Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene
2-Acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl-naphthalene was synthesised via Diels-Alder addition of 2-acetyl-3-methyl-1,4-benzoquinone to buta-1,3-diene followed by enolisation. It was identical with material obtained by pyridine-induced acetyl migration from the 1,3-butadiene adducts of both 3- and...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Taylor & Francis
1996
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| Online Access: | http://psasir.upm.edu.my/id/eprint/42373/ http://psasir.upm.edu.my/id/eprint/42373/1/Synthesis%20of%202-acetyl-5%2C8-dihydro-1%2C4-dihydroxy-3-methyl%20naphthal.pdf |
| _version_ | 1848849945354829824 |
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| author | Ahmad, Faujan Bruce, J. Malcolm |
| author_facet | Ahmad, Faujan Bruce, J. Malcolm |
| author_sort | Ahmad, Faujan |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | 2-Acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl-naphthalene was synthesised via Diels-Alder addition of 2-acetyl-3-methyl-1,4-benzoquinone to buta-1,3-diene followed by enolisation. It was identical with material obtained by pyridine-induced acetyl migration from the 1,3-butadiene adducts of both 3- and 6-methyl-2-acetyl-1,4-benzoquinone. |
| first_indexed | 2025-11-15T09:58:27Z |
| format | Article |
| id | upm-42373 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T09:58:27Z |
| publishDate | 1996 |
| publisher | Taylor & Francis |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-423732016-04-13T03:55:34Z http://psasir.upm.edu.my/id/eprint/42373/ Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene Ahmad, Faujan Bruce, J. Malcolm 2-Acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl-naphthalene was synthesised via Diels-Alder addition of 2-acetyl-3-methyl-1,4-benzoquinone to buta-1,3-diene followed by enolisation. It was identical with material obtained by pyridine-induced acetyl migration from the 1,3-butadiene adducts of both 3- and 6-methyl-2-acetyl-1,4-benzoquinone. Taylor & Francis 1996 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/42373/1/Synthesis%20of%202-acetyl-5%2C8-dihydro-1%2C4-dihydroxy-3-methyl%20naphthal.pdf Ahmad, Faujan and Bruce, J. Malcolm (1996) Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene. Synthetic Communications, 26 (7). pp. 1263-1271. ISSN 0039-7911; ESSN: 1532-2432 http://www.tandfonline.com/doi/abs/10.1080/00397919608003486 10.1080/00397919608003486 |
| spellingShingle | Ahmad, Faujan Bruce, J. Malcolm Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene |
| title | Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene |
| title_full | Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene |
| title_fullStr | Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene |
| title_full_unstemmed | Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene |
| title_short | Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of Diels-Alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene |
| title_sort | synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of diels-alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene |
| url | http://psasir.upm.edu.my/id/eprint/42373/ http://psasir.upm.edu.my/id/eprint/42373/ http://psasir.upm.edu.my/id/eprint/42373/ http://psasir.upm.edu.my/id/eprint/42373/1/Synthesis%20of%202-acetyl-5%2C8-dihydro-1%2C4-dihydroxy-3-methyl%20naphthal.pdf |