Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses

In this work, boro-telluride glasses with additional zinc, aluminum, and alkali–alkaline modifiers have been synthesized using the melt-quenching–annealing method. Six glasses were fabricated with composition of [(60 − x)B₂O₃–(10 + x)TeO₂–10ZnO–10Al₂O₃ 5Li₂O–5MgO] all in mol% and x varied from 0, 10...

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Main Authors: Kaky, Kawa M., Sayyed, M. I., Laariedh, F., Abdalsalam, Alyaa H., Tekin, Huseyin Ozan, Baki, S. O.
Format: Article
Language:English
Published: Springer 2019
Online Access:http://psasir.upm.edu.my/id/eprint/82285/
http://psasir.upm.edu.my/id/eprint/82285/1/Stuctural%2C%20optical.pdf
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author Kaky, Kawa M.
Sayyed, M. I.
Laariedh, F.
Abdalsalam, Alyaa H.
Tekin, Huseyin Ozan
Baki, S. O.
author_facet Kaky, Kawa M.
Sayyed, M. I.
Laariedh, F.
Abdalsalam, Alyaa H.
Tekin, Huseyin Ozan
Baki, S. O.
author_sort Kaky, Kawa M.
building UPM Institutional Repository
collection Online Access
description In this work, boro-telluride glasses with additional zinc, aluminum, and alkali–alkaline modifiers have been synthesized using the melt-quenching–annealing method. Six glasses were fabricated with composition of [(60 − x)B₂O₃–(10 + x)TeO₂–10ZnO–10Al₂O₃ 5Li₂O–5MgO] all in mol% and x varied from 0, 10, 20, 30, 40 and 50. The aim of this work is to understand the effect of changing the main glass former from B₂O₃ → TeO₂, to obtain new optical materials. To confirm the amorphous nature of these six glasses, X-ray diffraction was characterized for all six glasses from 10° to 80°. Optical absorption with wavelength range 200–800 nm in room temperature was measured, and the optical absorption coefficient α(λ) calculated to obtain the cutoff wavelength. In addition, gamma photons shielding features of the prepared K1–K6 glasses were evaluated by means of some essential parameters such as mass attenuation coefficients (μ/ρ) and effective atomic number (Zeff) at five energies between 0.356 and 1.33 MeV. No significant difference between the theoretical and simulation μ/ρ values was found. The effective atomic number results indiacte that as the TeO₂ content increases, the photons’ attenuation increases. The number of interactions of gamma photons with K6 sample (which contains the maximum amount of TeO₂) is relatively high (in comparison to the rest of the samples), which results in more attenuation and thus better shielding features for K6.
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spelling upm-822852020-10-16T20:33:55Z http://psasir.upm.edu.my/id/eprint/82285/ Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses Kaky, Kawa M. Sayyed, M. I. Laariedh, F. Abdalsalam, Alyaa H. Tekin, Huseyin Ozan Baki, S. O. In this work, boro-telluride glasses with additional zinc, aluminum, and alkali–alkaline modifiers have been synthesized using the melt-quenching–annealing method. Six glasses were fabricated with composition of [(60 − x)B₂O₃–(10 + x)TeO₂–10ZnO–10Al₂O₃ 5Li₂O–5MgO] all in mol% and x varied from 0, 10, 20, 30, 40 and 50. The aim of this work is to understand the effect of changing the main glass former from B₂O₃ → TeO₂, to obtain new optical materials. To confirm the amorphous nature of these six glasses, X-ray diffraction was characterized for all six glasses from 10° to 80°. Optical absorption with wavelength range 200–800 nm in room temperature was measured, and the optical absorption coefficient α(λ) calculated to obtain the cutoff wavelength. In addition, gamma photons shielding features of the prepared K1–K6 glasses were evaluated by means of some essential parameters such as mass attenuation coefficients (μ/ρ) and effective atomic number (Zeff) at five energies between 0.356 and 1.33 MeV. No significant difference between the theoretical and simulation μ/ρ values was found. The effective atomic number results indiacte that as the TeO₂ content increases, the photons’ attenuation increases. The number of interactions of gamma photons with K6 sample (which contains the maximum amount of TeO₂) is relatively high (in comparison to the rest of the samples), which results in more attenuation and thus better shielding features for K6. Springer 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/82285/1/Stuctural%2C%20optical.pdf Kaky, Kawa M. and Sayyed, M. I. and Laariedh, F. and Abdalsalam, Alyaa H. and Tekin, Huseyin Ozan and Baki, S. O. (2019) Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses. Applied Physics A-Materials Science & Processing, 125 (32). pp. 1-12. ISSN 0947-8396 10.1007/s00339-018-2329-3
spellingShingle Kaky, Kawa M.
Sayyed, M. I.
Laariedh, F.
Abdalsalam, Alyaa H.
Tekin, Huseyin Ozan
Baki, S. O.
Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses
title Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses
title_full Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses
title_fullStr Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses
title_full_unstemmed Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses
title_short Stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses
title_sort stuctural, optical and radiation shielding properties of zinc boro-tellurite alumina glasses
url http://psasir.upm.edu.my/id/eprint/82285/
http://psasir.upm.edu.my/id/eprint/82285/
http://psasir.upm.edu.my/id/eprint/82285/1/Stuctural%2C%20optical.pdf