Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry

A fast, simple and easily automated method was developed for the simultaneous determination of pesticide residues in tea using accelerated solvent extraction (ASE) with in-cell clean up and gas chromatography-tandem mass spectrometry (GC-MS/MS). This method integrates extraction and clean up process...

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Main Authors: Abdul Kadir, Haslina, Abas, Faridah, Zakaria, Osman, Ismail, Intan Safinar, Lajis, Nordin
Format: Article
Language:English
Published: Royal Society of Chemistry 2015
Online Access:http://psasir.upm.edu.my/id/eprint/43757/
http://psasir.upm.edu.my/id/eprint/43757/1/Analysis%20of%20pesticide%20residues%20in%20tea%20using.pdf
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author Abdul Kadir, Haslina
Abas, Faridah
Zakaria, Osman
Ismail, Intan Safinar
Lajis, Nordin
author_facet Abdul Kadir, Haslina
Abas, Faridah
Zakaria, Osman
Ismail, Intan Safinar
Lajis, Nordin
author_sort Abdul Kadir, Haslina
building UPM Institutional Repository
collection Online Access
description A fast, simple and easily automated method was developed for the simultaneous determination of pesticide residues in tea using accelerated solvent extraction (ASE) with in-cell clean up and gas chromatography-tandem mass spectrometry (GC-MS/MS). This method integrates extraction and clean up processes into a single step, by adding a clean-up sorbent along with the sample into the extraction cell. The efficiency of this method was characterized in terms of its recovery (with values ranging from 90 to 98%), repeatability along with intermediate precision (showing relative standard deviations less than 15%), and sensitivity (providing detection limits between 0.001 and 0.007mgg1). The concentration range of the pesticide residues found in the sample is from 0.008 to 0.161mgg1. The relative expanded uncertainty achieved for this method ranged from 24% to 34%. The results indicate that the proposed method is easy and reliable for the determination of pesticide residues in tea, and it is suitable for use in routine analysis.
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spelling upm-437572016-09-20T05:39:57Z http://psasir.upm.edu.my/id/eprint/43757/ Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry Abdul Kadir, Haslina Abas, Faridah Zakaria, Osman Ismail, Intan Safinar Lajis, Nordin A fast, simple and easily automated method was developed for the simultaneous determination of pesticide residues in tea using accelerated solvent extraction (ASE) with in-cell clean up and gas chromatography-tandem mass spectrometry (GC-MS/MS). This method integrates extraction and clean up processes into a single step, by adding a clean-up sorbent along with the sample into the extraction cell. The efficiency of this method was characterized in terms of its recovery (with values ranging from 90 to 98%), repeatability along with intermediate precision (showing relative standard deviations less than 15%), and sensitivity (providing detection limits between 0.001 and 0.007mgg1). The concentration range of the pesticide residues found in the sample is from 0.008 to 0.161mgg1. The relative expanded uncertainty achieved for this method ranged from 24% to 34%. The results indicate that the proposed method is easy and reliable for the determination of pesticide residues in tea, and it is suitable for use in routine analysis. Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/43757/1/Analysis%20of%20pesticide%20residues%20in%20tea%20using.pdf Abdul Kadir, Haslina and Abas, Faridah and Zakaria, Osman and Ismail, Intan Safinar and Lajis, Nordin (2015) Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry. Analytical Methods, 7 (7). pp. 3141-3147. ISSN 1759-9660; ESSN: 1759-9679 10.1039/C4AY03053B
spellingShingle Abdul Kadir, Haslina
Abas, Faridah
Zakaria, Osman
Ismail, Intan Safinar
Lajis, Nordin
Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry
title Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry
title_full Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry
title_fullStr Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry
title_full_unstemmed Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry
title_short Analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry
title_sort analysis of pesticide residues in tea using accelerated solvent extraction with in-cell cleanup and gas chromatography tandem mass spectrometry
url http://psasir.upm.edu.my/id/eprint/43757/
http://psasir.upm.edu.my/id/eprint/43757/
http://psasir.upm.edu.my/id/eprint/43757/1/Analysis%20of%20pesticide%20residues%20in%20tea%20using.pdf