2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate
The molecules in the crystal structure of the title compound,C19H17N3S2, are linked by an intermolecular N—H N [2.839 (5) A ° ] hydrogen bond via the -N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C—N bond but adopts a cis...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/7518/ http://psasir.upm.edu.my/id/eprint/7518/1/2-Naphthylmethyl_N-%5B1-%284-pyridyl%29ethylidene%5D.pdf |
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| author | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_facet | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_sort | How, Fiona Ni Foong |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The molecules in the crystal structure of the title compound,C19H17N3S2, are linked by an intermolecular N—H N [2.839 (5) A ° ] hydrogen bond via the -N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C—N bond but adopts a cis position with respect to the naphthalene ring across the C—S bond. There is a – stacking interaction between the naphthalene rings, with a centroid–centroid distance of 3.397 (2) A ° . |
| first_indexed | 2025-11-15T07:30:11Z |
| format | Article |
| id | upm-7518 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T07:30:11Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-75182013-05-27T07:35:22Z http://psasir.upm.edu.my/id/eprint/7518/ 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim The molecules in the crystal structure of the title compound,C19H17N3S2, are linked by an intermolecular N—H N [2.839 (5) A ° ] hydrogen bond via the -N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C—N bond but adopts a cis position with respect to the naphthalene ring across the C—S bond. There is a – stacking interaction between the naphthalene rings, with a centroid–centroid distance of 3.397 (2) A ° . International Union of Crystallography 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/7518/1/2-Naphthylmethyl_N-%5B1-%284-pyridyl%29ethylidene%5D.pdf How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 63 (7). pp. 3135-3136. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536807025652 10.1107/S1600536807025652 English |
| spellingShingle | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate |
| title | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate |
| title_full | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate |
| title_fullStr | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate |
| title_full_unstemmed | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate |
| title_short | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate |
| title_sort | 2-naphthylmethyl n-[1-(4-pyridyl)ethylidene hydrazinecarbodithioate |
| url | http://psasir.upm.edu.my/id/eprint/7518/ http://psasir.upm.edu.my/id/eprint/7518/ http://psasir.upm.edu.my/id/eprint/7518/ http://psasir.upm.edu.my/id/eprint/7518/1/2-Naphthylmethyl_N-%5B1-%284-pyridyl%29ethylidene%5D.pdf |