Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics

The influence of Sn doping in calcium (Ca) and copper (Cu) sItes either temperature for 30 hours soaking time were studied For Sn-free sample. heat treatment improved the superconducting transition temperature, TC(RI)) from 100 K to 104 K, when the sintered sample was annealed at 820°C The highes...

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Main Author: Hashim @ Ismail, Azhan
Format: Thesis
Language:English
English
Published: 1999
Subjects:
Online Access:http://psasir.upm.edu.my/id/eprint/8657/
http://psasir.upm.edu.my/id/eprint/8657/1/FSAS_1999_12_IR.pdf
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author Hashim @ Ismail, Azhan
author_facet Hashim @ Ismail, Azhan
author_sort Hashim @ Ismail, Azhan
building UPM Institutional Repository
collection Online Access
description The influence of Sn doping in calcium (Ca) and copper (Cu) sItes either temperature for 30 hours soaking time were studied For Sn-free sample. heat treatment improved the superconducting transition temperature, TC(RI)) from 100 K to 104 K, when the sintered sample was annealed at 820°C The highest Tc(R=0) of 104 K was observed for sintered sample (x=0 02) with simultaneous doping The heat treatment improved the Tc(R=0) from 60 K to 94 K or sample doped 111 Ca site when re-sintered at 855°C and from 66 K to 100 K for sample doped with Sn in Cu site when annealed at 840°C For simultaneous doping, the T C(R 0) dId not change significantly after heat treatment except for sample with x=0 05 that showed drastic improvement of T C(R=U) from 64 K (sintered) to above 100 K From XRD analysis, the volume of 2223 phase decreased as the Sn concentration increased A ll samples with Sn concentration above x=0 10 contall1ed unknown peaks which con respond to the non-superconducting phase although the lattice parameter of the samples shortened, the crystallographic structure remained in the tetragonal form.
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format Thesis
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institution Universiti Putra Malaysia
institution_category Local University
language English
English
last_indexed 2025-11-15T07:35:11Z
publishDate 1999
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spelling upm-86572023-12-14T00:24:15Z http://psasir.upm.edu.my/id/eprint/8657/ Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics Hashim @ Ismail, Azhan The influence of Sn doping in calcium (Ca) and copper (Cu) sItes either temperature for 30 hours soaking time were studied For Sn-free sample. heat treatment improved the superconducting transition temperature, TC(RI)) from 100 K to 104 K, when the sintered sample was annealed at 820°C The highest Tc(R=0) of 104 K was observed for sintered sample (x=0 02) with simultaneous doping The heat treatment improved the Tc(R=0) from 60 K to 94 K or sample doped 111 Ca site when re-sintered at 855°C and from 66 K to 100 K for sample doped with Sn in Cu site when annealed at 840°C For simultaneous doping, the T C(R 0) dId not change significantly after heat treatment except for sample with x=0 05 that showed drastic improvement of T C(R=U) from 64 K (sintered) to above 100 K From XRD analysis, the volume of 2223 phase decreased as the Sn concentration increased A ll samples with Sn concentration above x=0 10 contall1ed unknown peaks which con respond to the non-superconducting phase although the lattice parameter of the samples shortened, the crystallographic structure remained in the tetragonal form. 1999-12 Thesis NonPeerReviewed text en http://psasir.upm.edu.my/id/eprint/8657/1/FSAS_1999_12_IR.pdf Hashim @ Ismail, Azhan (1999) Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics. Doctoral thesis, Universiti Putra Malaysia. Ceramic superconductor English
spellingShingle Ceramic superconductor
Hashim @ Ismail, Azhan
Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics
title Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics
title_full Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics
title_fullStr Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics
title_full_unstemmed Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics
title_short Effect of stanum doping and heat treatment on Bi-Sr-Ca-Cu-O superconducting ceramics
title_sort effect of stanum doping and heat treatment on bi-sr-ca-cu-o superconducting ceramics
topic Ceramic superconductor
url http://psasir.upm.edu.my/id/eprint/8657/
http://psasir.upm.edu.my/id/eprint/8657/1/FSAS_1999_12_IR.pdf