Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding
Combination of mortar grinder mill (MG) and ionic liquid (IL) treatment was employed in order to fibrillate fibers from oil palm mesocarp fiber (OPMF) in one-step. The structural changes of OPMF before and after the treatment were examined by Thermogravimetric analysis (TGA), Fourier transformed inf...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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John Wiley & Sons
2017
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| Online Access: | http://psasir.upm.edu.my/id/eprint/61528/ http://psasir.upm.edu.my/id/eprint/61528/1/Dynamically%20controlled%20fibrillation%20under%20combination%20of%20ionic%20liquid%20with%20mechanical%20grinding.pdf |
| _version_ | 1848854429893132288 |
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| author | Eksiler, Kubra Andou, Yoshito Yilmaz, Faruk Shirai, Yoshihito Ariffin, Hidayah Hassan, Mohd Ali |
| author_facet | Eksiler, Kubra Andou, Yoshito Yilmaz, Faruk Shirai, Yoshihito Ariffin, Hidayah Hassan, Mohd Ali |
| author_sort | Eksiler, Kubra |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Combination of mortar grinder mill (MG) and ionic liquid (IL) treatment was employed in order to fibrillate fibers from oil palm mesocarp fiber (OPMF) in one-step. The structural changes of OPMF before and after the treatment were examined by Thermogravimetric analysis (TGA), Fourier transformed infrared (FT-IR) spectra, Wide-angle X-ray diffraction (WAXD), Dynamic light scattering (DLS) and Scanning electron microscopy (SEM). Compared with the only use of 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM[BF4]), combination of MG and IL helped to remove hemicellulose and lignin components partially from OPMF, and also fibrillated OPMF fibers at average particle diameter of 127 nm. Afterwards, the fibrillated fibers were utilized as reinforcement material for the purpose of enhancement of mechanical properties of poly(ɛ-caprolactone)(PCL). The addition of OPMF treated with the combined method led to a 64% increase in tensile strength in comparison with that of untreated OPMF. These results indicate that the combined method enables effective fibrillation. |
| first_indexed | 2025-11-15T11:09:44Z |
| format | Article |
| id | upm-61528 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T11:09:44Z |
| publishDate | 2017 |
| publisher | John Wiley & Sons |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-615282022-05-25T03:09:34Z http://psasir.upm.edu.my/id/eprint/61528/ Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding Eksiler, Kubra Andou, Yoshito Yilmaz, Faruk Shirai, Yoshihito Ariffin, Hidayah Hassan, Mohd Ali Combination of mortar grinder mill (MG) and ionic liquid (IL) treatment was employed in order to fibrillate fibers from oil palm mesocarp fiber (OPMF) in one-step. The structural changes of OPMF before and after the treatment were examined by Thermogravimetric analysis (TGA), Fourier transformed infrared (FT-IR) spectra, Wide-angle X-ray diffraction (WAXD), Dynamic light scattering (DLS) and Scanning electron microscopy (SEM). Compared with the only use of 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM[BF4]), combination of MG and IL helped to remove hemicellulose and lignin components partially from OPMF, and also fibrillated OPMF fibers at average particle diameter of 127 nm. Afterwards, the fibrillated fibers were utilized as reinforcement material for the purpose of enhancement of mechanical properties of poly(ɛ-caprolactone)(PCL). The addition of OPMF treated with the combined method led to a 64% increase in tensile strength in comparison with that of untreated OPMF. These results indicate that the combined method enables effective fibrillation. John Wiley & Sons 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/61528/1/Dynamically%20controlled%20fibrillation%20under%20combination%20of%20ionic%20liquid%20with%20mechanical%20grinding.pdf Eksiler, Kubra and Andou, Yoshito and Yilmaz, Faruk and Shirai, Yoshihito and Ariffin, Hidayah and Hassan, Mohd Ali (2017) Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding. Jourbal of Applied Polymer Science, 134 (7). art. no. 44469. pp. 1-7. ISSN 0021-8995; ESSN: 1097-4628 https://onlinelibrary.wiley.com/doi/10.1002/app.44469 10.1002/app.44469 |
| spellingShingle | Eksiler, Kubra Andou, Yoshito Yilmaz, Faruk Shirai, Yoshihito Ariffin, Hidayah Hassan, Mohd Ali Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding |
| title | Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding |
| title_full | Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding |
| title_fullStr | Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding |
| title_full_unstemmed | Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding |
| title_short | Dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding |
| title_sort | dynamically controlled fibrillation under combination of ionic liquid with mechanical grinding |
| url | http://psasir.upm.edu.my/id/eprint/61528/ http://psasir.upm.edu.my/id/eprint/61528/ http://psasir.upm.edu.my/id/eprint/61528/ http://psasir.upm.edu.my/id/eprint/61528/1/Dynamically%20controlled%20fibrillation%20under%20combination%20of%20ionic%20liquid%20with%20mechanical%20grinding.pdf |