Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method

Synthesis of cadmium sulfide (CdS) nanoparticles has been performed through the simple and rapid microwave-assisted polyol method, using cadmium chloride and thioacetamide as the cadmium and sulfur sources respectively. Attempts were made to control the size and crystallinity of the CdS nanoparticle...

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Main Authors: Soltani, Nayereh, Saion, Elias, Hussein, Mohd Zobir, Yunus, Robiah, Navasery, Manizheh
Format: Article
Language:English
Published: Trans Tech Publications 2013
Online Access:http://psasir.upm.edu.my/id/eprint/52234/
http://psasir.upm.edu.my/id/eprint/52234/1/Characterization%20of%20CdS%20nanoparticles%20synthesized%20using%20microwave-assisted%20polyol%20method.pdf
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author Soltani, Nayereh
Saion, Elias
Hussein, Mohd Zobir
Yunus, Robiah
Navasery, Manizheh
author_facet Soltani, Nayereh
Saion, Elias
Hussein, Mohd Zobir
Yunus, Robiah
Navasery, Manizheh
author_sort Soltani, Nayereh
building UPM Institutional Repository
collection Online Access
description Synthesis of cadmium sulfide (CdS) nanoparticles has been performed through the simple and rapid microwave-assisted polyol method, using cadmium chloride and thioacetamide as the cadmium and sulfur sources respectively. Attempts were made to control the size and crystallinity of the CdS nanoparticles by controlling microwave irradiation time and the initial molar ratio of the cadmium and sulfur sources. The structure of nanoparticles characterized by X-ray diffraction (XRD) was hexagonal. No peaks corresponding to impurities were detected, indicating the high purity of the product. The size of the prepared samples was calculated by Debye–Scherrer formula according to XRD spectra. The morphology of particles was observed in the transmission electron microscopy (TEM) images was spherical. The average size of nanoparticles was also estimated from these images. The optical absorption of CdS nanoparticles studied by UV-Visible spectroscopy showed a blue shift from bulk CdS due to quantum confinement. The size of nanoparticles was calculated by Brus formula according to UV-Visible spectrum and compared to XRD and TEM results.
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spelling upm-522342017-06-05T05:38:04Z http://psasir.upm.edu.my/id/eprint/52234/ Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method Soltani, Nayereh Saion, Elias Hussein, Mohd Zobir Yunus, Robiah Navasery, Manizheh Synthesis of cadmium sulfide (CdS) nanoparticles has been performed through the simple and rapid microwave-assisted polyol method, using cadmium chloride and thioacetamide as the cadmium and sulfur sources respectively. Attempts were made to control the size and crystallinity of the CdS nanoparticles by controlling microwave irradiation time and the initial molar ratio of the cadmium and sulfur sources. The structure of nanoparticles characterized by X-ray diffraction (XRD) was hexagonal. No peaks corresponding to impurities were detected, indicating the high purity of the product. The size of the prepared samples was calculated by Debye–Scherrer formula according to XRD spectra. The morphology of particles was observed in the transmission electron microscopy (TEM) images was spherical. The average size of nanoparticles was also estimated from these images. The optical absorption of CdS nanoparticles studied by UV-Visible spectroscopy showed a blue shift from bulk CdS due to quantum confinement. The size of nanoparticles was calculated by Brus formula according to UV-Visible spectrum and compared to XRD and TEM results. Trans Tech Publications 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/52234/1/Characterization%20of%20CdS%20nanoparticles%20synthesized%20using%20microwave-assisted%20polyol%20method.pdf Soltani, Nayereh and Saion, Elias and Hussein, Mohd Zobir and Yunus, Robiah and Navasery, Manizheh (2013) Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method. Advanced Materials Research, 667. pp. 122-127. ISSN 1022-6680; ESSN: 1662-8985 https://www.scientific.net/AMR.667.122 10.4028/www.scientific.net/AMR.667.122
spellingShingle Soltani, Nayereh
Saion, Elias
Hussein, Mohd Zobir
Yunus, Robiah
Navasery, Manizheh
Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method
title Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method
title_full Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method
title_fullStr Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method
title_full_unstemmed Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method
title_short Characterization of CdS nanoparticles synthesized using microwave-assisted polyol method
title_sort characterization of cds nanoparticles synthesized using microwave-assisted polyol method
url http://psasir.upm.edu.my/id/eprint/52234/
http://psasir.upm.edu.my/id/eprint/52234/
http://psasir.upm.edu.my/id/eprint/52234/
http://psasir.upm.edu.my/id/eprint/52234/1/Characterization%20of%20CdS%20nanoparticles%20synthesized%20using%20microwave-assisted%20polyol%20method.pdf