Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate
The title complex, [Cu2(C4H5O2)2(C12H8N2)2(H2O)2](NO3)2- 2H2O, contains a dimeric [Cu2(C4H5O2)2(C12H8N2)2- (H2O)2]2+ dication with two five-coordinated CuII ions linked by two methacrylate ions in a syn–syn bridging arrangement.The dication possesses pseudo-twofold rotational symmetry.The pentacoo...
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| Format: | Article |
| Language: | English English |
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International Union of Crystallography
2008
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| Online Access: | http://psasir.upm.edu.my/id/eprint/5808/ http://psasir.upm.edu.my/id/eprint/5808/1/Di-l-methacrylato-j4OO0-bis%5Baquabis%281%2C10-phenanthroline-j2N%2CN0%29-copper%28II%29%5D%20dinitrate%20dihydrate.pdf |
| _version_ | 1848840203158945792 |
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| author | Tarafder, Md. Tofazzal Hossain Reza, M. Y. Crouse, Karen Anne Suchada, Chantrapromm Fun, Hoong Kun |
| author_facet | Tarafder, Md. Tofazzal Hossain Reza, M. Y. Crouse, Karen Anne Suchada, Chantrapromm Fun, Hoong Kun |
| author_sort | Tarafder, Md. Tofazzal Hossain |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The title complex, [Cu2(C4H5O2)2(C12H8N2)2(H2O)2](NO3)2-
2H2O, contains a dimeric [Cu2(C4H5O2)2(C12H8N2)2-
(H2O)2]2+ dication with two five-coordinated CuII ions linked by two methacrylate ions in a syn–syn bridging arrangement.The dication possesses pseudo-twofold rotational symmetry.The pentacoordination of each CuII ion has a distorted squarepyramidal geometry, with two N donors from a phenanthroline ligand and two carboxylate O atoms occupying basal sites and the apical position being occupied by a water molecule. In the crystal packing, molecules are linked to form a threedimensional
framework by O—H O and C—H O hydrogen bonds and – interactions [centroid–centroid distances of 3.6039 (15), 3.5301 (15), 3.6015 (15),3.6496 (15) and 3.6858 (15) A ° ]. |
| first_indexed | 2025-11-15T07:23:36Z |
| format | Article |
| id | upm-5808 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T07:23:36Z |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-58082016-01-20T04:37:39Z http://psasir.upm.edu.my/id/eprint/5808/ Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate Tarafder, Md. Tofazzal Hossain Reza, M. Y. Crouse, Karen Anne Suchada, Chantrapromm Fun, Hoong Kun The title complex, [Cu2(C4H5O2)2(C12H8N2)2(H2O)2](NO3)2- 2H2O, contains a dimeric [Cu2(C4H5O2)2(C12H8N2)2- (H2O)2]2+ dication with two five-coordinated CuII ions linked by two methacrylate ions in a syn–syn bridging arrangement.The dication possesses pseudo-twofold rotational symmetry.The pentacoordination of each CuII ion has a distorted squarepyramidal geometry, with two N donors from a phenanthroline ligand and two carboxylate O atoms occupying basal sites and the apical position being occupied by a water molecule. In the crystal packing, molecules are linked to form a threedimensional framework by O—H O and C—H O hydrogen bonds and – interactions [centroid–centroid distances of 3.6039 (15), 3.5301 (15), 3.6015 (15),3.6496 (15) and 3.6858 (15) A ° ]. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/5808/1/Di-l-methacrylato-j4OO0-bis%5Baquabis%281%2C10-phenanthroline-j2N%2CN0%29-copper%28II%29%5D%20dinitrate%20dihydrate.pdf Tarafder, Md. Tofazzal Hossain and Reza, M. Y. and Crouse, Karen Anne and Suchada, Chantrapromm and Fun, Hoong Kun (2008) Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate. Acta Crystallographica Section E: Structure Reports Online, 64 (7). pp. 872-873. ISSN 1600-5368 http://journals.iucr.org/e/issues/2008/07/00/ci2604/ci2604.pdf 10.1107/S1600536808016218 English |
| spellingShingle | Tarafder, Md. Tofazzal Hossain Reza, M. Y. Crouse, Karen Anne Suchada, Chantrapromm Fun, Hoong Kun Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate |
| title | Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate |
| title_full | Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate |
| title_fullStr | Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate |
| title_full_unstemmed | Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate |
| title_short | Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate |
| title_sort | di-l-methacrylato-j4o:o0-bis[aquabis(1,10-phenanthroline-j2n,n0)-copper(ii)] dinitrate dihydrate |
| url | http://psasir.upm.edu.my/id/eprint/5808/ http://psasir.upm.edu.my/id/eprint/5808/ http://psasir.upm.edu.my/id/eprint/5808/ http://psasir.upm.edu.my/id/eprint/5808/1/Di-l-methacrylato-j4OO0-bis%5Baquabis%281%2C10-phenanthroline-j2N%2CN0%29-copper%28II%29%5D%20dinitrate%20dihydrate.pdf |