Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions
The catalytic transesterification of crude Jatropha curcus oil (JCO) with supercritical methanol (scMeOH), in the presence of calcium lanthanum mixed oxide (CaLaO) heterogeneous base catalyst was carried out using a batch reactor at near critical temperatures and pressures. The performance of synthe...
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| Format: | Article |
| Language: | English |
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Elsevier
2015
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| Online Access: | http://psasir.upm.edu.my/id/eprint/43939/ http://psasir.upm.edu.my/id/eprint/43939/1/Biodiesel%20production%20from%20Jatropha%20curcas%20L.%20oil%20with%20Ca%20and%20La%20mixed%20oxide%20catalyst%20in%20near%20supercritical%20methanol%20conditions%20%282%29.pdf |
| _version_ | 1848850364811444224 |
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| author | Teo, Siow Hwa Goto, Motonobu Yap, Taufiq Yun Hin |
| author_facet | Teo, Siow Hwa Goto, Motonobu Yap, Taufiq Yun Hin |
| author_sort | Teo, Siow Hwa |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The catalytic transesterification of crude Jatropha curcus oil (JCO) with supercritical methanol (scMeOH), in the presence of calcium lanthanum mixed oxide (CaLaO) heterogeneous base catalyst was carried out using a batch reactor at near critical temperatures and pressures. The performance of synthesized CaLaO mixed oxide catalysts was examined by characterizing it through instruments such as XRD, BET and CO2-TPD, revealed that the Ca/La atomic ratio strongly affects the phase structure, catalyst basic sites, and thus the catalytic reactivity. The reaction parameters including Ca/La atomic molar ratio in the mixed metal oxide catalyst, molar ratio of methanol to oil, catalyst concentration, reaction pressure, temperature and time were varied one at a time and optimized based on the content of fatty acid methyl esters (FAMEs). The highest FAME yield for supercritical methanolysis reached 93% under the optimum reaction conditions: 240 °C, 8.2 MPa, a molar ratio of methanol to oil of 21:1, and reaction time of 10 min in the presence of 1 wt.% catalyst. The results demonstrated that the presence of CaLaO mixed oxide catalyst in the reaction system effectively reduced reaction temperature, time and pressure of supercritical conditions. It required a very low concentration to mitigate the harsh operation conditions (290 °C, 15 MPa, 60 min) of the scMeOH process. On the other hand, supercritical reaction compensated for low conversion rate of solid catalytic transesterification whereby, it takes one step further by improving the role of catalyst with supercritical conditions to achieve higher yield and shorter processing time. The reusability of CaLaO mixed oxide catalyst for repeated use was tested, the catalytic activity was >80% when the catalyst was employed for fourth time. The study concluded that slight leaching of Ca2+ (0.52–6.07 ppm) and La3+ (0.34–2.33 ppm) occurred during transesterification reaction, however it is below acceptable levels of metals as ASTM D6751 (United State) and in Europe, EN 14214 (Europe) standards. This proved that heterogeneous catalytic supercritical reaction process is more promising than non-catalytic processes and it can be turned to practical use in the near future. |
| first_indexed | 2025-11-15T10:05:07Z |
| format | Article |
| id | upm-43939 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T10:05:07Z |
| publishDate | 2015 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-439392016-11-29T09:07:12Z http://psasir.upm.edu.my/id/eprint/43939/ Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions Teo, Siow Hwa Goto, Motonobu Yap, Taufiq Yun Hin The catalytic transesterification of crude Jatropha curcus oil (JCO) with supercritical methanol (scMeOH), in the presence of calcium lanthanum mixed oxide (CaLaO) heterogeneous base catalyst was carried out using a batch reactor at near critical temperatures and pressures. The performance of synthesized CaLaO mixed oxide catalysts was examined by characterizing it through instruments such as XRD, BET and CO2-TPD, revealed that the Ca/La atomic ratio strongly affects the phase structure, catalyst basic sites, and thus the catalytic reactivity. The reaction parameters including Ca/La atomic molar ratio in the mixed metal oxide catalyst, molar ratio of methanol to oil, catalyst concentration, reaction pressure, temperature and time were varied one at a time and optimized based on the content of fatty acid methyl esters (FAMEs). The highest FAME yield for supercritical methanolysis reached 93% under the optimum reaction conditions: 240 °C, 8.2 MPa, a molar ratio of methanol to oil of 21:1, and reaction time of 10 min in the presence of 1 wt.% catalyst. The results demonstrated that the presence of CaLaO mixed oxide catalyst in the reaction system effectively reduced reaction temperature, time and pressure of supercritical conditions. It required a very low concentration to mitigate the harsh operation conditions (290 °C, 15 MPa, 60 min) of the scMeOH process. On the other hand, supercritical reaction compensated for low conversion rate of solid catalytic transesterification whereby, it takes one step further by improving the role of catalyst with supercritical conditions to achieve higher yield and shorter processing time. The reusability of CaLaO mixed oxide catalyst for repeated use was tested, the catalytic activity was >80% when the catalyst was employed for fourth time. The study concluded that slight leaching of Ca2+ (0.52–6.07 ppm) and La3+ (0.34–2.33 ppm) occurred during transesterification reaction, however it is below acceptable levels of metals as ASTM D6751 (United State) and in Europe, EN 14214 (Europe) standards. This proved that heterogeneous catalytic supercritical reaction process is more promising than non-catalytic processes and it can be turned to practical use in the near future. Elsevier 2015-09 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/43939/1/Biodiesel%20production%20from%20Jatropha%20curcas%20L.%20oil%20with%20Ca%20and%20La%20mixed%20oxide%20catalyst%20in%20near%20supercritical%20methanol%20conditions%20%282%29.pdf Teo, Siow Hwa and Goto, Motonobu and Yap, Taufiq Yun Hin (2015) Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions. The Journal of Supercritical Fluids, 104. pp. 243-250. ISSN 0896-8446; ESSN: 1872-8162 http://www.sciencedirect.com/science/article/pii/S089684461530053X 10.1016/j.supflu.2015.06.023 |
| spellingShingle | Teo, Siow Hwa Goto, Motonobu Yap, Taufiq Yun Hin Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions |
| title | Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions |
| title_full | Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions |
| title_fullStr | Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions |
| title_full_unstemmed | Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions |
| title_short | Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions |
| title_sort | biodiesel production from jatropha curcas l. oil with ca and la mixed oxide catalyst in near supercritical methanol conditions |
| url | http://psasir.upm.edu.my/id/eprint/43939/ http://psasir.upm.edu.my/id/eprint/43939/ http://psasir.upm.edu.my/id/eprint/43939/ http://psasir.upm.edu.my/id/eprint/43939/1/Biodiesel%20production%20from%20Jatropha%20curcas%20L.%20oil%20with%20Ca%20and%20La%20mixed%20oxide%20catalyst%20in%20near%20supercritical%20methanol%20conditions%20%282%29.pdf |