Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release

A carbonation process to control the specific surface area of mesoporous calcium carbonate and the dissolution profile of ferulic acid on mesoporous carbonate particles are presented. The effects of water content on the physicochemical properties, specific surface area, pore size, crystallinity, and...

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Main Authors: Kadota, Kazunori, Ibe, Toi, Sugawara, Yuto, Takano, Hitomi, Yusof, Yus Aniza, Uchiyama, Hiromasa, Tozuka, Yuichi, Yamanaka, Shinya
Format: Article
Published: Royal Society of Chemistry 2020
Online Access:http://psasir.upm.edu.my/id/eprint/86510/
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author Kadota, Kazunori
Ibe, Toi
Sugawara, Yuto
Takano, Hitomi
Yusof, Yus Aniza
Uchiyama, Hiromasa
Tozuka, Yuichi
Yamanaka, Shinya
author_facet Kadota, Kazunori
Ibe, Toi
Sugawara, Yuto
Takano, Hitomi
Yusof, Yus Aniza
Uchiyama, Hiromasa
Tozuka, Yuichi
Yamanaka, Shinya
author_sort Kadota, Kazunori
building UPM Institutional Repository
collection Online Access
description A carbonation process to control the specific surface area of mesoporous calcium carbonate and the dissolution profile of ferulic acid on mesoporous carbonate particles are presented. The effects of water content on the physicochemical properties, specific surface area, pore size, crystallinity, and morphology are evaluated. Mesoporous calcium carbonate particles are synthesised with well-controlled specific surface areas of 38.8 to 234 m2 g-1. Each of the submicron-size secondary particles consists of a primary particle of nano-size. During secondary particle formation, primary particle growth is curbed in the case with less water content. By contrast, growth is promoted via dissolution and recrystallisation in the presence of water. The release rates of ferulic acid are gradually enhanced with increasing specific surface area of the mesoporous calcium carbonate, that reflects crystallinity of ferulic acid.
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institution Universiti Putra Malaysia
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publishDate 2020
publisher Royal Society of Chemistry
recordtype eprints
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spelling upm-865102023-11-06T03:01:25Z http://psasir.upm.edu.my/id/eprint/86510/ Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release Kadota, Kazunori Ibe, Toi Sugawara, Yuto Takano, Hitomi Yusof, Yus Aniza Uchiyama, Hiromasa Tozuka, Yuichi Yamanaka, Shinya A carbonation process to control the specific surface area of mesoporous calcium carbonate and the dissolution profile of ferulic acid on mesoporous carbonate particles are presented. The effects of water content on the physicochemical properties, specific surface area, pore size, crystallinity, and morphology are evaluated. Mesoporous calcium carbonate particles are synthesised with well-controlled specific surface areas of 38.8 to 234 m2 g-1. Each of the submicron-size secondary particles consists of a primary particle of nano-size. During secondary particle formation, primary particle growth is curbed in the case with less water content. By contrast, growth is promoted via dissolution and recrystallisation in the presence of water. The release rates of ferulic acid are gradually enhanced with increasing specific surface area of the mesoporous calcium carbonate, that reflects crystallinity of ferulic acid. Royal Society of Chemistry 2020-07-28 Article PeerReviewed Kadota, Kazunori and Ibe, Toi and Sugawara, Yuto and Takano, Hitomi and Yusof, Yus Aniza and Uchiyama, Hiromasa and Tozuka, Yuichi and Yamanaka, Shinya (2020) Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release. RSC Advances, 10 (47). 28019 - 28025. ISSN 2046-2069 https://pubs.rsc.org/en/content/articlelanding/2020/ra/d0ra05542e 10.1039/D0RA05542E
spellingShingle Kadota, Kazunori
Ibe, Toi
Sugawara, Yuto
Takano, Hitomi
Yusof, Yus Aniza
Uchiyama, Hiromasa
Tozuka, Yuichi
Yamanaka, Shinya
Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release
title Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release
title_full Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release
title_fullStr Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release
title_full_unstemmed Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release
title_short Water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release
title_sort water-assisted synthesis of mesoporous calcium carbonate with a controlled specific surface area and its potential to ferulic acid release
url http://psasir.upm.edu.my/id/eprint/86510/
http://psasir.upm.edu.my/id/eprint/86510/
http://psasir.upm.edu.my/id/eprint/86510/