Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent

This study aims to produce optimized biochar from oil palm empty fruit bunches (OPEFB), as a green, low cost adsorbent for uptake of zinc from aqueous solution. The impact of pyrolysis conditions, namely, highest treatment temperature (HTT), heating rate (HR), and residence time (RT) on biochar yiel...

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Main Authors: Zamani, Seyed Ali, Yunus, Robiah, Abd. Wahid, Samsuri, Mohd Salleh, Mohamad Amran, Asady, Bahareh
Format: Article
Language:English
Published: Hindawi Publishing Corporation 2017
Online Access:http://psasir.upm.edu.my/id/eprint/62956/
http://psasir.upm.edu.my/id/eprint/62956/1/Removal%20of%20Zinc%20from%20Aqueous%20Solution%20by%20Optimized%20Oil%20Palm%20Empty.pdf
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author Zamani, Seyed Ali
Yunus, Robiah
Abd. Wahid, Samsuri
Mohd Salleh, Mohamad Amran
Asady, Bahareh
author_facet Zamani, Seyed Ali
Yunus, Robiah
Abd. Wahid, Samsuri
Mohd Salleh, Mohamad Amran
Asady, Bahareh
author_sort Zamani, Seyed Ali
building UPM Institutional Repository
collection Online Access
description This study aims to produce optimized biochar from oil palm empty fruit bunches (OPEFB), as a green, low cost adsorbent for uptake of zinc from aqueous solution. The impact of pyrolysis conditions, namely, highest treatment temperature (HTT), heating rate (HR), and residence time (RT) on biochar yield and adsorption capacity towards zinc, was investigated. Mathematical modeling and optimization of independent variables were performed employing response surface methodology (RSM). HTT was found to be the most influential variable, followed by residence time and heating rate. Based on the central composite design (CCD), two quadratic models were developed to correlate three independent variables to responses. The optimum production condition for OPEFB biochar was found as follows: HTT of 615°C, HR of 8°C/min, and RT of 128 minutes. The optimum biochar showed 15.18 mg/g adsorption capacity for zinc and 25.49% of yield which was in agreement with the predicted values, satisfactory. Results of the characterization of optimum product illustrated well-developed BET surface area and porous structure in optimum product which favored its sorptive ability.
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spelling upm-629562019-11-04T08:15:23Z http://psasir.upm.edu.my/id/eprint/62956/ Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent Zamani, Seyed Ali Yunus, Robiah Abd. Wahid, Samsuri Mohd Salleh, Mohamad Amran Asady, Bahareh This study aims to produce optimized biochar from oil palm empty fruit bunches (OPEFB), as a green, low cost adsorbent for uptake of zinc from aqueous solution. The impact of pyrolysis conditions, namely, highest treatment temperature (HTT), heating rate (HR), and residence time (RT) on biochar yield and adsorption capacity towards zinc, was investigated. Mathematical modeling and optimization of independent variables were performed employing response surface methodology (RSM). HTT was found to be the most influential variable, followed by residence time and heating rate. Based on the central composite design (CCD), two quadratic models were developed to correlate three independent variables to responses. The optimum production condition for OPEFB biochar was found as follows: HTT of 615°C, HR of 8°C/min, and RT of 128 minutes. The optimum biochar showed 15.18 mg/g adsorption capacity for zinc and 25.49% of yield which was in agreement with the predicted values, satisfactory. Results of the characterization of optimum product illustrated well-developed BET surface area and porous structure in optimum product which favored its sorptive ability. Hindawi Publishing Corporation 2017-03-21 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/62956/1/Removal%20of%20Zinc%20from%20Aqueous%20Solution%20by%20Optimized%20Oil%20Palm%20Empty.pdf Zamani, Seyed Ali and Yunus, Robiah and Abd. Wahid, Samsuri and Mohd Salleh, Mohamad Amran and Asady, Bahareh (2017) Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent. Bioinorganic Chemistry and Applications, 2017. art. no. 7914714. pp. 1-9. ISSN 1565-3633; ESSN: 1687-479X https://www.hindawi.com/journals/bca/2017/7914714/ 10.1155/2017/7914714
spellingShingle Zamani, Seyed Ali
Yunus, Robiah
Abd. Wahid, Samsuri
Mohd Salleh, Mohamad Amran
Asady, Bahareh
Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent
title Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent
title_full Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent
title_fullStr Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent
title_full_unstemmed Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent
title_short Removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent
title_sort removal of zinc from aqueous solution by optimized oil palm empty fruit bunches biochar as low cost adsorbent
url http://psasir.upm.edu.my/id/eprint/62956/
http://psasir.upm.edu.my/id/eprint/62956/
http://psasir.upm.edu.my/id/eprint/62956/
http://psasir.upm.edu.my/id/eprint/62956/1/Removal%20of%20Zinc%20from%20Aqueous%20Solution%20by%20Optimized%20Oil%20Palm%20Empty.pdf