Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor
This work reports the combination of graphitic nanofibers (GNF) and carbon nanotubes (CNT) as the electrode material for supercapacitors. The hybrid CNT/GNF was prepared via a synthesis route that involved simple sonication and stirring. The loading of CNT was varied from 5 to 40% weight percentages...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2016
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| Online Access: | http://psasir.upm.edu.my/id/eprint/53574/ http://psasir.upm.edu.my/id/eprint/53574/1/Physicochemical%20and%20electrochemical%20properties%20of%20carbon%20nanotube.pdf |
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| author | Talalah Ramli, Nurul Infaza Abdul Rashid, Suraya Sulaiman, Yusran Mamat, Md Shuhazlly Mohd Zobir, Syazwan Afif Krishnan, Shutesh |
| author_facet | Talalah Ramli, Nurul Infaza Abdul Rashid, Suraya Sulaiman, Yusran Mamat, Md Shuhazlly Mohd Zobir, Syazwan Afif Krishnan, Shutesh |
| author_sort | Talalah Ramli, Nurul Infaza |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | This work reports the combination of graphitic nanofibers (GNF) and carbon nanotubes (CNT) as the electrode material for supercapacitors. The hybrid CNT/GNF was prepared via a synthesis route that involved simple sonication and stirring. The loading of CNT was varied from 5 to 40% weight percentages. A specific capacitance of 174 Fg−1 has been obtained for 20 wt% CNT loading at 50 mV F g−1th 1 M H2SO4 aqueous solution as the electrolyte. The addition of 20 wt% CNT raised the specific capacitance by 87% more than the GNF electrodes. Field Emission Scanning Electron Microscopy (FESEM) and Transmission Electron Microscope (TEM) reveals the random entanglement of CNT and GNF that create diffusion paths for ion transportation. Conformational changes were monitored by Raman spectroscopy, where two dominant peaks (D and G) showed strong intensities and sharp profiles. X-ray Diffraction spectroscopy (XRD) confirmed the purity of CNT/GNF hybrid nanocomposites. 20 wt% of CNT addition also shows an outstanding thermal stability. The marked improvement of the hybrid performance was attributed to the high conductivity of the two constituent materials, coupled with sufficient accessible active sites for electrochemical reactions that resulted in a synergistic behavior of the materials. |
| first_indexed | 2025-11-15T10:36:11Z |
| format | Article |
| id | upm-53574 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T10:36:11Z |
| publishDate | 2016 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-535742017-11-08T04:31:43Z http://psasir.upm.edu.my/id/eprint/53574/ Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor Talalah Ramli, Nurul Infaza Abdul Rashid, Suraya Sulaiman, Yusran Mamat, Md Shuhazlly Mohd Zobir, Syazwan Afif Krishnan, Shutesh This work reports the combination of graphitic nanofibers (GNF) and carbon nanotubes (CNT) as the electrode material for supercapacitors. The hybrid CNT/GNF was prepared via a synthesis route that involved simple sonication and stirring. The loading of CNT was varied from 5 to 40% weight percentages. A specific capacitance of 174 Fg−1 has been obtained for 20 wt% CNT loading at 50 mV F g−1th 1 M H2SO4 aqueous solution as the electrolyte. The addition of 20 wt% CNT raised the specific capacitance by 87% more than the GNF electrodes. Field Emission Scanning Electron Microscopy (FESEM) and Transmission Electron Microscope (TEM) reveals the random entanglement of CNT and GNF that create diffusion paths for ion transportation. Conformational changes were monitored by Raman spectroscopy, where two dominant peaks (D and G) showed strong intensities and sharp profiles. X-ray Diffraction spectroscopy (XRD) confirmed the purity of CNT/GNF hybrid nanocomposites. 20 wt% of CNT addition also shows an outstanding thermal stability. The marked improvement of the hybrid performance was attributed to the high conductivity of the two constituent materials, coupled with sufficient accessible active sites for electrochemical reactions that resulted in a synergistic behavior of the materials. Elsevier 2016-10 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/53574/1/Physicochemical%20and%20electrochemical%20properties%20of%20carbon%20nanotube.pdf Talalah Ramli, Nurul Infaza and Abdul Rashid, Suraya and Sulaiman, Yusran and Mamat, Md Shuhazlly and Mohd Zobir, Syazwan Afif and Krishnan, Shutesh (2016) Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor. Journal of Power Sources, 328. pp. 195-202. ISSN 0378-7753; ESSN: 1873-2755 http://www.sciencedirect.com/science/article/pii/S0378775316309880 10.1016/j.jpowsour.2016.07.110 |
| spellingShingle | Talalah Ramli, Nurul Infaza Abdul Rashid, Suraya Sulaiman, Yusran Mamat, Md Shuhazlly Mohd Zobir, Syazwan Afif Krishnan, Shutesh Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor |
| title | Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor |
| title_full | Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor |
| title_fullStr | Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor |
| title_full_unstemmed | Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor |
| title_short | Physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor |
| title_sort | physicochemical and electrochemical properties of carbon nanotube/graphite nanofiber hybrid nanocomposites for supercapacitor |
| url | http://psasir.upm.edu.my/id/eprint/53574/ http://psasir.upm.edu.my/id/eprint/53574/ http://psasir.upm.edu.my/id/eprint/53574/ http://psasir.upm.edu.my/id/eprint/53574/1/Physicochemical%20and%20electrochemical%20properties%20of%20carbon%20nanotube.pdf |