Semisynthesis and in vitro anticancer activities of andrographolide analogues

The plant Andrographis paniculata found throughout Southeast Asia contains Andrographolide 1, a diterpenoid lactone, which has antitumour activities against in vitro and in vivo breast cancer models. In the present study, we report on the synthesis of andrographolide derivatives, 3,19-isopropylidene...

Full description

Bibliographic Details
Main Authors: Jada, Srinivasa Rao, Subur, Genevieve Suseno, Matthews, Charlie, Hamzah, Ahmad Sazali, Lajis, Md Nordin, Saad, Mohammad Said, Stevens, M. F. G., Stanslas, Johnson
Format: Article
Language:English
English
Published: Elsevier 2007
Online Access:http://psasir.upm.edu.my/id/eprint/7522/
http://psasir.upm.edu.my/id/eprint/7522/1/Semisynthesis%20and%20in%20vitro%20anticancer%20activities%20of%20andrographolide%20analogues.pdf
_version_ 1848840618213638144
author Jada, Srinivasa Rao
Subur, Genevieve Suseno
Matthews, Charlie
Hamzah, Ahmad Sazali
Lajis, Md Nordin
Saad, Mohammad Said
Stevens, M. F. G.
Stanslas, Johnson
author_facet Jada, Srinivasa Rao
Subur, Genevieve Suseno
Matthews, Charlie
Hamzah, Ahmad Sazali
Lajis, Md Nordin
Saad, Mohammad Said
Stevens, M. F. G.
Stanslas, Johnson
author_sort Jada, Srinivasa Rao
building UPM Institutional Repository
collection Online Access
description The plant Andrographis paniculata found throughout Southeast Asia contains Andrographolide 1, a diterpenoid lactone, which has antitumour activities against in vitro and in vivo breast cancer models. In the present study, we report on the synthesis of andrographolide derivatives, 3,19-isopropylideneandrographolide (2), 14-acetyl-3,19-isopropylideneandrographolide (3) and 14-acetylandrographolide (4), and their in vitro antitumour activities against a 2-cell line panel consisting of MCF-7 (breast cancer cell line) and HCT-116 (colon cancer cell line). Compounds 2 and 4 were also screened at the US National Cancer Institute (NCI) for their activities against a panel of 60 human cancer cell lines derived from nine cancer types. Compound 2 was found to be selective towards leukaemia and colon cancer cells, and compound 4 was selective towards leukaemia, ovarian and renal cancer cells at all the dose-response parameters. Compounds 2 and 4 showed non-specific phase of the cell cycle arrest in MCF-7 cells treated at different intervals with different concentrations. NCI’s COMPARE and SOM mechanistic analyses indicated that the anticancer activities of these new class of compounds were not similar to that of standard anticancer agents, suggesting novel mechanism(s) of action.
first_indexed 2025-11-15T07:30:12Z
format Article
id upm-7522
institution Universiti Putra Malaysia
institution_category Local University
language English
English
last_indexed 2025-11-15T07:30:12Z
publishDate 2007
publisher Elsevier
recordtype eprints
repository_type Digital Repository
spelling upm-75222015-10-20T04:07:16Z http://psasir.upm.edu.my/id/eprint/7522/ Semisynthesis and in vitro anticancer activities of andrographolide analogues Jada, Srinivasa Rao Subur, Genevieve Suseno Matthews, Charlie Hamzah, Ahmad Sazali Lajis, Md Nordin Saad, Mohammad Said Stevens, M. F. G. Stanslas, Johnson The plant Andrographis paniculata found throughout Southeast Asia contains Andrographolide 1, a diterpenoid lactone, which has antitumour activities against in vitro and in vivo breast cancer models. In the present study, we report on the synthesis of andrographolide derivatives, 3,19-isopropylideneandrographolide (2), 14-acetyl-3,19-isopropylideneandrographolide (3) and 14-acetylandrographolide (4), and their in vitro antitumour activities against a 2-cell line panel consisting of MCF-7 (breast cancer cell line) and HCT-116 (colon cancer cell line). Compounds 2 and 4 were also screened at the US National Cancer Institute (NCI) for their activities against a panel of 60 human cancer cell lines derived from nine cancer types. Compound 2 was found to be selective towards leukaemia and colon cancer cells, and compound 4 was selective towards leukaemia, ovarian and renal cancer cells at all the dose-response parameters. Compounds 2 and 4 showed non-specific phase of the cell cycle arrest in MCF-7 cells treated at different intervals with different concentrations. NCI’s COMPARE and SOM mechanistic analyses indicated that the anticancer activities of these new class of compounds were not similar to that of standard anticancer agents, suggesting novel mechanism(s) of action. Elsevier 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/7522/1/Semisynthesis%20and%20in%20vitro%20anticancer%20activities%20of%20andrographolide%20analogues.pdf Jada, Srinivasa Rao and Subur, Genevieve Suseno and Matthews, Charlie and Hamzah, Ahmad Sazali and Lajis, Md Nordin and Saad, Mohammad Said and Stevens, M. F. G. and Stanslas, Johnson (2007) Semisynthesis and in vitro anticancer activities of andrographolide analogues. Phytochemistry, 68 (6). pp. 904-912. ISSN 0031-9422 http://dx.doi.org/10.1016/j.phytochem.2006.11.031 10.1016/j.phytochem.2006.11.031 English
spellingShingle Jada, Srinivasa Rao
Subur, Genevieve Suseno
Matthews, Charlie
Hamzah, Ahmad Sazali
Lajis, Md Nordin
Saad, Mohammad Said
Stevens, M. F. G.
Stanslas, Johnson
Semisynthesis and in vitro anticancer activities of andrographolide analogues
title Semisynthesis and in vitro anticancer activities of andrographolide analogues
title_full Semisynthesis and in vitro anticancer activities of andrographolide analogues
title_fullStr Semisynthesis and in vitro anticancer activities of andrographolide analogues
title_full_unstemmed Semisynthesis and in vitro anticancer activities of andrographolide analogues
title_short Semisynthesis and in vitro anticancer activities of andrographolide analogues
title_sort semisynthesis and in vitro anticancer activities of andrographolide analogues
url http://psasir.upm.edu.my/id/eprint/7522/
http://psasir.upm.edu.my/id/eprint/7522/
http://psasir.upm.edu.my/id/eprint/7522/
http://psasir.upm.edu.my/id/eprint/7522/1/Semisynthesis%20and%20in%20vitro%20anticancer%20activities%20of%20andrographolide%20analogues.pdf