Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics

The effect of rare earth nanoparticles, M=Sm2O3, Nd2O3 and Ho2O3 added to (Bi1.6Pb0.4Sr2Ca2Cu3O10+δ)1-x(M)x, where x = 0.00 - 0.05, superconductor were studied by X-ray diffraction technique (XRD), resistivity (R), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX). The volu...

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Main Authors: Hussein, Baqiah, Shaari, Abdul Halim, Chen, Soo Kien, Lim, Kean Pah, Awang Kechik, Mohd Mustafa
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2016
Subjects:
Online Access:http://psasir.upm.edu.my/id/eprint/54106/
http://psasir.upm.edu.my/id/eprint/54106/1/Effects%20of%20rare%20earth%20nanoparticles%20.pdf
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author Hussein, Baqiah
Shaari, Abdul Halim
Chen, Soo Kien
Lim, Kean Pah
Awang Kechik, Mohd Mustafa
author_facet Hussein, Baqiah
Shaari, Abdul Halim
Chen, Soo Kien
Lim, Kean Pah
Awang Kechik, Mohd Mustafa
author_sort Hussein, Baqiah
building UPM Institutional Repository
collection Online Access
description The effect of rare earth nanoparticles, M=Sm2O3, Nd2O3 and Ho2O3 added to (Bi1.6Pb0.4Sr2Ca2Cu3O10+δ)1-x(M)x, where x = 0.00 - 0.05, superconductor were studied by X-ray diffraction technique (XRD), resistivity (R), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX). The volume fraction of high-Tc phase, Bi-2223, decreased from 84% for pure sample to 48, 30 and 23% at x = 0.05 for Sm2O3, Ho2O3 and Nd2O3 additions, respectively. The critical temperature Tc(R=0) that is 102 K for the pure sample decreased to 78, 73 and 69 K at x = 0.05 for samples with Sm2O3, Nd2O3 and Ho2O3 nanoparticles additions, respectively. The additions of rare earth nanoparticles decreased the grain size and increased the random orientation of the grains. The results showed that the phases’ formations, variations of lattice parameters and electrical properties are sensitive to the size of nanoparticles and magnetic properties of its ions.
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spelling upm-541062018-10-17T06:42:06Z http://psasir.upm.edu.my/id/eprint/54106/ Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics Hussein, Baqiah Shaari, Abdul Halim Chen, Soo Kien Lim, Kean Pah Awang Kechik, Mohd Mustafa The effect of rare earth nanoparticles, M=Sm2O3, Nd2O3 and Ho2O3 added to (Bi1.6Pb0.4Sr2Ca2Cu3O10+δ)1-x(M)x, where x = 0.00 - 0.05, superconductor were studied by X-ray diffraction technique (XRD), resistivity (R), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX). The volume fraction of high-Tc phase, Bi-2223, decreased from 84% for pure sample to 48, 30 and 23% at x = 0.05 for Sm2O3, Ho2O3 and Nd2O3 additions, respectively. The critical temperature Tc(R=0) that is 102 K for the pure sample decreased to 78, 73 and 69 K at x = 0.05 for samples with Sm2O3, Nd2O3 and Ho2O3 nanoparticles additions, respectively. The additions of rare earth nanoparticles decreased the grain size and increased the random orientation of the grains. The results showed that the phases’ formations, variations of lattice parameters and electrical properties are sensitive to the size of nanoparticles and magnetic properties of its ions. Penerbit Universiti Kebangsaan Malaysia 2016 Article NonPeerReviewed text en http://psasir.upm.edu.my/id/eprint/54106/1/Effects%20of%20rare%20earth%20nanoparticles%20.pdf Hussein, Baqiah and Shaari, Abdul Halim and Chen, Soo Kien and Lim, Kean Pah and Awang Kechik, Mohd Mustafa (2016) Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics. Sains Malaysiana, 45 (4). pp. 643-651. ISSN 0026-6039 http://www.ukm.my/jsm/english_journals/vol45num4_2016/contentsVol45num4_2016.html High Tc phase (Bi-2223); Hole concentration; Pairing mechanism; Sm2O3, Ho2O3 and Nd2O3 rare earth nanoparticles
spellingShingle High Tc phase (Bi-2223); Hole concentration; Pairing mechanism; Sm2O3, Ho2O3 and Nd2O3 rare earth nanoparticles
Hussein, Baqiah
Shaari, Abdul Halim
Chen, Soo Kien
Lim, Kean Pah
Awang Kechik, Mohd Mustafa
Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_full Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_fullStr Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_full_unstemmed Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_short Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_sort effects of rare earth nanoparticles (m = sm2o3, ho2o3, nd2o3) addition on the microstructure and superconducting transition of bi1.6pb0.4sr2ca2cu3o10+δ ceramics
topic High Tc phase (Bi-2223); Hole concentration; Pairing mechanism; Sm2O3, Ho2O3 and Nd2O3 rare earth nanoparticles
url http://psasir.upm.edu.my/id/eprint/54106/
http://psasir.upm.edu.my/id/eprint/54106/
http://psasir.upm.edu.my/id/eprint/54106/1/Effects%20of%20rare%20earth%20nanoparticles%20.pdf