Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production

Empty fruit bunches (EFBs) from the palm plantation sector are abundant agricultural waste products in Malaysia. Supercritical water gasification (SCWG) is a prominent way to convert high-moisture-content biomass such as EFBs into valuable end products. This investigation is focused on EFB conversio...

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Main Authors: S., Sivasangar, Ali, Salmiaton, Zainal, Zulkarnain, Yap, Taufiq Yun Hin
Format: Article
Language:English
Published: Elsevier 2015
Online Access:http://psasir.upm.edu.my/id/eprint/46430/
http://psasir.upm.edu.my/id/eprint/46430/1/Supercritical%20water%20gasification%20of%20empty%20fruit%20bunches%20from%20oil%20palm%20for%20hydrogen%20production.pdf
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author S., Sivasangar
Ali, Salmiaton
Zainal, Zulkarnain
Yap, Taufiq Yun Hin
author_facet S., Sivasangar
Ali, Salmiaton
Zainal, Zulkarnain
Yap, Taufiq Yun Hin
author_sort S., Sivasangar
building UPM Institutional Repository
collection Online Access
description Empty fruit bunches (EFBs) from the palm plantation sector are abundant agricultural waste products in Malaysia. Supercritical water gasification (SCWG) is a prominent way to convert high-moisture-content biomass such as EFBs into valuable end products. This investigation is focused on EFB conversion into hydrogen-rich products using SCWG (temperature = 380 °C and pressure ≈ 240 bar). Lignocellulosic model compounds (xylan, cellulose, and lignin) were used to study the degradation patterns and gas compositions under similar reaction conditions. The effect of the EFB/water ratio and the SCWG reaction time on the composition of the product gas was examined. Carbon gasification does not improve with increasing EFB/water ratio as well as with increasing reaction time caused by the thermally stable tar formation during reaction. The hydrogen concentration was found to be increased with reaction time along with raising the EFB/water ratio to 0.3 g (3.75 wt%). In addition, the possibility of using palm oil mill effluent as a reaction medium in comparison to deionized water was analyzed.
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spelling upm-464302018-03-01T08:11:48Z http://psasir.upm.edu.my/id/eprint/46430/ Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production S., Sivasangar Ali, Salmiaton Zainal, Zulkarnain Yap, Taufiq Yun Hin Empty fruit bunches (EFBs) from the palm plantation sector are abundant agricultural waste products in Malaysia. Supercritical water gasification (SCWG) is a prominent way to convert high-moisture-content biomass such as EFBs into valuable end products. This investigation is focused on EFB conversion into hydrogen-rich products using SCWG (temperature = 380 °C and pressure ≈ 240 bar). Lignocellulosic model compounds (xylan, cellulose, and lignin) were used to study the degradation patterns and gas compositions under similar reaction conditions. The effect of the EFB/water ratio and the SCWG reaction time on the composition of the product gas was examined. Carbon gasification does not improve with increasing EFB/water ratio as well as with increasing reaction time caused by the thermally stable tar formation during reaction. The hydrogen concentration was found to be increased with reaction time along with raising the EFB/water ratio to 0.3 g (3.75 wt%). In addition, the possibility of using palm oil mill effluent as a reaction medium in comparison to deionized water was analyzed. Elsevier 2015-03 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/46430/1/Supercritical%20water%20gasification%20of%20empty%20fruit%20bunches%20from%20oil%20palm%20for%20hydrogen%20production.pdf S., Sivasangar and Ali, Salmiaton and Zainal, Zulkarnain and Yap, Taufiq Yun Hin (2015) Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production. Fuel, 143. pp. 563-569. ISSN 0016-2361; ESSN: 1873-7153 http://www.journals.elsevier.com/fuel/ 10.1016/j.fuel.2014.11.073
spellingShingle S., Sivasangar
Ali, Salmiaton
Zainal, Zulkarnain
Yap, Taufiq Yun Hin
Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production
title Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production
title_full Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production
title_fullStr Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production
title_full_unstemmed Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production
title_short Supercritical water gasification of empty fruit bunches from oil palm for hydrogen production
title_sort supercritical water gasification of empty fruit bunches from oil palm for hydrogen production
url http://psasir.upm.edu.my/id/eprint/46430/
http://psasir.upm.edu.my/id/eprint/46430/
http://psasir.upm.edu.my/id/eprint/46430/
http://psasir.upm.edu.my/id/eprint/46430/1/Supercritical%20water%20gasification%20of%20empty%20fruit%20bunches%20from%20oil%20palm%20for%20hydrogen%20production.pdf