Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution

An abnormal grain growth of the ZnO-based ceramics due to highly reactive vanadium liquid phase disrupts its nonlinear properties. The effect of Nd2O3 concentration from 0.01 to 0.05 mol% on microstructure and electrical properties of ZnO-based varistor ceramics were investigated. The sample was fab...

Full description

Bibliographic Details
Main Authors: Azis, Raba'ah Syahidah, Zakaria, Azmi, Abdullah, W. R. W., Isa, N. H.
Format: Article
Language:English
Published: National Institute R and D of Materials Physics 2017
Online Access:http://psasir.upm.edu.my/id/eprint/62423/
http://psasir.upm.edu.my/id/eprint/62423/1/CERAMIC.pdf
_version_ 1848854624150224896
author Azis, Raba'ah Syahidah
Zakaria, Azmi
Abdullah, W. R. W.
Isa, N. H.
author_facet Azis, Raba'ah Syahidah
Zakaria, Azmi
Abdullah, W. R. W.
Isa, N. H.
author_sort Azis, Raba'ah Syahidah
building UPM Institutional Repository
collection Online Access
description An abnormal grain growth of the ZnO-based ceramics due to highly reactive vanadium liquid phase disrupts its nonlinear properties. The effect of Nd2O3 concentration from 0.01 to 0.05 mol% on microstructure and electrical properties of ZnO-based varistor ceramics were investigated. The sample was fabricated via solid state method and sintered at 900 °C for 2 h. XRD analysis shows the V2O5 and Zn2Nb2Mn2O9 phase formation. SEM analysis shows the grain is more uniform and enlarged to 3.54 μm with Nd2O3 addition up to 0.03 mol%. Nd2O3 also increased both the nonlinear coefficient α and the breakdown electric field, E1mA to an optimum of 9.94 and 75 V/mm. Beyond that concentration, oxygen O vacancy formed at the grain boundary and diminished the electrical properties.
first_indexed 2025-11-15T11:12:49Z
format Article
id upm-62423
institution Universiti Putra Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T11:12:49Z
publishDate 2017
publisher National Institute R and D of Materials Physics
recordtype eprints
repository_type Digital Repository
spelling upm-624232021-01-21T15:43:42Z http://psasir.upm.edu.my/id/eprint/62423/ Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution Azis, Raba'ah Syahidah Zakaria, Azmi Abdullah, W. R. W. Isa, N. H. An abnormal grain growth of the ZnO-based ceramics due to highly reactive vanadium liquid phase disrupts its nonlinear properties. The effect of Nd2O3 concentration from 0.01 to 0.05 mol% on microstructure and electrical properties of ZnO-based varistor ceramics were investigated. The sample was fabricated via solid state method and sintered at 900 °C for 2 h. XRD analysis shows the V2O5 and Zn2Nb2Mn2O9 phase formation. SEM analysis shows the grain is more uniform and enlarged to 3.54 μm with Nd2O3 addition up to 0.03 mol%. Nd2O3 also increased both the nonlinear coefficient α and the breakdown electric field, E1mA to an optimum of 9.94 and 75 V/mm. Beyond that concentration, oxygen O vacancy formed at the grain boundary and diminished the electrical properties. National Institute R and D of Materials Physics 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/62423/1/CERAMIC.pdf Azis, Raba'ah Syahidah and Zakaria, Azmi and Abdullah, W. R. W. and Isa, N. H. (2017) Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution. Digest Journal of Nanomaterials and Biostructures, 12 (3). 821 - 827. ISSN 1842-3582 https://chalcogen.ro/821_IsaNH.pdf
spellingShingle Azis, Raba'ah Syahidah
Zakaria, Azmi
Abdullah, W. R. W.
Isa, N. H.
Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution
title Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution
title_full Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution
title_fullStr Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution
title_full_unstemmed Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution
title_short Microstructure and nonlinear properties of Zn-V-Mn-Nb-O varistor ceramics with Nd2O3 substitution
title_sort microstructure and nonlinear properties of zn-v-mn-nb-o varistor ceramics with nd2o3 substitution
url http://psasir.upm.edu.my/id/eprint/62423/
http://psasir.upm.edu.my/id/eprint/62423/
http://psasir.upm.edu.my/id/eprint/62423/1/CERAMIC.pdf