Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation

Titanium dioxide (TiO2) nanoparticles and TiO2 with recycled graphite (TiO2/G) nanocomposite have been successfully synthesized by alkaline fusion method using synthetic rutile for measuring the degradation time of the cigarette smoke under the visible light irradiation. In this work, the synthetic...

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Main Authors: Rosli, Natrah Shafiqah, Che Abdullah, Che Azurahanim, Hazan, Roshasnorlyza
Format: Article
Language:English
Published: Elsevier 2018
Online Access:http://psasir.upm.edu.my/id/eprint/74069/
http://psasir.upm.edu.my/id/eprint/74069/1/Synthesis%2C%20characterization%20and%20investigation%20of%20photocatalytic%20activity%20of%20nano-titania%20from%20natural%20ilmenite%20with%20graphite%20for%20cigarette%20smoke%20degradation.pdf
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author Rosli, Natrah Shafiqah
Che Abdullah, Che Azurahanim
Hazan, Roshasnorlyza
author_facet Rosli, Natrah Shafiqah
Che Abdullah, Che Azurahanim
Hazan, Roshasnorlyza
author_sort Rosli, Natrah Shafiqah
building UPM Institutional Repository
collection Online Access
description Titanium dioxide (TiO2) nanoparticles and TiO2 with recycled graphite (TiO2/G) nanocomposite have been successfully synthesized by alkaline fusion method using synthetic rutile for measuring the degradation time of the cigarette smoke under the visible light irradiation. In this work, the synthetic rutile was derived from natural Malaysian Ilmenite’s waste to produce a low cost of TiO2 nanoparticles via environmental friendly process. The prepared samples were then analyzed using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and Energy Dispersive X-Ray Fluorescence (EDXRF) to study their structural phase composition, functional group, and elemental composition respectively. The surface morphology and the size of the particles were studied using Field Emission Scanning Electron Microscopy (FESEM) and Particle Size Analyzer (PSA), respectively. The functionality of the prepared nanoparticles in terms of photocatalyst activity was analyzed by degradation of cigarette smoke under the exposure to the visible light. The UV–Vis Spectroscopy (UV–VIS) results revealed that the energy band gap of modified TiO2/G nanocomposite decreases to 2.90 eV compared with the commercial TiO2, 3.06 eV. This is capable enough to TiO2/G nanocomposite degrade the smoke under the visible light irradiation for 2 min faster compared to others types of TiO2 nanoparticles. This indicated the material has the ability to purify the toxins in the air.
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spelling upm-740692020-04-28T19:01:43Z http://psasir.upm.edu.my/id/eprint/74069/ Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation Rosli, Natrah Shafiqah Che Abdullah, Che Azurahanim Hazan, Roshasnorlyza Titanium dioxide (TiO2) nanoparticles and TiO2 with recycled graphite (TiO2/G) nanocomposite have been successfully synthesized by alkaline fusion method using synthetic rutile for measuring the degradation time of the cigarette smoke under the visible light irradiation. In this work, the synthetic rutile was derived from natural Malaysian Ilmenite’s waste to produce a low cost of TiO2 nanoparticles via environmental friendly process. The prepared samples were then analyzed using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and Energy Dispersive X-Ray Fluorescence (EDXRF) to study their structural phase composition, functional group, and elemental composition respectively. The surface morphology and the size of the particles were studied using Field Emission Scanning Electron Microscopy (FESEM) and Particle Size Analyzer (PSA), respectively. The functionality of the prepared nanoparticles in terms of photocatalyst activity was analyzed by degradation of cigarette smoke under the exposure to the visible light. The UV–Vis Spectroscopy (UV–VIS) results revealed that the energy band gap of modified TiO2/G nanocomposite decreases to 2.90 eV compared with the commercial TiO2, 3.06 eV. This is capable enough to TiO2/G nanocomposite degrade the smoke under the visible light irradiation for 2 min faster compared to others types of TiO2 nanoparticles. This indicated the material has the ability to purify the toxins in the air. Elsevier 2018 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/74069/1/Synthesis%2C%20characterization%20and%20investigation%20of%20photocatalytic%20activity%20of%20nano-titania%20from%20natural%20ilmenite%20with%20graphite%20for%20cigarette%20smoke%20degradation.pdf Rosli, Natrah Shafiqah and Che Abdullah, Che Azurahanim and Hazan, Roshasnorlyza (2018) Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation. Results in Physics, 11. 72 - 78. ISSN ESSN: 2211-3797 10.1016/j.rinp.2018.08.032
spellingShingle Rosli, Natrah Shafiqah
Che Abdullah, Che Azurahanim
Hazan, Roshasnorlyza
Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation
title Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation
title_full Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation
title_fullStr Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation
title_full_unstemmed Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation
title_short Synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation
title_sort synthesis, characterization and investigation of photocatalytic activity of nano-titania from natural ilmenite with graphite for cigarette smoke degradation
url http://psasir.upm.edu.my/id/eprint/74069/
http://psasir.upm.edu.my/id/eprint/74069/
http://psasir.upm.edu.my/id/eprint/74069/1/Synthesis%2C%20characterization%20and%20investigation%20of%20photocatalytic%20activity%20of%20nano-titania%20from%20natural%20ilmenite%20with%20graphite%20for%20cigarette%20smoke%20degradation.pdf