8.12 emu·g−1. Brunauer-Emmett-Teller (BET) surface area analysis revealed the specific surface area of NCs between 79.4 and 161.5 m2·g−1. Fourier transform infrared (FTIR) spectra showed non-bond chemical interaction between the iron oxide and rigid silicate layers. Ultraviolet–visible (UV–vis) diffuse reflectance spectroscopy confirms that the material has band gap energy of about 2.55 eV. The NC with w.r. of 1:3 (iron oxide to activated sericite) showed the best performance with high specific surface area and sufficient magnetization for easy magnetic separation. The selected NC showed maximum removal efficiency over 99% for methylene blue and crystal violet dyes within 20 min. Elsevier 2020-05 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/86599/1/Low%20cost%20and%20efficient%20synthesis%20.pdf Abdullah, Nurul Hidayah and Shameli, Kamyar and Abdullah, Ezzat Chan and Abdullah, Luqman Chuah (2020) Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes. Materials Characterization, 163. pp. 1-21. ISSN 1044-5803 https://www.sciencedirect.com/science/article/abs/pii/S1044580319325070 10.1016/j.matchar.2020.110275 |
| spellingShingle | Abdullah, Nurul Hidayah Shameli, Kamyar Abdullah, Ezzat Chan Abdullah, Luqman Chuah Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes |
| title | Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes |
| title_full | Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes |
| title_fullStr | Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes |
| title_full_unstemmed | Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes |
| title_short | Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes |
| title_sort | low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes |
| url | http://psasir.upm.edu.my/id/eprint/86599/ http://psasir.upm.edu.my/id/eprint/86599/ http://psasir.upm.edu.my/id/eprint/86599/ http://psasir.upm.edu.my/id/eprint/86599/1/Low%20cost%20and%20efficient%20synthesis%20.pdf |