Synthesis of BaTiO3 nanoparticles via hydrothermal method

In this work, BaTiO3 nanoparticles were synthesized through hydrothermal method. The powder obtained from the hydrothermal process (as-synthesized powder) was calcined at 1000 °C. The phase formation and morphology of the as-synthesized and calcined powders were studied using X-ray diffraction (XRD)...

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Main Authors: Hasbullah, Nurul Norfarina, Oon, Jew Lee, Liew, Josephine Ying Chyi, Soo, Kien Chen, Talib, Zainal Abidin
Format: Article
Language:English
Published: Trans Tech Publications 2017
Online Access:http://psasir.upm.edu.my/id/eprint/63362/
http://psasir.upm.edu.my/id/eprint/63362/1/Synthesis%20of%20BaTiO3%20nanoparticles%20via%20hydrothermal%20method.pdf
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author Hasbullah, Nurul Norfarina
Oon, Jew Lee
Liew, Josephine Ying Chyi
Soo, Kien Chen
Talib, Zainal Abidin
author_facet Hasbullah, Nurul Norfarina
Oon, Jew Lee
Liew, Josephine Ying Chyi
Soo, Kien Chen
Talib, Zainal Abidin
author_sort Hasbullah, Nurul Norfarina
building UPM Institutional Repository
collection Online Access
description In this work, BaTiO3 nanoparticles were synthesized through hydrothermal method. The powder obtained from the hydrothermal process (as-synthesized powder) was calcined at 1000 °C. The phase formation and morphology of the as-synthesized and calcined powders were studied using X-ray diffraction (XRD), thermogravimetric (TGA) and differential scanning calorimetry (DSC) analyzer, and transmission electron microscope (TEM). The XRD data showed that the as-synthesized powder is partially amorphous. Upon calcining the powder at 1000 °C, highly crystalline BaTiO3 with tetragonal structure was obtained. As shown by TGA and DSC analysis, the precursor powder was completely transformed into BaTiO3 at 1000 °C. The presence of BaCO3 as an impurity phase in the powder is due to the lack of Ba2+ / Ti3+/4+. Transmission electron microscope images showed that the particle size of the as-synthesized powder increased after calcination due to crystal growth. In addition, nanocubes with the average size of around 11.66 nm were obtained as a result of the calcination compared to the ellipsoid like particles of the as-synthesized powder.
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spelling upm-633622018-10-16T00:31:09Z http://psasir.upm.edu.my/id/eprint/63362/ Synthesis of BaTiO3 nanoparticles via hydrothermal method Hasbullah, Nurul Norfarina Oon, Jew Lee Liew, Josephine Ying Chyi Soo, Kien Chen Talib, Zainal Abidin In this work, BaTiO3 nanoparticles were synthesized through hydrothermal method. The powder obtained from the hydrothermal process (as-synthesized powder) was calcined at 1000 °C. The phase formation and morphology of the as-synthesized and calcined powders were studied using X-ray diffraction (XRD), thermogravimetric (TGA) and differential scanning calorimetry (DSC) analyzer, and transmission electron microscope (TEM). The XRD data showed that the as-synthesized powder is partially amorphous. Upon calcining the powder at 1000 °C, highly crystalline BaTiO3 with tetragonal structure was obtained. As shown by TGA and DSC analysis, the precursor powder was completely transformed into BaTiO3 at 1000 °C. The presence of BaCO3 as an impurity phase in the powder is due to the lack of Ba2+ / Ti3+/4+. Transmission electron microscope images showed that the particle size of the as-synthesized powder increased after calcination due to crystal growth. In addition, nanocubes with the average size of around 11.66 nm were obtained as a result of the calcination compared to the ellipsoid like particles of the as-synthesized powder. Trans Tech Publications 2017-10 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/63362/1/Synthesis%20of%20BaTiO3%20nanoparticles%20via%20hydrothermal%20method.pdf Hasbullah, Nurul Norfarina and Oon, Jew Lee and Liew, Josephine Ying Chyi and Soo, Kien Chen and Talib, Zainal Abidin (2017) Synthesis of BaTiO3 nanoparticles via hydrothermal method. Solid State Phenomena, 268. 172 - 176. ISSN 1012-0394; ESSN: 1662-9779 https://www.scientific.net/SSP.268.172
spellingShingle Hasbullah, Nurul Norfarina
Oon, Jew Lee
Liew, Josephine Ying Chyi
Soo, Kien Chen
Talib, Zainal Abidin
Synthesis of BaTiO3 nanoparticles via hydrothermal method
title Synthesis of BaTiO3 nanoparticles via hydrothermal method
title_full Synthesis of BaTiO3 nanoparticles via hydrothermal method
title_fullStr Synthesis of BaTiO3 nanoparticles via hydrothermal method
title_full_unstemmed Synthesis of BaTiO3 nanoparticles via hydrothermal method
title_short Synthesis of BaTiO3 nanoparticles via hydrothermal method
title_sort synthesis of batio3 nanoparticles via hydrothermal method
url http://psasir.upm.edu.my/id/eprint/63362/
http://psasir.upm.edu.my/id/eprint/63362/
http://psasir.upm.edu.my/id/eprint/63362/1/Synthesis%20of%20BaTiO3%20nanoparticles%20via%20hydrothermal%20method.pdf