Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applicat...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI
2019
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| Online Access: | http://psasir.upm.edu.my/id/eprint/38377/ http://psasir.upm.edu.my/id/eprint/38377/1/38377.pdf |
| _version_ | 1848848862898290688 |
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| author | Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Hussein, Mohd Zobir Akhtar, Muhammad Nadeem |
| author_facet | Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Hussein, Mohd Zobir Akhtar, Muhammad Nadeem |
| author_sort | Israr, Hira |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities. |
| first_indexed | 2025-11-15T09:41:15Z |
| format | Article |
| id | upm-38377 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T09:41:15Z |
| publishDate | 2019 |
| publisher | MDPI |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-383772020-05-04T16:25:29Z http://psasir.upm.edu.my/id/eprint/38377/ Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Hussein, Mohd Zobir Akhtar, Muhammad Nadeem We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities. MDPI 2019 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/38377/1/38377.pdf Israr, Hira and Rasool, Nasir and Rizwan, Komal and Hashmi, Muhammad Ali and Mahmood, Tariq and Rashid, Umer and Hussein, Mohd Zobir and Akhtar, Muhammad Nadeem (2019) Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses. Symmetry, 11 (5). art. no. 622. pp. 1-11. ISSN 2073-8994 https://www.mdpi.com/2073-8994/11/5/622 10.3390/sym11050622 |
| spellingShingle | Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Hussein, Mohd Zobir Akhtar, Muhammad Nadeem Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_full | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_fullStr | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_full_unstemmed | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_short | Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| title_sort | synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses |
| url | http://psasir.upm.edu.my/id/eprint/38377/ http://psasir.upm.edu.my/id/eprint/38377/ http://psasir.upm.edu.my/id/eprint/38377/ http://psasir.upm.edu.my/id/eprint/38377/1/38377.pdf |