Structural and dielectric properties of iron doped barium strontium titanate for storage applications

Barium strontium titanate (BST) and iron doped barium strontium titanate (BSTF) ceramics with general formula (Ba0.5Sr0.5Ti1−yFeyO3) and different iron (Fe) contents were prepared by slow rate injection sol–gel technique. The phase analysis, morphology and dielectric properties of BSTFs were investi...

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Main Authors: Saeed, Ayad, Ruthramurthy, Balachandran, Wong, Hin Yong, Ong, Boon Hoong, Tan, Kar Ban, Yow, Ho Kwang
Format: Article
Language:English
Published: Springer 2015
Online Access:http://psasir.upm.edu.my/id/eprint/42216/
http://psasir.upm.edu.my/id/eprint/42216/1/Structural%20and%20dielectric%20properties%20of%20iron%20doped%20barium%20strontium%20titanate%20for%20storage%20applications.pdf
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author Saeed, Ayad
Ruthramurthy, Balachandran
Wong, Hin Yong
Ong, Boon Hoong
Tan, Kar Ban
Yow, Ho Kwang
author_facet Saeed, Ayad
Ruthramurthy, Balachandran
Wong, Hin Yong
Ong, Boon Hoong
Tan, Kar Ban
Yow, Ho Kwang
author_sort Saeed, Ayad
building UPM Institutional Repository
collection Online Access
description Barium strontium titanate (BST) and iron doped barium strontium titanate (BSTF) ceramics with general formula (Ba0.5Sr0.5Ti1−yFeyO3) and different iron (Fe) contents were prepared by slow rate injection sol–gel technique. The phase analysis, morphology and dielectric properties of BSTFs were investigated. The phase analysis was carried out using XRD which revealed the crystallization of BSTF in perovskite structure with single phase. The Fe doped BST peaks shifted toward higher angles and the calculated crystallite size was 19 nm on average. The BSTF morphology was studied using TEM which showed that the particle size was affected by Fe content. The average particle size was found to be 37 nm for (Ba0.5Sr0.5Ti1−yFeyO3) with Fe concentration of (y = 0.01, 0.05 and 0.1) calcined at (600, 800 and 1000 °C). The dielectric measurements were carried out using impedance analyzer at room temperature as a function of frequency in the range of 10 Hz to 1 MHz. The dielectric constant and dielectric loss of the 1 mol% Fe-doped Ba0.5Sr0.5TiO3 at 1 kHz were 1453.69 and 0.0063, respectively. The BSTF ceramics with high dielectric constant and low dielectric loss were obtained for the application DRAM cell capacitor.
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spelling upm-422162016-04-12T04:44:32Z http://psasir.upm.edu.my/id/eprint/42216/ Structural and dielectric properties of iron doped barium strontium titanate for storage applications Saeed, Ayad Ruthramurthy, Balachandran Wong, Hin Yong Ong, Boon Hoong Tan, Kar Ban Yow, Ho Kwang Barium strontium titanate (BST) and iron doped barium strontium titanate (BSTF) ceramics with general formula (Ba0.5Sr0.5Ti1−yFeyO3) and different iron (Fe) contents were prepared by slow rate injection sol–gel technique. The phase analysis, morphology and dielectric properties of BSTFs were investigated. The phase analysis was carried out using XRD which revealed the crystallization of BSTF in perovskite structure with single phase. The Fe doped BST peaks shifted toward higher angles and the calculated crystallite size was 19 nm on average. The BSTF morphology was studied using TEM which showed that the particle size was affected by Fe content. The average particle size was found to be 37 nm for (Ba0.5Sr0.5Ti1−yFeyO3) with Fe concentration of (y = 0.01, 0.05 and 0.1) calcined at (600, 800 and 1000 °C). The dielectric measurements were carried out using impedance analyzer at room temperature as a function of frequency in the range of 10 Hz to 1 MHz. The dielectric constant and dielectric loss of the 1 mol% Fe-doped Ba0.5Sr0.5TiO3 at 1 kHz were 1453.69 and 0.0063, respectively. The BSTF ceramics with high dielectric constant and low dielectric loss were obtained for the application DRAM cell capacitor. Springer 2015 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/42216/1/Structural%20and%20dielectric%20properties%20of%20iron%20doped%20barium%20strontium%20titanate%20for%20storage%20applications.pdf Saeed, Ayad and Ruthramurthy, Balachandran and Wong, Hin Yong and Ong, Boon Hoong and Tan, Kar Ban and Yow, Ho Kwang (2015) Structural and dielectric properties of iron doped barium strontium titanate for storage applications. Journal of Materials Science: Materials in Electronics, 26 (12). pp. 9859-9864. ISSN 0957-4522; ESSN: 1573-482X http://link.springer.com/article/10.1007%2Fs10854-015-3661-4 10.1007/s10854-015-3661-4
spellingShingle Saeed, Ayad
Ruthramurthy, Balachandran
Wong, Hin Yong
Ong, Boon Hoong
Tan, Kar Ban
Yow, Ho Kwang
Structural and dielectric properties of iron doped barium strontium titanate for storage applications
title Structural and dielectric properties of iron doped barium strontium titanate for storage applications
title_full Structural and dielectric properties of iron doped barium strontium titanate for storage applications
title_fullStr Structural and dielectric properties of iron doped barium strontium titanate for storage applications
title_full_unstemmed Structural and dielectric properties of iron doped barium strontium titanate for storage applications
title_short Structural and dielectric properties of iron doped barium strontium titanate for storage applications
title_sort structural and dielectric properties of iron doped barium strontium titanate for storage applications
url http://psasir.upm.edu.my/id/eprint/42216/
http://psasir.upm.edu.my/id/eprint/42216/
http://psasir.upm.edu.my/id/eprint/42216/
http://psasir.upm.edu.my/id/eprint/42216/1/Structural%20and%20dielectric%20properties%20of%20iron%20doped%20barium%20strontium%20titanate%20for%20storage%20applications.pdf