Di-l-methacrylato-j4O:O0-bis[aquabis(1,10-phenanthroline-j2N,N0)-copper(II)] dinitrate dihydrate
The title complex, [Cu2(C4H5O2)2(C12H8N2)2(H2O)2](NO3)2- 2H2O, contains a dimeric [Cu2(C4H5O2)2(C12H8N2)2- (H2O)2]2+ dication with two five-coordinated CuII ions linked by two methacrylate ions in a syn–syn bridging arrangement.The dication possesses pseudo-twofold rotational symmetry.The pentacoo...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2008
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| Online Access: | http://psasir.upm.edu.my/id/eprint/5808/ http://psasir.upm.edu.my/id/eprint/5808/1/Di-l-methacrylato-j4OO0-bis%5Baquabis%281%2C10-phenanthroline-j2N%2CN0%29-copper%28II%29%5D%20dinitrate%20dihydrate.pdf |
| Summary: | The title complex, [Cu2(C4H5O2)2(C12H8N2)2(H2O)2](NO3)2-
2H2O, contains a dimeric [Cu2(C4H5O2)2(C12H8N2)2-
(H2O)2]2+ dication with two five-coordinated CuII ions linked by two methacrylate ions in a syn–syn bridging arrangement.The dication possesses pseudo-twofold rotational symmetry.The pentacoordination of each CuII ion has a distorted squarepyramidal geometry, with two N donors from a phenanthroline ligand and two carboxylate O atoms occupying basal sites and the apical position being occupied by a water molecule. In the crystal packing, molecules are linked to form a threedimensional
framework by O—H O and C—H O hydrogen bonds and – interactions [centroid–centroid distances of 3.6039 (15), 3.5301 (15), 3.6015 (15),3.6496 (15) and 3.6858 (15) A ° ]. |
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