PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency

The usage of biopolymers in developing biodegradable food packaging films that are sustainable and safe towards environment has been restricted because of the poor mechanical and barrier properties of the biopolymers. This study aims to enhance the limited properties of biopolymers particularly poly...

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Main Authors: Othman, Siti Hajar, Ling, Hee Nyia, A. Talib, Rosnita, Naim, Mohd Nazli, Risyon, Nazratul Putri, Md. Saifullah
Format: Article
Language:English
Published: Scientific.Net 2019
Online Access:http://psasir.upm.edu.my/id/eprint/81744/
http://psasir.upm.edu.my/id/eprint/81744/1/PLA_MMT%20and%20PLA.pdf
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author Othman, Siti Hajar
Ling, Hee Nyia
A. Talib, Rosnita
Naim, Mohd Nazli
Risyon, Nazratul Putri
Md. Saifullah
author_facet Othman, Siti Hajar
Ling, Hee Nyia
A. Talib, Rosnita
Naim, Mohd Nazli
Risyon, Nazratul Putri
Md. Saifullah
author_sort Othman, Siti Hajar
building UPM Institutional Repository
collection Online Access
description The usage of biopolymers in developing biodegradable food packaging films that are sustainable and safe towards environment has been restricted because of the poor mechanical and barrier properties of the biopolymers. This study aims to enhance the limited properties of biopolymers particularly polylactic acid (PLA) for food packaging applications by investigating the effects of incorporating different types (montmorillonite (MMT) and halloysite) and concentrations (0–9 wt.%) of nanoclays on the mechanical, oxygen barrier, and transparency properties of the films. PLA with 3 wt.% concentration of nanoclays resulted in the optimum mechanical and oxygen barrier properties due to the strong interaction between nanoclays and torturous path length created by nanoclays respectively. Nevertheless, these properties reduced as more nanoclays (≥5 wt.%) was added into the films due to agglomeration of nanoclays. PLA incorporated with MMT nanoclay exhibited better properties compared to halloysite nanoclay due to the nanoclay structure in nature. Addition of 3 wt.% nanoclays into virtually transparent PLA film have only small effects on the transparency of the film whereby the reduction in light transmittance was only around 10%. This study is crucial to improve the feasibility of biopolymers usage for food packaging applications
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institution Universiti Putra Malaysia
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language English
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spelling upm-817442022-12-14T08:00:41Z http://psasir.upm.edu.my/id/eprint/81744/ PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency Othman, Siti Hajar Ling, Hee Nyia A. Talib, Rosnita Naim, Mohd Nazli Risyon, Nazratul Putri Md. Saifullah The usage of biopolymers in developing biodegradable food packaging films that are sustainable and safe towards environment has been restricted because of the poor mechanical and barrier properties of the biopolymers. This study aims to enhance the limited properties of biopolymers particularly polylactic acid (PLA) for food packaging applications by investigating the effects of incorporating different types (montmorillonite (MMT) and halloysite) and concentrations (0–9 wt.%) of nanoclays on the mechanical, oxygen barrier, and transparency properties of the films. PLA with 3 wt.% concentration of nanoclays resulted in the optimum mechanical and oxygen barrier properties due to the strong interaction between nanoclays and torturous path length created by nanoclays respectively. Nevertheless, these properties reduced as more nanoclays (≥5 wt.%) was added into the films due to agglomeration of nanoclays. PLA incorporated with MMT nanoclay exhibited better properties compared to halloysite nanoclay due to the nanoclay structure in nature. Addition of 3 wt.% nanoclays into virtually transparent PLA film have only small effects on the transparency of the film whereby the reduction in light transmittance was only around 10%. This study is crucial to improve the feasibility of biopolymers usage for food packaging applications Scientific.Net 2019-08 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/81744/1/PLA_MMT%20and%20PLA.pdf Othman, Siti Hajar and Ling, Hee Nyia and A. Talib, Rosnita and Naim, Mohd Nazli and Risyon, Nazratul Putri and Md. Saifullah (2019) PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency. Journal of Nano Research, 59. pp. 77-93. ISSN 1662-5250; ESSN:1661-9897 https://www.scientific.net/JNanoR.59.77 10.4028/www.scientific.net/JNanoR.59.77
spellingShingle Othman, Siti Hajar
Ling, Hee Nyia
A. Talib, Rosnita
Naim, Mohd Nazli
Risyon, Nazratul Putri
Md. Saifullah
PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency
title PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency
title_full PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency
title_fullStr PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency
title_full_unstemmed PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency
title_short PLA/MMT and PLA/Halloysite Bio-Nanocomposite Films: mechanical, barrier, and transparency
title_sort pla/mmt and pla/halloysite bio-nanocomposite films: mechanical, barrier, and transparency
url http://psasir.upm.edu.my/id/eprint/81744/
http://psasir.upm.edu.my/id/eprint/81744/
http://psasir.upm.edu.my/id/eprint/81744/
http://psasir.upm.edu.my/id/eprint/81744/1/PLA_MMT%20and%20PLA.pdf