Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil

Epoxidized jatropha oil (EJO) was investigated as a sustainable alternative to petrochemical-based plasticizers to reinforce the plastics, leading to increased ductility and toughness of kenaf-reinforced poly(lactic acid) (PLA). The EJO was melt-blended into kenaf-reinforced PLA at concentrations fr...

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Main Authors: Kamarudin, Siti Hasnah, Abdullah, Luqman Chuah, Aung, Min Min, Ratnam, Chantara Thevy
Format: Article
Language:English
Published: College of Natural Resources, North Carolina State University 2019
Online Access:http://psasir.upm.edu.my/id/eprint/81312/
http://psasir.upm.edu.my/id/eprint/81312/1/KENAF.pdf
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author Kamarudin, Siti Hasnah
Abdullah, Luqman Chuah
Aung, Min Min
Ratnam, Chantara Thevy
author_facet Kamarudin, Siti Hasnah
Abdullah, Luqman Chuah
Aung, Min Min
Ratnam, Chantara Thevy
author_sort Kamarudin, Siti Hasnah
building UPM Institutional Repository
collection Online Access
description Epoxidized jatropha oil (EJO) was investigated as a sustainable alternative to petrochemical-based plasticizers to reinforce the plastics, leading to increased ductility and toughness of kenaf-reinforced poly(lactic acid) (PLA). The EJO was melt-blended into kenaf-reinforced PLA at concentrations from 1 wt% to 5 wt%. The blends were then hot-pressed into sheets to characterize their mechanical and physical properties. Kenaf fibers were treated with 6% sodium hydroxide (NaOH), and the effects thereof on the composites’ tensile, flexural, and impact properties, as well as their water absorption and density were stu died. The impact strengths of the kenaf-reinforced PLA composites were improved with the addition of EJO up to 5 wt%, with a maximum over 10 times that of the neat PLA. The flexural strength and modulus increased 4% and 50%, respectively, for treated kenaf-reinforced PLA plasticized with EJO. This increase demonstrated the alkalization treatment’s notable improvements to the composites’ properties. Furthermore, analysis by scanning electron microscopy (SEM) of the composites’ tensile fracture surfaces indicated better interaction adhesion of the treated kenaf-reinforced PLA plasticized with EJO compared with the untreated composites. Compared to untreated 1 wt% EJO biocomposites, the treated 5 wt% EJO biocomposites reduced water absorption from 3.1% to 1.6% after 8 weeks of immersion.
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spelling upm-813122021-06-13T13:24:03Z http://psasir.upm.edu.my/id/eprint/81312/ Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil Kamarudin, Siti Hasnah Abdullah, Luqman Chuah Aung, Min Min Ratnam, Chantara Thevy Epoxidized jatropha oil (EJO) was investigated as a sustainable alternative to petrochemical-based plasticizers to reinforce the plastics, leading to increased ductility and toughness of kenaf-reinforced poly(lactic acid) (PLA). The EJO was melt-blended into kenaf-reinforced PLA at concentrations from 1 wt% to 5 wt%. The blends were then hot-pressed into sheets to characterize their mechanical and physical properties. Kenaf fibers were treated with 6% sodium hydroxide (NaOH), and the effects thereof on the composites’ tensile, flexural, and impact properties, as well as their water absorption and density were stu died. The impact strengths of the kenaf-reinforced PLA composites were improved with the addition of EJO up to 5 wt%, with a maximum over 10 times that of the neat PLA. The flexural strength and modulus increased 4% and 50%, respectively, for treated kenaf-reinforced PLA plasticized with EJO. This increase demonstrated the alkalization treatment’s notable improvements to the composites’ properties. Furthermore, analysis by scanning electron microscopy (SEM) of the composites’ tensile fracture surfaces indicated better interaction adhesion of the treated kenaf-reinforced PLA plasticized with EJO compared with the untreated composites. Compared to untreated 1 wt% EJO biocomposites, the treated 5 wt% EJO biocomposites reduced water absorption from 3.1% to 1.6% after 8 weeks of immersion. College of Natural Resources, North Carolina State University 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/81312/1/KENAF.pdf Kamarudin, Siti Hasnah and Abdullah, Luqman Chuah and Aung, Min Min and Ratnam, Chantara Thevy (2019) Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil. BioResources, 14 (4). pp. 9001-9020. ISSN 1930-2126 https://bioresources.cnr.ncsu.edu/resources/mechanical-and-physical-properties-of-kenaf-reinforced-polylactic-acid-plasticized-with-epoxidized-jatropha-oil/
spellingShingle Kamarudin, Siti Hasnah
Abdullah, Luqman Chuah
Aung, Min Min
Ratnam, Chantara Thevy
Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil
title Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil
title_full Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil
title_fullStr Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil
title_full_unstemmed Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil
title_short Mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil
title_sort mechanical and physical properties of kenaf-reinforced poly(lactic acid) plasticized with epoxidized jatropha oil
url http://psasir.upm.edu.my/id/eprint/81312/
http://psasir.upm.edu.my/id/eprint/81312/
http://psasir.upm.edu.my/id/eprint/81312/1/KENAF.pdf