Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films

Mixed dye consists of six commercial dyes and textile effluents from cotton dyeing process were treated by electrochemical-assisted photodegradation under halogen lamp illumination. Two types of effluents were collected which are samples before and after undergone pre-treatment at the factory wastew...

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Main Authors: Zainal, Zulkarnain, Hussein, Mohd Zobir, Kassim, Anuar, Yusof, Nor Azah, Chong, Yong Lee
Format: Article
Language:English
English
Published: Elsevier 2007
Online Access:http://psasir.upm.edu.my/id/eprint/7661/
http://psasir.upm.edu.my/id/eprint/7661/1/Electrochemical-assisted%20photodegradation%20of%20mixed%20dye%20and%20textile%20effluents%20using%20TiO2%20thin%20films.pdf
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author Zainal, Zulkarnain
Hussein, Mohd Zobir
Kassim, Anuar
Yusof, Nor Azah
Chong, Yong Lee
author_facet Zainal, Zulkarnain
Hussein, Mohd Zobir
Kassim, Anuar
Yusof, Nor Azah
Chong, Yong Lee
author_sort Zainal, Zulkarnain
building UPM Institutional Repository
collection Online Access
description Mixed dye consists of six commercial dyes and textile effluents from cotton dyeing process were treated by electrochemical-assisted photodegradation under halogen lamp illumination. Two types of effluents were collected which are samples before and after undergone pre-treatment at the factory wastewater treatment plant. The photodegradation process was studied by evaluating the changes in concentration employing UV–vis spectrophotometer (UV–vis) and total organic carbon (TOC) analysis. The photoelectrochemical degradation of mixed dye was found to follow the Langmuir Hinshelwood pseudo-first order kinetic while pseudo-second order kinetic model for effluents by using TOC analyses. The chemical oxygen demand (COD) and biochemical oxygen demand (BOD) values of mixed dye and raw effluents were reported. Photoelectrochemical characteristic of pollutants was studied using the cyclic voltammetry technique. Raw effluent was found to exhibit stronger reduction behaviour at cathodic bias potential but slightly less photoresponse at anodic bias than mixed dye.
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language English
English
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publishDate 2007
publisher Elsevier
recordtype eprints
repository_type Digital Repository
spelling upm-76612015-12-01T00:32:08Z http://psasir.upm.edu.my/id/eprint/7661/ Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films Zainal, Zulkarnain Hussein, Mohd Zobir Kassim, Anuar Yusof, Nor Azah Chong, Yong Lee Mixed dye consists of six commercial dyes and textile effluents from cotton dyeing process were treated by electrochemical-assisted photodegradation under halogen lamp illumination. Two types of effluents were collected which are samples before and after undergone pre-treatment at the factory wastewater treatment plant. The photodegradation process was studied by evaluating the changes in concentration employing UV–vis spectrophotometer (UV–vis) and total organic carbon (TOC) analysis. The photoelectrochemical degradation of mixed dye was found to follow the Langmuir Hinshelwood pseudo-first order kinetic while pseudo-second order kinetic model for effluents by using TOC analyses. The chemical oxygen demand (COD) and biochemical oxygen demand (BOD) values of mixed dye and raw effluents were reported. Photoelectrochemical characteristic of pollutants was studied using the cyclic voltammetry technique. Raw effluent was found to exhibit stronger reduction behaviour at cathodic bias potential but slightly less photoresponse at anodic bias than mixed dye. Elsevier 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/7661/1/Electrochemical-assisted%20photodegradation%20of%20mixed%20dye%20and%20textile%20effluents%20using%20TiO2%20thin%20films.pdf Zainal, Zulkarnain and Hussein, Mohd Zobir and Kassim, Anuar and Yusof, Nor Azah and Chong, Yong Lee (2007) Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films. Journal of Hazardous Materials, 146 (1-2). pp. 73-80. ISSN 0304-3894 http://dx.doi.org/10.1016/j.jhazmat.2006.11.055 10.1016/j.jhazmat.2006.11.055 English
spellingShingle Zainal, Zulkarnain
Hussein, Mohd Zobir
Kassim, Anuar
Yusof, Nor Azah
Chong, Yong Lee
Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films
title Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films
title_full Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films
title_fullStr Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films
title_full_unstemmed Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films
title_short Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films
title_sort electrochemical-assisted photodegradation of mixed dye and textile effluents using tio2 thin films
url http://psasir.upm.edu.my/id/eprint/7661/
http://psasir.upm.edu.my/id/eprint/7661/
http://psasir.upm.edu.my/id/eprint/7661/
http://psasir.upm.edu.my/id/eprint/7661/1/Electrochemical-assisted%20photodegradation%20of%20mixed%20dye%20and%20textile%20effluents%20using%20TiO2%20thin%20films.pdf