Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles

The effect of different sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite was investigated. In this study, a ZnO-Zn2SiO4 composite was prepared by encapsulated zinc nitrate hexahydrate with amorphous silica nanoparticles in deionized water. The amorphous silica nan...

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Main Authors: Che Engku Ali, Engku Abd Ghapur, Matori, Khamirul Amin, Saion, Elias, Abd. Aziz, Sidek, Mohd Zaid, Mohd Hafiz, Alibe, Ibrahim Mustapha
Format: Article
Language:English
Published: Springer 2019
Online Access:http://psasir.upm.edu.my/id/eprint/79541/
http://psasir.upm.edu.my/id/eprint/79541/1/Effect%20of%20sintering%20temperatures%20.pdf
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author Che Engku Ali, Engku Abd Ghapur
Matori, Khamirul Amin
Saion, Elias
Abd. Aziz, Sidek
Mohd Zaid, Mohd Hafiz
Alibe, Ibrahim Mustapha
author_facet Che Engku Ali, Engku Abd Ghapur
Matori, Khamirul Amin
Saion, Elias
Abd. Aziz, Sidek
Mohd Zaid, Mohd Hafiz
Alibe, Ibrahim Mustapha
author_sort Che Engku Ali, Engku Abd Ghapur
building UPM Institutional Repository
collection Online Access
description The effect of different sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite was investigated. In this study, a ZnO-Zn2SiO4 composite was prepared by encapsulated zinc nitrate hexahydrate with amorphous silica nanoparticles in deionized water. The amorphous silica nanoparticles were prepared by reacting sodium silicate with ethanol. Zinc nitrate was mixed with the obtained amorphous silica nanoparticles with the ratio of 2:1 and 1.25:1 for Zn:Si and subjected to the different sintering temperatures from 600 to 1000 °C. Field emission scanning electron microscope (FESEM) microstructure showed that samples exhibit spherical morphology up to 700 °C and dumbbell morphology above 800 °C sintering temperature. The formation of Zn2SiO4 crystal phase appears from 700 °C and onwards together with ZnO crystal phase. The gaining of sintering temperature has also raised the amount of Zn2SiO4 phase and band gap values of the ZnO-Zn2SiO4 composite.
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institution Universiti Putra Malaysia
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publisher Springer
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spelling upm-795412021-06-02T09:55:35Z http://psasir.upm.edu.my/id/eprint/79541/ Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles Che Engku Ali, Engku Abd Ghapur Matori, Khamirul Amin Saion, Elias Abd. Aziz, Sidek Mohd Zaid, Mohd Hafiz Alibe, Ibrahim Mustapha The effect of different sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite was investigated. In this study, a ZnO-Zn2SiO4 composite was prepared by encapsulated zinc nitrate hexahydrate with amorphous silica nanoparticles in deionized water. The amorphous silica nanoparticles were prepared by reacting sodium silicate with ethanol. Zinc nitrate was mixed with the obtained amorphous silica nanoparticles with the ratio of 2:1 and 1.25:1 for Zn:Si and subjected to the different sintering temperatures from 600 to 1000 °C. Field emission scanning electron microscope (FESEM) microstructure showed that samples exhibit spherical morphology up to 700 °C and dumbbell morphology above 800 °C sintering temperature. The formation of Zn2SiO4 crystal phase appears from 700 °C and onwards together with ZnO crystal phase. The gaining of sintering temperature has also raised the amount of Zn2SiO4 phase and band gap values of the ZnO-Zn2SiO4 composite. Springer 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/79541/1/Effect%20of%20sintering%20temperatures%20.pdf Che Engku Ali, Engku Abd Ghapur and Matori, Khamirul Amin and Saion, Elias and Abd. Aziz, Sidek and Mohd Zaid, Mohd Hafiz and Alibe, Ibrahim Mustapha (2019) Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles. Journal of the Australian Ceramic Society, 55 (1). pp. 115-122. ISSN 2510-1560; ESSN: 2510-1579 https://link.springer.com/article/10.1007/s41779-018-0217-0 10.1007/s41779-018-0217-0
spellingShingle Che Engku Ali, Engku Abd Ghapur
Matori, Khamirul Amin
Saion, Elias
Abd. Aziz, Sidek
Mohd Zaid, Mohd Hafiz
Alibe, Ibrahim Mustapha
Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles
title Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles
title_full Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles
title_fullStr Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles
title_full_unstemmed Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles
title_short Effect of sintering temperatures on structural and optical properties of ZnO-Zn2SiO4 composite prepared by using amorphous SiO2 nanoparticles
title_sort effect of sintering temperatures on structural and optical properties of zno-zn2sio4 composite prepared by using amorphous sio2 nanoparticles
url http://psasir.upm.edu.my/id/eprint/79541/
http://psasir.upm.edu.my/id/eprint/79541/
http://psasir.upm.edu.my/id/eprint/79541/
http://psasir.upm.edu.my/id/eprint/79541/1/Effect%20of%20sintering%20temperatures%20.pdf