Determination of iodine value of palm oil based on triglyceride composition

The triglyceride (TG) composition of palm oil is normally determined by high-performance liquid chromatography (HPLC). The HPLC chromatograms indicated a good separation of most of the TG components in the oil. The TG can be classified based on either the TG groups, i.e., triunsaturated, monosaturat...

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Main Authors: H. M. Salim, Tri Haryati, Che Man, Yaakob, Mohd Ghazali, Hasanah, Ali, Asbi, Buana, Lalang
Format: Article
Language:English
English
Published: AOCS Press 1998
Online Access:http://psasir.upm.edu.my/id/eprint/51690/
http://psasir.upm.edu.my/id/eprint/51690/1/51690.pdf
http://psasir.upm.edu.my/id/eprint/51690/7/J%20Americ%20Oil%20Chem%20Soc%20-%201998%20-%20Haryati%20-%20Determination%20of%20iodine%20value%20of%20palm%20oil%20based%20on%20triglyceride%20composition.pdf
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author H. M. Salim, Tri Haryati
Che Man, Yaakob
Mohd Ghazali, Hasanah
Ali, Asbi
Buana, Lalang
author_facet H. M. Salim, Tri Haryati
Che Man, Yaakob
Mohd Ghazali, Hasanah
Ali, Asbi
Buana, Lalang
author_sort H. M. Salim, Tri Haryati
building UPM Institutional Repository
collection Online Access
description The triglyceride (TG) composition of palm oil is normally determined by high-performance liquid chromatography (HPLC). The HPLC chromatograms indicated a good separation of most of the TG components in the oil. The TG can be classified based on either the TG groups, i.e., triunsaturated, monosaturated, disaturated, or trisaturated, or the number of double bonds, i.e., zero, one, two, three, or four double bonds. The more unsaturated the fatty acid, the greater the iodine value (IV). Therefore, it is hypothesized that the IV of an oil can be determined based upon the TG composition of the oil. Based on the TG groups, stepwise regression analysis showed that the areas of the disaturated, trisaturated, and triunsaturated TG peaks could predict the IV with a coefficient of determination (R2) of 0.990. The regression based on the number of double bonds yielded a good regression equation with R2=0.992. The important variables were the peak area of the fatty acids that contained zero, one, two, and three double bonds. This study concludes that the TG composition can be used to predict the IV of palm oil. The best prediction model is obtained by using the number of double bonds in the TG as the independent variable.
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spelling upm-516902024-07-26T09:30:35Z http://psasir.upm.edu.my/id/eprint/51690/ Determination of iodine value of palm oil based on triglyceride composition H. M. Salim, Tri Haryati Che Man, Yaakob Mohd Ghazali, Hasanah Ali, Asbi Buana, Lalang The triglyceride (TG) composition of palm oil is normally determined by high-performance liquid chromatography (HPLC). The HPLC chromatograms indicated a good separation of most of the TG components in the oil. The TG can be classified based on either the TG groups, i.e., triunsaturated, monosaturated, disaturated, or trisaturated, or the number of double bonds, i.e., zero, one, two, three, or four double bonds. The more unsaturated the fatty acid, the greater the iodine value (IV). Therefore, it is hypothesized that the IV of an oil can be determined based upon the TG composition of the oil. Based on the TG groups, stepwise regression analysis showed that the areas of the disaturated, trisaturated, and triunsaturated TG peaks could predict the IV with a coefficient of determination (R2) of 0.990. The regression based on the number of double bonds yielded a good regression equation with R2=0.992. The important variables were the peak area of the fatty acids that contained zero, one, two, and three double bonds. This study concludes that the TG composition can be used to predict the IV of palm oil. The best prediction model is obtained by using the number of double bonds in the TG as the independent variable. AOCS Press 1998 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/51690/1/51690.pdf text en http://psasir.upm.edu.my/id/eprint/51690/7/J%20Americ%20Oil%20Chem%20Soc%20-%201998%20-%20Haryati%20-%20Determination%20of%20iodine%20value%20of%20palm%20oil%20based%20on%20triglyceride%20composition.pdf H. M. Salim, Tri Haryati and Che Man, Yaakob and Mohd Ghazali, Hasanah and Ali, Asbi and Buana, Lalang (1998) Determination of iodine value of palm oil based on triglyceride composition. Journal of the American Oil Chemists' Society, 75 (7). pp. 789-792. ISSN 0003-021X; ESSN: 1558-9331 https://rd.springer.com/article/10.1007/s11746-998-0227-0 10.1007/s11746-998-0227-0
spellingShingle H. M. Salim, Tri Haryati
Che Man, Yaakob
Mohd Ghazali, Hasanah
Ali, Asbi
Buana, Lalang
Determination of iodine value of palm oil based on triglyceride composition
title Determination of iodine value of palm oil based on triglyceride composition
title_full Determination of iodine value of palm oil based on triglyceride composition
title_fullStr Determination of iodine value of palm oil based on triglyceride composition
title_full_unstemmed Determination of iodine value of palm oil based on triglyceride composition
title_short Determination of iodine value of palm oil based on triglyceride composition
title_sort determination of iodine value of palm oil based on triglyceride composition
url http://psasir.upm.edu.my/id/eprint/51690/
http://psasir.upm.edu.my/id/eprint/51690/
http://psasir.upm.edu.my/id/eprint/51690/
http://psasir.upm.edu.my/id/eprint/51690/1/51690.pdf
http://psasir.upm.edu.my/id/eprint/51690/7/J%20Americ%20Oil%20Chem%20Soc%20-%201998%20-%20Haryati%20-%20Determination%20of%20iodine%20value%20of%20palm%20oil%20based%20on%20triglyceride%20composition.pdf