Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method
The intercalation of chloroacetic acid (CAA) into the interlayer gallery of zinc layered hydroxide has been achieved via a facile direct reaction method. The nanohybrid synthesised, zinc layered hydroxide-chloroacetate was characterised using Powder X-ray diffraction patterns (PXRD), which demonstra...
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| Format: | Article |
| Language: | English |
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Taylor & Francis
2016
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| Online Access: | http://psasir.upm.edu.my/id/eprint/62831/ http://psasir.upm.edu.my/id/eprint/62831/1/Preparation%20of%20zinc%20layered%20.pdf |
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| author | Hashim, Norhayati Muda, Zuhailimuna Mohd Sharif, Sharifah Norain Md Isa, Illyas Mohd Ali, Noorshida Ghazuli, Mohammad Rafaei Hussein, Mohd Zobir |
| author_facet | Hashim, Norhayati Muda, Zuhailimuna Mohd Sharif, Sharifah Norain Md Isa, Illyas Mohd Ali, Noorshida Ghazuli, Mohammad Rafaei Hussein, Mohd Zobir |
| author_sort | Hashim, Norhayati |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The intercalation of chloroacetic acid (CAA) into the interlayer gallery of zinc layered hydroxide has been achieved via a facile direct reaction method. The nanohybrid synthesised, zinc layered hydroxide-chloroacetate was characterised using Powder X-ray diffraction patterns (PXRD), which demonstrated the progressive evolution of the nanohybrid structure, as the CAA molarity were increased from 0.05 to 0.3 M. Sharp and symmetrical peaks of 0.3 M CAA were observed in the PXRD pattern. The emergence of intercalation peak, with basal spacing of 14.3 Å signifying the success intercalation of chloroacetate anions into the interlayer space of the host. The intercalation was also validated by FTIR spectroscopy and CHNS elemental analyser. The increased thermal stability of zinc layered hydroxide-chloroacetate nanohybrid was confirmed by thermogravimetric analysis. |
| first_indexed | 2025-11-15T11:13:37Z |
| format | Article |
| id | upm-62831 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T11:13:37Z |
| publishDate | 2016 |
| publisher | Taylor & Francis |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-628312022-11-10T04:04:54Z http://psasir.upm.edu.my/id/eprint/62831/ Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method Hashim, Norhayati Muda, Zuhailimuna Mohd Sharif, Sharifah Norain Md Isa, Illyas Mohd Ali, Noorshida Ghazuli, Mohammad Rafaei Hussein, Mohd Zobir The intercalation of chloroacetic acid (CAA) into the interlayer gallery of zinc layered hydroxide has been achieved via a facile direct reaction method. The nanohybrid synthesised, zinc layered hydroxide-chloroacetate was characterised using Powder X-ray diffraction patterns (PXRD), which demonstrated the progressive evolution of the nanohybrid structure, as the CAA molarity were increased from 0.05 to 0.3 M. Sharp and symmetrical peaks of 0.3 M CAA were observed in the PXRD pattern. The emergence of intercalation peak, with basal spacing of 14.3 Å signifying the success intercalation of chloroacetate anions into the interlayer space of the host. The intercalation was also validated by FTIR spectroscopy and CHNS elemental analyser. The increased thermal stability of zinc layered hydroxide-chloroacetate nanohybrid was confirmed by thermogravimetric analysis. Taylor & Francis 2016-12 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/62831/1/Preparation%20of%20zinc%20layered%20.pdf Hashim, Norhayati and Muda, Zuhailimuna and Mohd Sharif, Sharifah Norain and Md Isa, Illyas and Mohd Ali, Noorshida and Ghazuli, Mohammad Rafaei and Hussein, Mohd Zobir (2016) Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method. Materials Research Innovations, 21 (6). 396 - 400. ISSN 1433-075X https://www.tandfonline.com/doi/full/10.1080/14328917.2016.1265248 10.1080/14328917.2016.1265248 |
| spellingShingle | Hashim, Norhayati Muda, Zuhailimuna Mohd Sharif, Sharifah Norain Md Isa, Illyas Mohd Ali, Noorshida Ghazuli, Mohammad Rafaei Hussein, Mohd Zobir Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method |
| title | Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method |
| title_full | Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method |
| title_fullStr | Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method |
| title_full_unstemmed | Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method |
| title_short | Preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method |
| title_sort | preparation of zinc layered hydroxide–chloroacetate nanohybrid using direct reaction method |
| url | http://psasir.upm.edu.my/id/eprint/62831/ http://psasir.upm.edu.my/id/eprint/62831/ http://psasir.upm.edu.my/id/eprint/62831/ http://psasir.upm.edu.my/id/eprint/62831/1/Preparation%20of%20zinc%20layered%20.pdf |