Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems

The glass samples of zinc borotellurite glass doped with dysprosium nanoparticles with chemical formula TeO20.7B2O30.30.7ZnO0.31-xDy2O3x (where x= 0.01, 0.02, 0.03, 0.04 and 0.05 molar fraction) have been fabricated by using melt quenching technique. In this study, the structural and optical propert...

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Main Authors: Mohd Nor, Ami Hazlin, Mohamed Kamari, Halimah, Muhammad, Farah Diana, M. F., Faznny, Mustafa, Iskandar Shahrim
Format: Article
Language:English
Published: Scientific.Net 2017
Online Access:http://psasir.upm.edu.my/id/eprint/61564/
http://psasir.upm.edu.my/id/eprint/61564/1/Effect%20of%20dysprosium%20nanoparticles%20on%20the%20optical%20properties%20of%20zinc%20borotellurite%20glass%20systems.pdf
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author Mohd Nor, Ami Hazlin
Mohamed Kamari, Halimah
Muhammad, Farah Diana
M. F., Faznny
Mustafa, Iskandar Shahrim
author_facet Mohd Nor, Ami Hazlin
Mohamed Kamari, Halimah
Muhammad, Farah Diana
M. F., Faznny
Mustafa, Iskandar Shahrim
author_sort Mohd Nor, Ami Hazlin
building UPM Institutional Repository
collection Online Access
description The glass samples of zinc borotellurite glass doped with dysprosium nanoparticles with chemical formula TeO20.7B2O30.30.7ZnO0.31-xDy2O3x (where x= 0.01, 0.02, 0.03, 0.04 and 0.05 molar fraction) have been fabricated by using melt quenching technique. In this study, the structural and optical properties of the zinc borotellurite glass doped with dysprosium nanoparticles were characterized by using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and UV-Vis spectroscopy. From the XRD, the amorphous nature of the glass samples has been confirmed. The infrared spectra revealed four obvious bands which are assigned for BO3, BO4 and TeO4 vibrational groups. The direct and indirect optical band gap, as well as Urbach energy, was calculated through absorption spectra obtained from UV-Vis spectroscopy. From the spectra, it is observed that both direct and indirect optical band gap decreases as the concentration of dysprosium nanoparticles increase. Other than that, the Urbach energy is observed to have an inverse trend with the optical band gap. The Urbach energy is increases as the concentration of dysprosium nanoparticles increases.
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spelling upm-615642022-05-25T02:43:41Z http://psasir.upm.edu.my/id/eprint/61564/ Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems Mohd Nor, Ami Hazlin Mohamed Kamari, Halimah Muhammad, Farah Diana M. F., Faznny Mustafa, Iskandar Shahrim The glass samples of zinc borotellurite glass doped with dysprosium nanoparticles with chemical formula TeO20.7B2O30.30.7ZnO0.31-xDy2O3x (where x= 0.01, 0.02, 0.03, 0.04 and 0.05 molar fraction) have been fabricated by using melt quenching technique. In this study, the structural and optical properties of the zinc borotellurite glass doped with dysprosium nanoparticles were characterized by using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and UV-Vis spectroscopy. From the XRD, the amorphous nature of the glass samples has been confirmed. The infrared spectra revealed four obvious bands which are assigned for BO3, BO4 and TeO4 vibrational groups. The direct and indirect optical band gap, as well as Urbach energy, was calculated through absorption spectra obtained from UV-Vis spectroscopy. From the spectra, it is observed that both direct and indirect optical band gap decreases as the concentration of dysprosium nanoparticles increase. Other than that, the Urbach energy is observed to have an inverse trend with the optical band gap. The Urbach energy is increases as the concentration of dysprosium nanoparticles increases. Scientific.Net 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/61564/1/Effect%20of%20dysprosium%20nanoparticles%20on%20the%20optical%20properties%20of%20zinc%20borotellurite%20glass%20systems.pdf Mohd Nor, Ami Hazlin and Mohamed Kamari, Halimah and Muhammad, Farah Diana and M. F., Faznny and Mustafa, Iskandar Shahrim (2017) Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems. Solid State Phenomena, 268. 13 - 17. ISSN 1012-0394; ESSN: 1662-9779 https://www.scientific.net/SSP.268.13 10.4028/www.scientific.net/SSP.268.13
spellingShingle Mohd Nor, Ami Hazlin
Mohamed Kamari, Halimah
Muhammad, Farah Diana
M. F., Faznny
Mustafa, Iskandar Shahrim
Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems
title Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems
title_full Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems
title_fullStr Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems
title_full_unstemmed Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems
title_short Effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems
title_sort effect of dysprosium nanoparticles on the optical properties of zinc borotellurite glass systems
url http://psasir.upm.edu.my/id/eprint/61564/
http://psasir.upm.edu.my/id/eprint/61564/
http://psasir.upm.edu.my/id/eprint/61564/
http://psasir.upm.edu.my/id/eprint/61564/1/Effect%20of%20dysprosium%20nanoparticles%20on%20the%20optical%20properties%20of%20zinc%20borotellurite%20glass%20systems.pdf