Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation

This paper is an expansion of our previous work on the synthesis of graphene oxides and reduced graphene oxides from different kinds of oil palm waste-based feedstocks, namely, OPL (oil palm leaf), PKS (palm kernel shell), and EFB (empty fruit bunch). Here, the electrochemical measurements of the re...

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Main Authors: Nasir, Salisu, Hussein, Mohd Zobir, Zainal, Zulkarnain, Yusof, Nor Azah
Format: Article
Language:English
Published: Hindawi 2019
Online Access:http://psasir.upm.edu.my/id/eprint/81161/
http://psasir.upm.edu.my/id/eprint/81161/1/KERNEL.pdf
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author Nasir, Salisu
Hussein, Mohd Zobir
Zainal, Zulkarnain
Yusof, Nor Azah
author_facet Nasir, Salisu
Hussein, Mohd Zobir
Zainal, Zulkarnain
Yusof, Nor Azah
author_sort Nasir, Salisu
building UPM Institutional Repository
collection Online Access
description This paper is an expansion of our previous work on the synthesis of graphene oxides and reduced graphene oxides from different kinds of oil palm waste-based feedstocks, namely, OPL (oil palm leaf), PKS (palm kernel shell), and EFB (empty fruit bunch). Here, the electrochemical measurements of the resulting reduced graphene oxides derived via mild-temperature annealing reduction of the graphene oxides were accomplished using cyclic voltammetry and galvanostatic charge/discharge processes. The findings put forward their promising features for supercapacitor applications. For instance, the reduced graphene oxide derived using EFB precursor (rGOEFB) which has a BET surface area of 117 m2 g-1 exhibits a specific capacitance of 688 F g−1 at an applied current density of 0.8 A g-1. This is higher than that observed for reduced graphene oxides derived from oil palm leaf (rGOOPL), palm kernel shell (rGOPKS), and the commercially acquired graphite (rGOCG), which possessed specific capacitance values of 632, 424, and 220 F g−1, respectively. It can be deduced that the specific capacitance of the reduced graphene oxide samples increases in the following order: (rGOCG) < (rGOPKS) < (rGOOPL) < (rGOEFB). In summary, these new classes of carbon-based nanomaterials could be applied as efficient electrode materials for supercapacitor application with potential good performance. With this novel green and sustainable approach, various carbon-based nanomaterials can be fabricated for a broad range of multifunctional applications.
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spelling upm-811612021-05-07T00:51:22Z http://psasir.upm.edu.my/id/eprint/81161/ Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation Nasir, Salisu Hussein, Mohd Zobir Zainal, Zulkarnain Yusof, Nor Azah This paper is an expansion of our previous work on the synthesis of graphene oxides and reduced graphene oxides from different kinds of oil palm waste-based feedstocks, namely, OPL (oil palm leaf), PKS (palm kernel shell), and EFB (empty fruit bunch). Here, the electrochemical measurements of the resulting reduced graphene oxides derived via mild-temperature annealing reduction of the graphene oxides were accomplished using cyclic voltammetry and galvanostatic charge/discharge processes. The findings put forward their promising features for supercapacitor applications. For instance, the reduced graphene oxide derived using EFB precursor (rGOEFB) which has a BET surface area of 117 m2 g-1 exhibits a specific capacitance of 688 F g−1 at an applied current density of 0.8 A g-1. This is higher than that observed for reduced graphene oxides derived from oil palm leaf (rGOOPL), palm kernel shell (rGOPKS), and the commercially acquired graphite (rGOCG), which possessed specific capacitance values of 632, 424, and 220 F g−1, respectively. It can be deduced that the specific capacitance of the reduced graphene oxide samples increases in the following order: (rGOCG) < (rGOPKS) < (rGOOPL) < (rGOEFB). In summary, these new classes of carbon-based nanomaterials could be applied as efficient electrode materials for supercapacitor application with potential good performance. With this novel green and sustainable approach, various carbon-based nanomaterials can be fabricated for a broad range of multifunctional applications. Hindawi 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/81161/1/KERNEL.pdf Nasir, Salisu and Hussein, Mohd Zobir and Zainal, Zulkarnain and Yusof, Nor Azah (2019) Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation. Journal of Nanomaterials, 2019. art. no. 1970365. pp. 1-14. ISSN 1687-4110; ESSN: 1687-4129 https://www.hindawi.com/journals/jnm/2019/1970365/ 10.1155/2019/1970365
spellingShingle Nasir, Salisu
Hussein, Mohd Zobir
Zainal, Zulkarnain
Yusof, Nor Azah
Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation
title Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation
title_full Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation
title_fullStr Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation
title_full_unstemmed Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation
title_short Development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation
title_sort development of new carbon-based electrode material from oil palm wastes-derived reduced graphene oxide and its capacitive performance evaluation
url http://psasir.upm.edu.my/id/eprint/81161/
http://psasir.upm.edu.my/id/eprint/81161/
http://psasir.upm.edu.my/id/eprint/81161/
http://psasir.upm.edu.my/id/eprint/81161/1/KERNEL.pdf