Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols
Efficient synthesis of n‐3 PUFA‐enriched triacylglycerol (TAG) by the esterification of glycerol with n‐3 PUFA in deep eutectic solvents (DES) is reported. There was a 1.2‐fold increase of TAG yield in DES compared with that in the solvent‐free system. Adsorption of the produced water by DES during...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH Verlag GmbH & Co. KGaA
2017
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| Online Access: | http://psasir.upm.edu.my/id/eprint/61289/ http://psasir.upm.edu.my/id/eprint/61289/1/Deep%20eutectic%20solvents%20enable%20the%20enhanced%20production%20of%20n-3%20PUFA-enriched%20triacylglycerols.pdf |
| _version_ | 1848854383838625792 |
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| author | Long, Xu Li, Zhang Daoming, Li Pengzhan, Liu Tan, Chin Ping Weifei, Wang Xiangqian, Liu Boo, Yang Liang Dongming, Lan Yonghua, Wang |
| author_facet | Long, Xu Li, Zhang Daoming, Li Pengzhan, Liu Tan, Chin Ping Weifei, Wang Xiangqian, Liu Boo, Yang Liang Dongming, Lan Yonghua, Wang |
| author_sort | Long, Xu |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Efficient synthesis of n‐3 PUFA‐enriched triacylglycerol (TAG) by the esterification of glycerol with n‐3 PUFA in deep eutectic solvents (DES) is reported. There was a 1.2‐fold increase of TAG yield in DES compared with that in the solvent‐free system. Adsorption of the produced water by DES during esterification contributed to enhance the conversion efficiency by changing the reaction equilibrium. DES also served as an effective solvent for enriching the n‐3 PUFA of TAG in the upper layer of reaction media. A TAG yield of 55% was achieved under the optimal condition. Practical Applications: Enzymatic synthesis of n‐3 PUFA‐enriched triacylglycerol (TAG) is challenged by low yields. Here, deep eutectic solvents show great potential for enhancing the production of n‐3 PUFA‐enriched TAG. |
| first_indexed | 2025-11-15T11:09:00Z |
| format | Article |
| id | upm-61289 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T11:09:00Z |
| publishDate | 2017 |
| publisher | Wiley-VCH Verlag GmbH & Co. KGaA |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-612892018-07-26T08:31:03Z http://psasir.upm.edu.my/id/eprint/61289/ Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols Long, Xu Li, Zhang Daoming, Li Pengzhan, Liu Tan, Chin Ping Weifei, Wang Xiangqian, Liu Boo, Yang Liang Dongming, Lan Yonghua, Wang Efficient synthesis of n‐3 PUFA‐enriched triacylglycerol (TAG) by the esterification of glycerol with n‐3 PUFA in deep eutectic solvents (DES) is reported. There was a 1.2‐fold increase of TAG yield in DES compared with that in the solvent‐free system. Adsorption of the produced water by DES during esterification contributed to enhance the conversion efficiency by changing the reaction equilibrium. DES also served as an effective solvent for enriching the n‐3 PUFA of TAG in the upper layer of reaction media. A TAG yield of 55% was achieved under the optimal condition. Practical Applications: Enzymatic synthesis of n‐3 PUFA‐enriched triacylglycerol (TAG) is challenged by low yields. Here, deep eutectic solvents show great potential for enhancing the production of n‐3 PUFA‐enriched TAG. Wiley-VCH Verlag GmbH & Co. KGaA 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/61289/1/Deep%20eutectic%20solvents%20enable%20the%20enhanced%20production%20of%20n-3%20PUFA-enriched%20triacylglycerols.pdf Long, Xu and Li, Zhang and Daoming, Li and Pengzhan, Liu and Tan, Chin Ping and Weifei, Wang and Xiangqian, Liu and Boo, Yang Liang and Dongming, Lan and Yonghua, Wang (2017) Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols. European Journal of Lipid Science and Technology, 119. pp. 1-6. ISSN 1438-7697; ESSN: 1438-9312 https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejlt.201700300 10.1002/ejlt.201700300 |
| spellingShingle | Long, Xu Li, Zhang Daoming, Li Pengzhan, Liu Tan, Chin Ping Weifei, Wang Xiangqian, Liu Boo, Yang Liang Dongming, Lan Yonghua, Wang Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols |
| title | Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols |
| title_full | Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols |
| title_fullStr | Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols |
| title_full_unstemmed | Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols |
| title_short | Deep eutectic solvents enable the enhanced production of n-3 PUFA-enriched triacylglycerols |
| title_sort | deep eutectic solvents enable the enhanced production of n-3 pufa-enriched triacylglycerols |
| url | http://psasir.upm.edu.my/id/eprint/61289/ http://psasir.upm.edu.my/id/eprint/61289/ http://psasir.upm.edu.my/id/eprint/61289/ http://psasir.upm.edu.my/id/eprint/61289/1/Deep%20eutectic%20solvents%20enable%20the%20enhanced%20production%20of%20n-3%20PUFA-enriched%20triacylglycerols.pdf |