Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution

In this study, the performance of surface plasmon resonance method incorporated with polypyrrole sensing layer was examined for detection of Cu (II) and Fe (III) ions in aqueous solutions. The polypyrrole was prepared by electro-oxidation method on a gold layer for the detecting low concentration io...

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Main Authors: Sadrolhosseini, Amir Reza, Muhammad Noor, Ahmad Shukri, Abd. Moksin, Mohd Maarof, Abdi, Mahnaz M., Soleimani, Hassan, Abas, Ahmad Fauzi, Talib, Zainal Abdin
Format: Conference or Workshop Item
Language:English
Published: American Institute of Physics 2012
Online Access:http://psasir.upm.edu.my/id/eprint/57267/
http://psasir.upm.edu.my/id/eprint/57267/1/Polypyrrole%20thin%20film%20sensor%20base%20surface%20plasmon%20resonance%20for%20detection%20of%20Cu%28II%29%20and%20Fe%28III%29%20in%20aqueous%20solution.pdf
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author Sadrolhosseini, Amir Reza
Muhammad Noor, Ahmad Shukri
Abd. Moksin, Mohd Maarof
Abdi, Mahnaz M.
Soleimani, Hassan
Abas, Ahmad Fauzi
Talib, Zainal Abdin
author_facet Sadrolhosseini, Amir Reza
Muhammad Noor, Ahmad Shukri
Abd. Moksin, Mohd Maarof
Abdi, Mahnaz M.
Soleimani, Hassan
Abas, Ahmad Fauzi
Talib, Zainal Abdin
author_sort Sadrolhosseini, Amir Reza
building UPM Institutional Repository
collection Online Access
description In this study, the performance of surface plasmon resonance method incorporated with polypyrrole sensing layer was examined for detection of Cu (II) and Fe (III) ions in aqueous solutions. The polypyrrole was prepared by electro-oxidation method on a gold layer for the detecting low concentration ions (0.1, 1 5 10 20 ppm). The experiments carried out at room temperature, and each sample was flowed through the flow cell. A photodiode registered the SPR signals as the function of rotation angle and thickness of layers. For observing the association and dissociation processes, the experiments repeated more than ten times, and the sensorgrams were obtained. Furthermore, Langmuir model was utilized to describe the binding interactions of ions with the polypyrrole layer. The lower concentration detection limit was about 0.1 ppm and the terminal resonance angles were occurred after the 300 s. The sensor was also found to be more sensitive to the presence of Cu than Fe ions.
first_indexed 2025-11-15T10:52:04Z
format Conference or Workshop Item
id upm-57267
institution Universiti Putra Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T10:52:04Z
publishDate 2012
publisher American Institute of Physics
recordtype eprints
repository_type Digital Repository
spelling upm-572672017-09-26T03:48:22Z http://psasir.upm.edu.my/id/eprint/57267/ Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution Sadrolhosseini, Amir Reza Muhammad Noor, Ahmad Shukri Abd. Moksin, Mohd Maarof Abdi, Mahnaz M. Soleimani, Hassan Abas, Ahmad Fauzi Talib, Zainal Abdin In this study, the performance of surface plasmon resonance method incorporated with polypyrrole sensing layer was examined for detection of Cu (II) and Fe (III) ions in aqueous solutions. The polypyrrole was prepared by electro-oxidation method on a gold layer for the detecting low concentration ions (0.1, 1 5 10 20 ppm). The experiments carried out at room temperature, and each sample was flowed through the flow cell. A photodiode registered the SPR signals as the function of rotation angle and thickness of layers. For observing the association and dissociation processes, the experiments repeated more than ten times, and the sensorgrams were obtained. Furthermore, Langmuir model was utilized to describe the binding interactions of ions with the polypyrrole layer. The lower concentration detection limit was about 0.1 ppm and the terminal resonance angles were occurred after the 300 s. The sensor was also found to be more sensitive to the presence of Cu than Fe ions. American Institute of Physics 2012 Conference or Workshop Item PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/57267/1/Polypyrrole%20thin%20film%20sensor%20base%20surface%20plasmon%20resonance%20for%20detection%20of%20Cu%28II%29%20and%20Fe%28III%29%20in%20aqueous%20solution.pdf Sadrolhosseini, Amir Reza and Muhammad Noor, Ahmad Shukri and Abd. Moksin, Mohd Maarof and Abdi, Mahnaz M. and Soleimani, Hassan and Abas, Ahmad Fauzi and Talib, Zainal Abdin (2012) Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution. In: 2nd International Conference on Fundamental and Applied Sciences (ICFAS2012), 12-14 June 2012, Kuala Lumpur Convention Centre, Kuala Lumpur. (pp. 200-204). 10.1063/1.4757465
spellingShingle Sadrolhosseini, Amir Reza
Muhammad Noor, Ahmad Shukri
Abd. Moksin, Mohd Maarof
Abdi, Mahnaz M.
Soleimani, Hassan
Abas, Ahmad Fauzi
Talib, Zainal Abdin
Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution
title Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution
title_full Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution
title_fullStr Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution
title_full_unstemmed Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution
title_short Polypyrrole thin film sensor base surface plasmon resonance for detection of Cu(II) and Fe(III) in aqueous solution
title_sort polypyrrole thin film sensor base surface plasmon resonance for detection of cu(ii) and fe(iii) in aqueous solution
url http://psasir.upm.edu.my/id/eprint/57267/
http://psasir.upm.edu.my/id/eprint/57267/
http://psasir.upm.edu.my/id/eprint/57267/1/Polypyrrole%20thin%20film%20sensor%20base%20surface%20plasmon%20resonance%20for%20detection%20of%20Cu%28II%29%20and%20Fe%28III%29%20in%20aqueous%20solution.pdf