Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant
The utilization of ferric-manganese promoted molybdenum oxide/zirconia (Fe-Mn- MoO/ZrO2) (FMMZ) solid acid catalyst for production of biodiesel was demonstrated. FMMZ is produced through impregnation reaction followed by calcination at 600°C for 3 h. The characterization of FMMZ had been done using...
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| Format: | Article |
| Language: | English |
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Japan Oil Chemists' Society
2015
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| Online Access: | http://psasir.upm.edu.my/id/eprint/46474/ http://psasir.upm.edu.my/id/eprint/46474/1/Synthesis%20of%20waste%20cooking%20oil%20based%20biodiesel%20via%20ferric-manganese%20promoted%20molybdenum%20oxide%20zirconia%20nanoparticle%20solid%20acid%20catalyst%3B%20influence%20of%20ferric%20and%20manganese%20dopant.pdf |
| _version_ | 1848850667561549824 |
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| author | Alhassan, Fatah H. Rashid, Umer Yap, Taufiq Yun Hin |
| author_facet | Alhassan, Fatah H. Rashid, Umer Yap, Taufiq Yun Hin |
| author_sort | Alhassan, Fatah H. |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The utilization of ferric-manganese promoted molybdenum oxide/zirconia (Fe-Mn- MoO/ZrO2) (FMMZ) solid acid catalyst for production of biodiesel was demonstrated. FMMZ is produced through impregnation reaction followed by calcination at 600°C for 3 h. The characterization of FMMZ had been done using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermal gravimetric analysis (TGA), temperature programmed desorption of NH, (TPD-NH,), transmission electron microscopy (TEM) and Brunner-Emmett-Teller (BET) surface area measurement. The effect of waste cooking oil methyl esters(WCOME's) yield on the reactions variables such as reaction temperature, catalyst loading, molar ratio of methanol/oil and reusability were also assessed. The catalyst was used to convert the waste cooking oil into corresponding methyl esters (95.6%‡0.15) within 5 h at 200°C reaction temperature, 600 rpm stirring speed,1:25 molar ratio of oil to alcohol and 4% w/w catalyst loading. The reported catalyst was successfully recycled in six connective experiments without loss in activity. Moreover, the fuel properties of WCOME's were also reported using ASTM D 6751 methods. |
| first_indexed | 2025-11-15T10:09:56Z |
| format | Article |
| id | upm-46474 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T10:09:56Z |
| publishDate | 2015 |
| publisher | Japan Oil Chemists' Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-464742022-06-20T03:41:38Z http://psasir.upm.edu.my/id/eprint/46474/ Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant Alhassan, Fatah H. Rashid, Umer Yap, Taufiq Yun Hin The utilization of ferric-manganese promoted molybdenum oxide/zirconia (Fe-Mn- MoO/ZrO2) (FMMZ) solid acid catalyst for production of biodiesel was demonstrated. FMMZ is produced through impregnation reaction followed by calcination at 600°C for 3 h. The characterization of FMMZ had been done using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermal gravimetric analysis (TGA), temperature programmed desorption of NH, (TPD-NH,), transmission electron microscopy (TEM) and Brunner-Emmett-Teller (BET) surface area measurement. The effect of waste cooking oil methyl esters(WCOME's) yield on the reactions variables such as reaction temperature, catalyst loading, molar ratio of methanol/oil and reusability were also assessed. The catalyst was used to convert the waste cooking oil into corresponding methyl esters (95.6%‡0.15) within 5 h at 200°C reaction temperature, 600 rpm stirring speed,1:25 molar ratio of oil to alcohol and 4% w/w catalyst loading. The reported catalyst was successfully recycled in six connective experiments without loss in activity. Moreover, the fuel properties of WCOME's were also reported using ASTM D 6751 methods. Japan Oil Chemists' Society 2015 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/46474/1/Synthesis%20of%20waste%20cooking%20oil%20based%20biodiesel%20via%20ferric-manganese%20promoted%20molybdenum%20oxide%20zirconia%20nanoparticle%20solid%20acid%20catalyst%3B%20influence%20of%20ferric%20and%20manganese%20dopant.pdf Alhassan, Fatah H. and Rashid, Umer and Yap, Taufiq Yun Hin (2015) Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant. Journal of Oleo Science, 64 (5). pp. 505-514. ISSN 1345-8957; ESSN: 1347-3352 https://www.jstage.jst.go.jp/article/jos/64/5/64_ess14228/_article 10.5650/jos.ess14228 |
| spellingShingle | Alhassan, Fatah H. Rashid, Umer Yap, Taufiq Yun Hin Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant |
| title | Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant |
| title_full | Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant |
| title_fullStr | Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant |
| title_full_unstemmed | Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant |
| title_short | Synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant |
| title_sort | synthesis of waste cooking oil based biodiesel via ferric-manganese promoted molybdenum oxide zirconia nanoparticle solid acid catalyst: influence of ferric and manganese dopant |
| url | http://psasir.upm.edu.my/id/eprint/46474/ http://psasir.upm.edu.my/id/eprint/46474/ http://psasir.upm.edu.my/id/eprint/46474/ http://psasir.upm.edu.my/id/eprint/46474/1/Synthesis%20of%20waste%20cooking%20oil%20based%20biodiesel%20via%20ferric-manganese%20promoted%20molybdenum%20oxide%20zirconia%20nanoparticle%20solid%20acid%20catalyst%3B%20influence%20of%20ferric%20and%20manganese%20dopant.pdf |