Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties
Polyurethane acrylate (PUA) from vegetable oil has been synthesized and prepared for solid polymer electrolyte. Polyol has been end-capped with Toluene 2,4-Diisocyanate (TDI) followed by hydroxylethylmethylacrylate (HEMA) in a urethanation process to produce PUA. The mixtures were cured to make thin...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI
2018
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| Online Access: | http://psasir.upm.edu.my/id/eprint/72582/ http://psasir.upm.edu.my/id/eprint/72582/1/Enhancement%20of%20plasticizing%20effect%20on%20bio-based%20polyurethane%20acrylate%20solid%20polymer%20electrolyte%20and%20its%20properties.pdf |
| _version_ | 1848857154917761024 |
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| author | Tuan Naiwi, Tuan Syarifah Rossyidah Aung, Min Min Ahmad, Azizan Rayung, Marwah Su'ait, Mohd Sukor Yusof, Nor Azah Lae, Khine Zar Wynn |
| author_facet | Tuan Naiwi, Tuan Syarifah Rossyidah Aung, Min Min Ahmad, Azizan Rayung, Marwah Su'ait, Mohd Sukor Yusof, Nor Azah Lae, Khine Zar Wynn |
| author_sort | Tuan Naiwi, Tuan Syarifah Rossyidah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Polyurethane acrylate (PUA) from vegetable oil has been synthesized and prepared for solid polymer electrolyte. Polyol has been end-capped with Toluene 2,4-Diisocyanate (TDI) followed by hydroxylethylmethylacrylate (HEMA) in a urethanation process to produce PUA. The mixtures were cured to make thin polymeric films under UV radiation to produce excellent cured films which exhibit good thermal stability and obtain high ionic conductivity value. 3 to 15 wt. % of ethylene carbonate (EC) mixed with 25 wt. % LiClO4 was added to PUA to obtain PUA electrolyte systems. PUA modified with plasticizer EC 9 wt. % achieved the highest conductivity of 7.86 × 10−4 S/cm, and relatively improved the linear sweep voltammetry, transference number and dielectric properties. Fourier Transform Infrared Spectroscopy (FTIR) and dielectric analysis were presented. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), followed by X-ray Diffraction (XRD) and morphology have been studied. The addition of plasticizer to the polyurethane acrylate shows significant improvement in terms of the conductivity and performance of the polymer electrolyte. |
| first_indexed | 2025-11-15T11:53:03Z |
| format | Article |
| id | upm-72582 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T11:53:03Z |
| publishDate | 2018 |
| publisher | MDPI |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-725822020-11-05T02:49:08Z http://psasir.upm.edu.my/id/eprint/72582/ Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties Tuan Naiwi, Tuan Syarifah Rossyidah Aung, Min Min Ahmad, Azizan Rayung, Marwah Su'ait, Mohd Sukor Yusof, Nor Azah Lae, Khine Zar Wynn Polyurethane acrylate (PUA) from vegetable oil has been synthesized and prepared for solid polymer electrolyte. Polyol has been end-capped with Toluene 2,4-Diisocyanate (TDI) followed by hydroxylethylmethylacrylate (HEMA) in a urethanation process to produce PUA. The mixtures were cured to make thin polymeric films under UV radiation to produce excellent cured films which exhibit good thermal stability and obtain high ionic conductivity value. 3 to 15 wt. % of ethylene carbonate (EC) mixed with 25 wt. % LiClO4 was added to PUA to obtain PUA electrolyte systems. PUA modified with plasticizer EC 9 wt. % achieved the highest conductivity of 7.86 × 10−4 S/cm, and relatively improved the linear sweep voltammetry, transference number and dielectric properties. Fourier Transform Infrared Spectroscopy (FTIR) and dielectric analysis were presented. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), followed by X-ray Diffraction (XRD) and morphology have been studied. The addition of plasticizer to the polyurethane acrylate shows significant improvement in terms of the conductivity and performance of the polymer electrolyte. MDPI 2018 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/72582/1/Enhancement%20of%20plasticizing%20effect%20on%20bio-based%20polyurethane%20acrylate%20solid%20polymer%20electrolyte%20and%20its%20properties.pdf Tuan Naiwi, Tuan Syarifah Rossyidah and Aung, Min Min and Ahmad, Azizan and Rayung, Marwah and Su'ait, Mohd Sukor and Yusof, Nor Azah and Lae, Khine Zar Wynn (2018) Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties. Polymers, 10 (10). pp. 1-19. ISSN 2073-4360 https://www.mdpi.com/2073-4360/10/10/1142 10.3390/polym10101142 |
| spellingShingle | Tuan Naiwi, Tuan Syarifah Rossyidah Aung, Min Min Ahmad, Azizan Rayung, Marwah Su'ait, Mohd Sukor Yusof, Nor Azah Lae, Khine Zar Wynn Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties |
| title | Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties |
| title_full | Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties |
| title_fullStr | Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties |
| title_full_unstemmed | Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties |
| title_short | Enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties |
| title_sort | enhancement of plasticizing effect on bio-based polyurethane acrylate solid polymer electrolyte and its properties |
| url | http://psasir.upm.edu.my/id/eprint/72582/ http://psasir.upm.edu.my/id/eprint/72582/ http://psasir.upm.edu.my/id/eprint/72582/ http://psasir.upm.edu.my/id/eprint/72582/1/Enhancement%20of%20plasticizing%20effect%20on%20bio-based%20polyurethane%20acrylate%20solid%20polymer%20electrolyte%20and%20its%20properties.pdf |