The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase

In this work, the synthesis of MgB2 by reaction between MgB4 and Mg has been investigated. The MgB4 powders were initially acid-washed in order to eliminate mainly as well as other impurities. Later, an appropriate amount of Mg was added for reaction at temperature range from 650°C to 950°C for 4 ho...

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Main Authors: Tan, Kim Lee, Tan, Kwee Yong, Chen, Soo Kien, Shaari, Abdul Halim, Lim, Kean Pah
Format: Conference or Workshop Item
Language:English
Published: Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia 2010
Online Access:http://psasir.upm.edu.my/id/eprint/64970/
http://psasir.upm.edu.my/id/eprint/64970/1/2010-4.pdf
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author Tan, Kim Lee
Tan, Kwee Yong
Chen, Soo Kien
Shaari, Abdul Halim
Lim, Kean Pah
author_facet Tan, Kim Lee
Tan, Kwee Yong
Chen, Soo Kien
Shaari, Abdul Halim
Lim, Kean Pah
author_sort Tan, Kim Lee
building UPM Institutional Repository
collection Online Access
description In this work, the synthesis of MgB2 by reaction between MgB4 and Mg has been investigated. The MgB4 powders were initially acid-washed in order to eliminate mainly as well as other impurities. Later, an appropriate amount of Mg was added for reaction at temperature range from 650°C to 950°C for 4 hours. The samples were characterized by x-ray diffraction (XRD), scanning electron microscope (SEM) and SQUID magnetometer (MPMS). Results from XRD showed the dominant phase of MgB2 with some impurities of MgB4 and MgO in all samples. The scanning electron micrographs showed denser microstructures compared to samples obtained by direct in-situ reaction of Mg and B. However, the measured physical density was decreased upon increasing the sintering temperature attributed to the loss of Mg. The superconducting transition temperature, Tc at 37.2K was found to improve at lower sintering temperature.
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format Conference or Workshop Item
id upm-64970
institution Universiti Putra Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T11:21:14Z
publishDate 2010
publisher Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia
recordtype eprints
repository_type Digital Repository
spelling upm-649702018-09-03T04:16:14Z http://psasir.upm.edu.my/id/eprint/64970/ The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase Tan, Kim Lee Tan, Kwee Yong Chen, Soo Kien Shaari, Abdul Halim Lim, Kean Pah In this work, the synthesis of MgB2 by reaction between MgB4 and Mg has been investigated. The MgB4 powders were initially acid-washed in order to eliminate mainly as well as other impurities. Later, an appropriate amount of Mg was added for reaction at temperature range from 650°C to 950°C for 4 hours. The samples were characterized by x-ray diffraction (XRD), scanning electron microscope (SEM) and SQUID magnetometer (MPMS). Results from XRD showed the dominant phase of MgB2 with some impurities of MgB4 and MgO in all samples. The scanning electron micrographs showed denser microstructures compared to samples obtained by direct in-situ reaction of Mg and B. However, the measured physical density was decreased upon increasing the sintering temperature attributed to the loss of Mg. The superconducting transition temperature, Tc at 37.2K was found to improve at lower sintering temperature. Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia 2010 Conference or Workshop Item PeerReviewed text en http://psasir.upm.edu.my/id/eprint/64970/1/2010-4.pdf Tan, Kim Lee and Tan, Kwee Yong and Chen, Soo Kien and Shaari, Abdul Halim and Lim, Kean Pah (2010) The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase. In: Regional Annual Fundamental Science Symposium 2010 (RAFSS 2010), 8-9 June 2010, Grand Season Hotel, Kuala Lumpur. (pp. 161-167).
spellingShingle Tan, Kim Lee
Tan, Kwee Yong
Chen, Soo Kien
Shaari, Abdul Halim
Lim, Kean Pah
The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase
title The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase
title_full The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase
title_fullStr The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase
title_full_unstemmed The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase
title_short The superconducting properties of MgB2 synthesized by reaction of Mg and higher boride phase
title_sort superconducting properties of mgb2 synthesized by reaction of mg and higher boride phase
url http://psasir.upm.edu.my/id/eprint/64970/
http://psasir.upm.edu.my/id/eprint/64970/1/2010-4.pdf