Effect of molecular structure on oxidative degradation of polyol ester

An experimental investigation was conducted to explore the thermal and heat flow characteristics of polyol esters with different molecular structures by using simultaneous thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) measurement. A significant difference in onset te...

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Main Authors: Abdul Raof, Nurliyana, Yunus, Robiah, Rashid, Umer, Azis, Norhafiz
Format: Conference or Workshop Item
Language:English
Published: Malaysian Tribology Society 2018
Online Access:http://psasir.upm.edu.my/id/eprint/71529/
http://psasir.upm.edu.my/id/eprint/71529/1/Asiatrib%202018-2.pdf
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author Abdul Raof, Nurliyana
Yunus, Robiah
Rashid, Umer
Azis, Norhafiz
author_facet Abdul Raof, Nurliyana
Yunus, Robiah
Rashid, Umer
Azis, Norhafiz
author_sort Abdul Raof, Nurliyana
building UPM Institutional Repository
collection Online Access
description An experimental investigation was conducted to explore the thermal and heat flow characteristics of polyol esters with different molecular structures by using simultaneous thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) measurement. A significant difference in onset temperature between the developed esters and mineral oil was observed. The comparison of oxidative stability of polyol esters and mineral transformer oil revealed that polyol esters are oxidatively stable up to >370°C while for mineral oil it was <300°C. As oxidative degradation starts at a lower temperature than thermal degradation, determination of oxidative stability is more important to study the potential the ester to be used as dielectric fluid.
first_indexed 2025-11-15T11:50:37Z
format Conference or Workshop Item
id upm-71529
institution Universiti Putra Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T11:50:37Z
publishDate 2018
publisher Malaysian Tribology Society
recordtype eprints
repository_type Digital Repository
spelling upm-715292019-10-04T08:33:36Z http://psasir.upm.edu.my/id/eprint/71529/ Effect of molecular structure on oxidative degradation of polyol ester Abdul Raof, Nurliyana Yunus, Robiah Rashid, Umer Azis, Norhafiz An experimental investigation was conducted to explore the thermal and heat flow characteristics of polyol esters with different molecular structures by using simultaneous thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) measurement. A significant difference in onset temperature between the developed esters and mineral oil was observed. The comparison of oxidative stability of polyol esters and mineral transformer oil revealed that polyol esters are oxidatively stable up to >370°C while for mineral oil it was <300°C. As oxidative degradation starts at a lower temperature than thermal degradation, determination of oxidative stability is more important to study the potential the ester to be used as dielectric fluid. Malaysian Tribology Society 2018 Conference or Workshop Item PeerReviewed text en http://psasir.upm.edu.my/id/eprint/71529/1/Asiatrib%202018-2.pdf Abdul Raof, Nurliyana and Yunus, Robiah and Rashid, Umer and Azis, Norhafiz (2018) Effect of molecular structure on oxidative degradation of polyol ester. In: Asia International Conference on Tribology 2018 (ASIATRIB 2018), 17-20 Sept. 2018, Kuching, Sarawak, Malaysia. (pp. 353-354).
spellingShingle Abdul Raof, Nurliyana
Yunus, Robiah
Rashid, Umer
Azis, Norhafiz
Effect of molecular structure on oxidative degradation of polyol ester
title Effect of molecular structure on oxidative degradation of polyol ester
title_full Effect of molecular structure on oxidative degradation of polyol ester
title_fullStr Effect of molecular structure on oxidative degradation of polyol ester
title_full_unstemmed Effect of molecular structure on oxidative degradation of polyol ester
title_short Effect of molecular structure on oxidative degradation of polyol ester
title_sort effect of molecular structure on oxidative degradation of polyol ester
url http://psasir.upm.edu.my/id/eprint/71529/
http://psasir.upm.edu.my/id/eprint/71529/1/Asiatrib%202018-2.pdf