Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives

The inhibitive actions of fatty acid derivatives namely palmitate hydrazide (PH), N-ethylidene palmitate hydrazide (EPH) and N-phenylmethylidene palmitate hydrazide (PPH) on mild steel in 1 M hydrochloric acid were investigated using open circuit potential, linear polarisation and electrochemical im...

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Main Authors: Mohd, Noor Khairin, Ghazali, Mariyam Jameelah, Yeong, Shoot Kian, Ibrahim, Nor Azowa, Wan Yunus, Wan Md. Zin, Mohd Noor, Siti Mariam, Idris, Zainab
Format: Article
Language:English
Published: Malaysian Palm Oil Board 2017
Online Access:http://psasir.upm.edu.my/id/eprint/61240/
http://psasir.upm.edu.my/id/eprint/61240/1/STEEL.pdf
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author Mohd, Noor Khairin
Ghazali, Mariyam Jameelah
Yeong, Shoot Kian
Ibrahim, Nor Azowa
Wan Yunus, Wan Md. Zin
Mohd Noor, Siti Mariam
Idris, Zainab
author_facet Mohd, Noor Khairin
Ghazali, Mariyam Jameelah
Yeong, Shoot Kian
Ibrahim, Nor Azowa
Wan Yunus, Wan Md. Zin
Mohd Noor, Siti Mariam
Idris, Zainab
author_sort Mohd, Noor Khairin
building UPM Institutional Repository
collection Online Access
description The inhibitive actions of fatty acid derivatives namely palmitate hydrazide (PH), N-ethylidene palmitate hydrazide (EPH) and N-phenylmethylidene palmitate hydrazide (PPH) on mild steel in 1 M hydrochloric acid were investigated using open circuit potential, linear polarisation and electrochemical impedance spectroscopy techniques. It was observed that the percentage of inhibition efficiency (η%) increased with increasing concentrations of inhibitor and temperature of test medium. The maximum η% approaches 85% in the presence of 200 mg litre-1 of inhibitors EPH and PPH at 308 ± 1K. The inhibitor efficiencies were found to be in the following order: PPH>EPH>PH. The adsorption of these inhibitors on mild steel surface obeys Langmuir adsorption isotherm. They act as mixed-type inhibitors. Scanning electron microscopy-energy dispersive X-ray (SEM-EDX) was also carried out on polished mild steel coupons and those immersed in the test medium with the absence and presence of 200 mg litre-1 of the inhibitors studied.
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institution Universiti Putra Malaysia
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language English
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publishDate 2017
publisher Malaysian Palm Oil Board
recordtype eprints
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spelling upm-612402021-07-17T23:01:35Z http://psasir.upm.edu.my/id/eprint/61240/ Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives Mohd, Noor Khairin Ghazali, Mariyam Jameelah Yeong, Shoot Kian Ibrahim, Nor Azowa Wan Yunus, Wan Md. Zin Mohd Noor, Siti Mariam Idris, Zainab The inhibitive actions of fatty acid derivatives namely palmitate hydrazide (PH), N-ethylidene palmitate hydrazide (EPH) and N-phenylmethylidene palmitate hydrazide (PPH) on mild steel in 1 M hydrochloric acid were investigated using open circuit potential, linear polarisation and electrochemical impedance spectroscopy techniques. It was observed that the percentage of inhibition efficiency (η%) increased with increasing concentrations of inhibitor and temperature of test medium. The maximum η% approaches 85% in the presence of 200 mg litre-1 of inhibitors EPH and PPH at 308 ± 1K. The inhibitor efficiencies were found to be in the following order: PPH>EPH>PH. The adsorption of these inhibitors on mild steel surface obeys Langmuir adsorption isotherm. They act as mixed-type inhibitors. Scanning electron microscopy-energy dispersive X-ray (SEM-EDX) was also carried out on polished mild steel coupons and those immersed in the test medium with the absence and presence of 200 mg litre-1 of the inhibitors studied. Malaysian Palm Oil Board 2017-03 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/61240/1/STEEL.pdf Mohd, Noor Khairin and Ghazali, Mariyam Jameelah and Yeong, Shoot Kian and Ibrahim, Nor Azowa and Wan Yunus, Wan Md. Zin and Mohd Noor, Siti Mariam and Idris, Zainab (2017) Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives. Journal of Oil Palm Research, 29 (1). 97 - 109. ISSN 1511-2780 http://jopr.mpob.gov.my/corrosion-inhibition-of-mild-steel-in-hydrochloric-acid-solution-using-fatty-acid-derivatives/ 10.21894/jopr.2017.2901.11
spellingShingle Mohd, Noor Khairin
Ghazali, Mariyam Jameelah
Yeong, Shoot Kian
Ibrahim, Nor Azowa
Wan Yunus, Wan Md. Zin
Mohd Noor, Siti Mariam
Idris, Zainab
Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives
title Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives
title_full Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives
title_fullStr Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives
title_full_unstemmed Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives
title_short Corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives
title_sort corrosion inhibition of mild steel in hydrochloric acid solution using fatty acid derivatives
url http://psasir.upm.edu.my/id/eprint/61240/
http://psasir.upm.edu.my/id/eprint/61240/
http://psasir.upm.edu.my/id/eprint/61240/
http://psasir.upm.edu.my/id/eprint/61240/1/STEEL.pdf