Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO)

The non-edible seed oil of the Jatropha plant is a renewable and sustainable material to produce vegetable oil-based epoxy and epoxy acrylate as raw polymeric material. The objective of this study is to synthesis Jatropha seed oil-based epoxy and acrylate epoxy resins through conventional methods. A...

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Main Authors: Wong, Jia Li, Aung, Min Min, Lim, Hong Ngee, Md Jamil, Siti Nurul Ain
Format: Article
Language:English
Published: Universiti Putra Malaysia Press 2017
Online Access:http://psasir.upm.edu.my/id/eprint/58339/
http://psasir.upm.edu.my/id/eprint/58339/1/11%20JTAS%28S%29-0018-2017-4thProof.pdf
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author Wong, Jia Li
Aung, Min Min
Lim, Hong Ngee
Md Jamil, Siti Nurul Ain
author_facet Wong, Jia Li
Aung, Min Min
Lim, Hong Ngee
Md Jamil, Siti Nurul Ain
author_sort Wong, Jia Li
building UPM Institutional Repository
collection Online Access
description The non-edible seed oil of the Jatropha plant is a renewable and sustainable material to produce vegetable oil-based epoxy and epoxy acrylate as raw polymeric material. The objective of this study is to synthesis Jatropha seed oil-based epoxy and acrylate epoxy resins through conventional methods. An epoxy ring of Epoxidised Jatropha Oil (EJO) was formed through an in-situ epoxidation process using hydrogen peroxide and formic acid as an oxygen donor and oxygen carrier respectively. Acrylated Epoxidised Jatropha Oil (AEJO) was produced by reacting EJO with acrylic acid with the existence of triethylamine and 4-methoxyphenol as a catalyst and inhibitor respectively. The measured oxirane-oxygen content (OOC) of EJO was 4.99%. The acid value of the AEJO was determined at 4.42 mg KOH/g. Both the EJO and AEJO were characterised by FTIR and 1H NMR spectroscopies.
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spelling upm-583392018-01-25T10:02:29Z http://psasir.upm.edu.my/id/eprint/58339/ Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO) Wong, Jia Li Aung, Min Min Lim, Hong Ngee Md Jamil, Siti Nurul Ain The non-edible seed oil of the Jatropha plant is a renewable and sustainable material to produce vegetable oil-based epoxy and epoxy acrylate as raw polymeric material. The objective of this study is to synthesis Jatropha seed oil-based epoxy and acrylate epoxy resins through conventional methods. An epoxy ring of Epoxidised Jatropha Oil (EJO) was formed through an in-situ epoxidation process using hydrogen peroxide and formic acid as an oxygen donor and oxygen carrier respectively. Acrylated Epoxidised Jatropha Oil (AEJO) was produced by reacting EJO with acrylic acid with the existence of triethylamine and 4-methoxyphenol as a catalyst and inhibitor respectively. The measured oxirane-oxygen content (OOC) of EJO was 4.99%. The acid value of the AEJO was determined at 4.42 mg KOH/g. Both the EJO and AEJO were characterised by FTIR and 1H NMR spectroscopies. Universiti Putra Malaysia Press 2017 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/58339/1/11%20JTAS%28S%29-0018-2017-4thProof.pdf Wong, Jia Li and Aung, Min Min and Lim, Hong Ngee and Md Jamil, Siti Nurul Ain (2017) Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO). Pertanika Journal of Tropical Agricultural Science, 40 (3). pp. 435-448. ISSN 1511-3701; ESSN: 2231-8542 http://www.pertanika.upm.edu.my/Pertanika%20PAPERS/JTAS%20Vol.%2040%20(3)%20Aug.%202017/11%20JTAS(S)-0018-2017-4thProof.pdf
spellingShingle Wong, Jia Li
Aung, Min Min
Lim, Hong Ngee
Md Jamil, Siti Nurul Ain
Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO)
title Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO)
title_full Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO)
title_fullStr Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO)
title_full_unstemmed Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO)
title_short Spectroscopic analysis of epoxidised jatropha oil (EJO) and acrylated epoxidised jatropha oil (AEJO)
title_sort spectroscopic analysis of epoxidised jatropha oil (ejo) and acrylated epoxidised jatropha oil (aejo)
url http://psasir.upm.edu.my/id/eprint/58339/
http://psasir.upm.edu.my/id/eprint/58339/
http://psasir.upm.edu.my/id/eprint/58339/1/11%20JTAS%28S%29-0018-2017-4thProof.pdf