Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties

This paper aims to compare the structural and optical properties of ternary Boro-tellurite glass with the addition of two different chemical modifier. Six glass samples from composition [(TeO2)0.7 (B2O3)0.3]1-x (BaO)x (x = 0.10, 0.20 and 0.30 mol%) and [(TeO2)0.7 (B2O3)0.3]1-x (Bi2O3)x (x = 0.10, 0....

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Main Authors: Amat, Azuraida, Mohamed Kamari, Halimah, Abd. Aziz, Sidek, C. A. C., Azurahanim, Mustafa, Iskandar Shahrim, M., Ishak, A., Nurazlin
Format: Article
Language:English
Published: Institutul National de Cercetare-Dezvoltare Pentru Fizica Materialelor,National Institute of Research and Development of Materials Physics 2015
Online Access:http://psasir.upm.edu.my/id/eprint/44120/
http://psasir.upm.edu.my/id/eprint/44120/1/Comparative%20studies%20of%20bismuth%20and%20barium%20boro%20tellurite%20glass%20system%20structural%20and%20optical%20properties.pdf
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author Amat, Azuraida
Mohamed Kamari, Halimah
Abd. Aziz, Sidek
C. A. C., Azurahanim
Mustafa, Iskandar Shahrim
M., Ishak
A., Nurazlin
author_facet Amat, Azuraida
Mohamed Kamari, Halimah
Abd. Aziz, Sidek
C. A. C., Azurahanim
Mustafa, Iskandar Shahrim
M., Ishak
A., Nurazlin
author_sort Amat, Azuraida
building UPM Institutional Repository
collection Online Access
description This paper aims to compare the structural and optical properties of ternary Boro-tellurite glass with the addition of two different chemical modifier. Six glass samples from composition [(TeO2)0.7 (B2O3)0.3]1-x (BaO)x (x = 0.10, 0.20 and 0.30 mol%) and [(TeO2)0.7 (B2O3)0.3]1-x (Bi2O3)x (x = 0.10, 0.20 and 0.30 mol%) were prepared by melt quenching method with suitable melting and quenching temperature. The X-ray diffraction (XRD) pattern confirms the amorphous nature of all glasses and the Fourier transform infrared spectroscopy (FTIR) spectra explore the fundamental groups and the local structural units in two different boro-tellurite glasses. The density for both glass series increased as barium oxide and bismuth oxide content increased. The optical band gap, Eopt values for bismuthboro-tellurite glasses are between 2.15–2.4 eV, while barium-boro-tellurite glasses are between 2.25–2.44 eV. The highest concentration of Bi2O3 in glass system shows the smallest Eopt. In conclusion, the obtained results shows that the addition of bismuth oxide in boro-tellurite glass improves its structural and optical properties.
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spelling upm-441202022-02-12T02:51:49Z http://psasir.upm.edu.my/id/eprint/44120/ Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties Amat, Azuraida Mohamed Kamari, Halimah Abd. Aziz, Sidek C. A. C., Azurahanim Mustafa, Iskandar Shahrim M., Ishak A., Nurazlin This paper aims to compare the structural and optical properties of ternary Boro-tellurite glass with the addition of two different chemical modifier. Six glass samples from composition [(TeO2)0.7 (B2O3)0.3]1-x (BaO)x (x = 0.10, 0.20 and 0.30 mol%) and [(TeO2)0.7 (B2O3)0.3]1-x (Bi2O3)x (x = 0.10, 0.20 and 0.30 mol%) were prepared by melt quenching method with suitable melting and quenching temperature. The X-ray diffraction (XRD) pattern confirms the amorphous nature of all glasses and the Fourier transform infrared spectroscopy (FTIR) spectra explore the fundamental groups and the local structural units in two different boro-tellurite glasses. The density for both glass series increased as barium oxide and bismuth oxide content increased. The optical band gap, Eopt values for bismuthboro-tellurite glasses are between 2.15–2.4 eV, while barium-boro-tellurite glasses are between 2.25–2.44 eV. The highest concentration of Bi2O3 in glass system shows the smallest Eopt. In conclusion, the obtained results shows that the addition of bismuth oxide in boro-tellurite glass improves its structural and optical properties. Institutul National de Cercetare-Dezvoltare Pentru Fizica Materialelor,National Institute of Research and Development of Materials Physics 2015-10 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/44120/1/Comparative%20studies%20of%20bismuth%20and%20barium%20boro%20tellurite%20glass%20system%20structural%20and%20optical%20properties.pdf Amat, Azuraida and Mohamed Kamari, Halimah and Abd. Aziz, Sidek and C. A. C., Azurahanim and Mustafa, Iskandar Shahrim and M., Ishak and A., Nurazlin (2015) Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties. Chalcogenide Letters, 12 (10). pp. 497-503. ISSN 1584-8663 https://chalcogen.ro/index.php/journals/chalcogenide-letters/2-uncategorised/63-volume-12-number-10-october-2015
spellingShingle Amat, Azuraida
Mohamed Kamari, Halimah
Abd. Aziz, Sidek
C. A. C., Azurahanim
Mustafa, Iskandar Shahrim
M., Ishak
A., Nurazlin
Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties
title Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties
title_full Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties
title_fullStr Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties
title_full_unstemmed Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties
title_short Comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties
title_sort comparative studies of bismuth and barium boro-tellurite glass system: structural and optical properties
url http://psasir.upm.edu.my/id/eprint/44120/
http://psasir.upm.edu.my/id/eprint/44120/
http://psasir.upm.edu.my/id/eprint/44120/1/Comparative%20studies%20of%20bismuth%20and%20barium%20boro%20tellurite%20glass%20system%20structural%20and%20optical%20properties.pdf