Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors

In this work we investigated both structural and optical characteristic of erbium doped ternary TeO2-TiO2-Bi2O3 tellurite oxide based glasses, synthesized via melt-quench method. The X-ray diffraction (XRD) and differential scanning calorimetry (DSC) confirmed its glassy nature and stability. Raman...

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Main Authors: Oon, Jew Lee, Hasbullah, Nurul Norfarina, Hui, San Lee, Soo, Kien Chen, Talib, Zainal Abidin
Format: Article
Language:English
Published: Penerbit Universiti Malaysia Terengganu 2017
Online Access:http://psasir.upm.edu.my/id/eprint/63301/
http://psasir.upm.edu.my/id/eprint/63301/1/Structural%20and%20luminescent%20diversities%20of%20Eu3%2B%20activated%20Gd2O3%20nanophosphors.pdf
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author Oon, Jew Lee
Hasbullah, Nurul Norfarina
Hui, San Lee
Soo, Kien Chen
Talib, Zainal Abidin
author_facet Oon, Jew Lee
Hasbullah, Nurul Norfarina
Hui, San Lee
Soo, Kien Chen
Talib, Zainal Abidin
author_sort Oon, Jew Lee
building UPM Institutional Repository
collection Online Access
description In this work we investigated both structural and optical characteristic of erbium doped ternary TeO2-TiO2-Bi2O3 tellurite oxide based glasses, synthesized via melt-quench method. The X-ray diffraction (XRD) and differential scanning calorimetry (DSC) confirmed its glassy nature and stability. Raman analysis revealed the presence of various coordination state TeO2 network consisting stretching/bending vibrations of Te-O bonds in the [TeO4] trigonal bi-pyramid units and fraction of [TeO3, TeO3+1] trigonal pyramids. From optical absorption measurement both optical band gap and Judd-Ofelt analysis (intensity parameters Ωt (t=2, 4, 6), transition probabilities, and radiative lifetimes of the Er3+ ions) have been performed for both host and doped glasses respectively. Photoluminescence studies for upconversion and near-infrared emissions analysis (under 980 nm excitation at room temperature. Both optical transition mechanism which involved nonradiative energy transfer between Er3+ ions through cross-relaxation and energy migration were also explained in detailed.
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spelling upm-633012018-10-15T03:01:59Z http://psasir.upm.edu.my/id/eprint/63301/ Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors Oon, Jew Lee Hasbullah, Nurul Norfarina Hui, San Lee Soo, Kien Chen Talib, Zainal Abidin In this work we investigated both structural and optical characteristic of erbium doped ternary TeO2-TiO2-Bi2O3 tellurite oxide based glasses, synthesized via melt-quench method. The X-ray diffraction (XRD) and differential scanning calorimetry (DSC) confirmed its glassy nature and stability. Raman analysis revealed the presence of various coordination state TeO2 network consisting stretching/bending vibrations of Te-O bonds in the [TeO4] trigonal bi-pyramid units and fraction of [TeO3, TeO3+1] trigonal pyramids. From optical absorption measurement both optical band gap and Judd-Ofelt analysis (intensity parameters Ωt (t=2, 4, 6), transition probabilities, and radiative lifetimes of the Er3+ ions) have been performed for both host and doped glasses respectively. Photoluminescence studies for upconversion and near-infrared emissions analysis (under 980 nm excitation at room temperature. Both optical transition mechanism which involved nonradiative energy transfer between Er3+ ions through cross-relaxation and energy migration were also explained in detailed. Penerbit Universiti Malaysia Terengganu 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/63301/1/Structural%20and%20luminescent%20diversities%20of%20Eu3%2B%20activated%20Gd2O3%20nanophosphors.pdf Oon, Jew Lee and Hasbullah, Nurul Norfarina and Hui, San Lee and Soo, Kien Chen and Talib, Zainal Abidin (2017) Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors. Journal of Sustainability Science and Management. 48 - 56. ISSN 1823-8556 http://jssm.umt.edu.my/wp-content/uploads/sites/51/2017/12/Chapter-7.pdf
spellingShingle Oon, Jew Lee
Hasbullah, Nurul Norfarina
Hui, San Lee
Soo, Kien Chen
Talib, Zainal Abidin
Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors
title Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors
title_full Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors
title_fullStr Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors
title_full_unstemmed Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors
title_short Structural and luminescent diversities of Eu3+ activated Gd2O3 nanophosphors
title_sort structural and luminescent diversities of eu3+ activated gd2o3 nanophosphors
url http://psasir.upm.edu.my/id/eprint/63301/
http://psasir.upm.edu.my/id/eprint/63301/
http://psasir.upm.edu.my/id/eprint/63301/1/Structural%20and%20luminescent%20diversities%20of%20Eu3%2B%20activated%20Gd2O3%20nanophosphors.pdf