Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel
Polyacrylonitrile (PAN) based gel polymer electrolytes (GPE) were prepared using lithium iodide (LiI), 1-butyl-3-methylimidazolium iodide (BMII) and tetrapropyl ammonium iodide (TPAI). The LiI mass fraction in the electrolyte was varied while keeping the masses of other components constant in order...
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| Format: | Article |
| Language: | English |
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Elsevier
2017
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| Online Access: | http://psasir.upm.edu.my/id/eprint/62777/ http://psasir.upm.edu.my/id/eprint/62777/1/Polyacrylonitrile%20gel%20.pdf |
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| author | Mohd Arof, Abdul Kariem Mohd Noor, Ikhwan Syafiq Buraidah, Mohd Hamdi Bandara, T.M.W.J. Abdul Careem, Maqsood Ahamed Albinsson, I. Mellander, B.-E. |
| author_facet | Mohd Arof, Abdul Kariem Mohd Noor, Ikhwan Syafiq Buraidah, Mohd Hamdi Bandara, T.M.W.J. Abdul Careem, Maqsood Ahamed Albinsson, I. Mellander, B.-E. |
| author_sort | Mohd Arof, Abdul Kariem |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Polyacrylonitrile (PAN) based gel polymer electrolytes (GPE) were prepared using lithium iodide (LiI), 1-butyl-3-methylimidazolium iodide (BMII) and tetrapropyl ammonium iodide (TPAI). The LiI mass fraction in the electrolyte was varied while keeping the masses of other components constant in order to enhance the solar cell performance. The addition of 4.61 wt.% LiI in the GPE increased the electrolyte room temperature ionic conductivity from (2.32 ± 0.02) to (3.91 ± 0.04) mS cm−1. The increase in conductivity with the addition of LiI salts was attributed to the increase in diffusion coefficient, mobility and number density of charge carriers as determined from Nyquist plot fitting. The incorporation of LiI salts in PAN-based GPE has enhanced the efficiency of the DSSC as expected. The best cell performance was obtained with an electrolyte containing 4.61 wt.% LiI sandwiched between a single mesoporous layer of TiO2 soaked in N3 dye sensitizer and a platinum counter electrode, which showed a power conversion efficiency (PCE) of (5.4 ± 0.1) % with a short circuit current density (Jsc) of (21.0 ± 1.1) mA cm−2, an open circuit voltage (Voc) of (0.48 ± 0.02) V and a fill factor (FF) of (53.4 ± 0.9) %. The DSSCs with 4.61 wt.% of LiI have been used to fabricate prototype solar panels for operating small devices. The panels were assembled using a number of cells, each having an area of 2 cm × 2 cm, connected in series and parallel. The panel, consisting of a set of eight cells in series which was connected in parallel with another set of eight cells in series, produces an average power conversion efficiency of (3.7 ± 0.2)% with a maximum output power of (17.1 ± 0.9) mW. |
| first_indexed | 2025-11-15T11:13:27Z |
| format | Article |
| id | upm-62777 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T11:13:27Z |
| publishDate | 2017 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-627772022-11-08T07:16:43Z http://psasir.upm.edu.my/id/eprint/62777/ Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel Mohd Arof, Abdul Kariem Mohd Noor, Ikhwan Syafiq Buraidah, Mohd Hamdi Bandara, T.M.W.J. Abdul Careem, Maqsood Ahamed Albinsson, I. Mellander, B.-E. Polyacrylonitrile (PAN) based gel polymer electrolytes (GPE) were prepared using lithium iodide (LiI), 1-butyl-3-methylimidazolium iodide (BMII) and tetrapropyl ammonium iodide (TPAI). The LiI mass fraction in the electrolyte was varied while keeping the masses of other components constant in order to enhance the solar cell performance. The addition of 4.61 wt.% LiI in the GPE increased the electrolyte room temperature ionic conductivity from (2.32 ± 0.02) to (3.91 ± 0.04) mS cm−1. The increase in conductivity with the addition of LiI salts was attributed to the increase in diffusion coefficient, mobility and number density of charge carriers as determined from Nyquist plot fitting. The incorporation of LiI salts in PAN-based GPE has enhanced the efficiency of the DSSC as expected. The best cell performance was obtained with an electrolyte containing 4.61 wt.% LiI sandwiched between a single mesoporous layer of TiO2 soaked in N3 dye sensitizer and a platinum counter electrode, which showed a power conversion efficiency (PCE) of (5.4 ± 0.1) % with a short circuit current density (Jsc) of (21.0 ± 1.1) mA cm−2, an open circuit voltage (Voc) of (0.48 ± 0.02) V and a fill factor (FF) of (53.4 ± 0.9) %. The DSSCs with 4.61 wt.% of LiI have been used to fabricate prototype solar panels for operating small devices. The panels were assembled using a number of cells, each having an area of 2 cm × 2 cm, connected in series and parallel. The panel, consisting of a set of eight cells in series which was connected in parallel with another set of eight cells in series, produces an average power conversion efficiency of (3.7 ± 0.2)% with a maximum output power of (17.1 ± 0.9) mW. Elsevier 2017-10 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/62777/1/Polyacrylonitrile%20gel%20.pdf Mohd Arof, Abdul Kariem and Mohd Noor, Ikhwan Syafiq and Buraidah, Mohd Hamdi and Bandara, T.M.W.J. and Abdul Careem, Maqsood Ahamed and Albinsson, I. and Mellander, B.-E. (2017) Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel. Electrochimica Acta, 251. 223 - 234. ISSN 0013-4686 https://reader.elsevier.com/reader/sd/pii/S0013468617317838?token=15E1B66B6E90A45D858F858182277A6D8BE53A1A5FC1C339C441D143B0C24339FED83F9B86AA6B6A56C72580CFC9187C&originRegion=eu-west-1&originCreation=20220921070325 10.1016/j.electacta.2017.08.129 |
| spellingShingle | Mohd Arof, Abdul Kariem Mohd Noor, Ikhwan Syafiq Buraidah, Mohd Hamdi Bandara, T.M.W.J. Abdul Careem, Maqsood Ahamed Albinsson, I. Mellander, B.-E. Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel |
| title | Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel |
| title_full | Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel |
| title_fullStr | Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel |
| title_full_unstemmed | Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel |
| title_short | Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel |
| title_sort | polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel |
| url | http://psasir.upm.edu.my/id/eprint/62777/ http://psasir.upm.edu.my/id/eprint/62777/ http://psasir.upm.edu.my/id/eprint/62777/ http://psasir.upm.edu.my/id/eprint/62777/1/Polyacrylonitrile%20gel%20.pdf |