Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics

The influence of temperature on microstructural, structural and ferroelectric evolution properties of multiferroic holmium manganese oxide (HoMnO3) ceramics were investigated. HoMnO3 ceramics were synthesized using a mechanochemical reaction of Ho2O3 and Mn2O3powders in a high energy ball milling ma...

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Main Authors: Abdullah, Nor Hapishah, Azis, Raba'ah Syahidah, Hashim, Mansor, Ismail, Ismayadi, Hassan, Jelan, Mustaffa, Muhammad Syazwan, Ibrahim, Idza Riati
Format: Article
Language:English
Published: Springer 2017
Online Access:http://psasir.upm.edu.my/id/eprint/62170/
http://psasir.upm.edu.my/id/eprint/62170/1/Influence%20of%20temperature%20on%20microstructure.pdf
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author Abdullah, Nor Hapishah
Azis, Raba'ah Syahidah
Hashim, Mansor
Ismail, Ismayadi
Hassan, Jelan
Mustaffa, Muhammad Syazwan
Ibrahim, Idza Riati
author_facet Abdullah, Nor Hapishah
Azis, Raba'ah Syahidah
Hashim, Mansor
Ismail, Ismayadi
Hassan, Jelan
Mustaffa, Muhammad Syazwan
Ibrahim, Idza Riati
author_sort Abdullah, Nor Hapishah
building UPM Institutional Repository
collection Online Access
description The influence of temperature on microstructural, structural and ferroelectric evolution properties of multiferroic holmium manganese oxide (HoMnO3) ceramics were investigated. HoMnO3 ceramics were synthesized using a mechanochemical reaction of Ho2O3 and Mn2O3powders in a high energy ball milling machine. The powder were sintered from 600 to 1250 °C with 50 °C increments. The results shows the microstructural, structural and ferroelectric hysteresis loop were observed to be dependent on sintering temperatures. The XRD characterization suggests an improvement of crystallinity with increasing sintering temperature. The hexagonal HoMnO3 were observed at temperature ≥1200 °C with the grain size of around 1600 nm. SEM micrographs showed larger grain size as the sintering temperature increased. The SEM results revealed a transformation of crystal structure occurs from orthorhombic to hexagonal at larger grain size regime. Polarization P—electric field Eferroelectric properties were observed to be enhanced with the increase of grain size through sintering temperature. The ferroelectric behavior was observed to change with the change of microstructure along with the structure transformation from orthorhombic to hexagonal. A complete systematic studies of the micron-nanometer grain size on microstructure-properties evolution of HoMnO3 multiferrroic ceramics is higlighted.
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institution Universiti Putra Malaysia
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spelling upm-621702019-04-18T06:51:19Z http://psasir.upm.edu.my/id/eprint/62170/ Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics Abdullah, Nor Hapishah Azis, Raba'ah Syahidah Hashim, Mansor Ismail, Ismayadi Hassan, Jelan Mustaffa, Muhammad Syazwan Ibrahim, Idza Riati The influence of temperature on microstructural, structural and ferroelectric evolution properties of multiferroic holmium manganese oxide (HoMnO3) ceramics were investigated. HoMnO3 ceramics were synthesized using a mechanochemical reaction of Ho2O3 and Mn2O3powders in a high energy ball milling machine. The powder were sintered from 600 to 1250 °C with 50 °C increments. The results shows the microstructural, structural and ferroelectric hysteresis loop were observed to be dependent on sintering temperatures. The XRD characterization suggests an improvement of crystallinity with increasing sintering temperature. The hexagonal HoMnO3 were observed at temperature ≥1200 °C with the grain size of around 1600 nm. SEM micrographs showed larger grain size as the sintering temperature increased. The SEM results revealed a transformation of crystal structure occurs from orthorhombic to hexagonal at larger grain size regime. Polarization P—electric field Eferroelectric properties were observed to be enhanced with the increase of grain size through sintering temperature. The ferroelectric behavior was observed to change with the change of microstructure along with the structure transformation from orthorhombic to hexagonal. A complete systematic studies of the micron-nanometer grain size on microstructure-properties evolution of HoMnO3 multiferrroic ceramics is higlighted. Springer 2017-11 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/62170/1/Influence%20of%20temperature%20on%20microstructure.pdf Abdullah, Nor Hapishah and Azis, Raba'ah Syahidah and Hashim, Mansor and Ismail, Ismayadi and Hassan, Jelan and Mustaffa, Muhammad Syazwan and Ibrahim, Idza Riati (2017) Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics. Journal of Materials Science: Materials in Electronics, 28 (21). 16053 - 16061. ISSN 0957-4522; ESSN: 1573-482X https://link.springer.com/article/10.1007/s10854-017-7505-2 10.1007/s10854-017-7505-2
spellingShingle Abdullah, Nor Hapishah
Azis, Raba'ah Syahidah
Hashim, Mansor
Ismail, Ismayadi
Hassan, Jelan
Mustaffa, Muhammad Syazwan
Ibrahim, Idza Riati
Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_full Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_fullStr Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_full_unstemmed Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_short Influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic HoMnO3 ceramics
title_sort influence of temperature on microstructure, structural and ferroelectricity evolution properties with nano and micrometer grain size in multiferroic homno3 ceramics
url http://psasir.upm.edu.my/id/eprint/62170/
http://psasir.upm.edu.my/id/eprint/62170/
http://psasir.upm.edu.my/id/eprint/62170/
http://psasir.upm.edu.my/id/eprint/62170/1/Influence%20of%20temperature%20on%20microstructure.pdf