Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash

Mixture of aluminum dross (AD) and coal fly ash (CFA) was used to produce high-temperature porous mullite for washcoat application. CFA is the combustion by-product of pulverized coal in a coal-fired power plant, while AD is a waste product produced in secondary aluminum refining. In this study, 80...

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Main Authors: Choo, Thye Foo, Mohd Salleh, Mohamad Amran, Kok, Kuan Ying, Matori, Khamirul Amin, Abdul Rashid, Suraya
Format: Article
Language:English
Published: MDPI 2020
Online Access:http://psasir.upm.edu.my/id/eprint/38129/
http://psasir.upm.edu.my/id/eprint/38129/1/38129.pdf
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author Choo, Thye Foo
Mohd Salleh, Mohamad Amran
Kok, Kuan Ying
Matori, Khamirul Amin
Abdul Rashid, Suraya
author_facet Choo, Thye Foo
Mohd Salleh, Mohamad Amran
Kok, Kuan Ying
Matori, Khamirul Amin
Abdul Rashid, Suraya
author_sort Choo, Thye Foo
building UPM Institutional Repository
collection Online Access
description Mixture of aluminum dross (AD) and coal fly ash (CFA) was used to produce high-temperature porous mullite for washcoat application. CFA is the combustion by-product of pulverized coal in a coal-fired power plant, while AD is a waste product produced in secondary aluminum refining. In this study, 80 wt% of AD and 20 wt% of CFA was used to prepare a mullite precursor (MP) via acid leaching and dry-milling. The precursor was coated on a substrate and subsequently fired at 1500 °C. The results showed that the precursor transformed to a hierarchical porous microstructure assembled by large interlocked acicular mullite crystals. The pore structures consisted of large interconnected open pores and small pores. The specific surface area of the mullite washcoat was 4.85 m2g−1 after heating at 1500 °C for 4 h. The specific surface area was compatible with the specific surface area of other high-temperature washcoats.
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language English
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publisher MDPI
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spelling upm-381292020-05-03T22:54:08Z http://psasir.upm.edu.my/id/eprint/38129/ Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash Choo, Thye Foo Mohd Salleh, Mohamad Amran Kok, Kuan Ying Matori, Khamirul Amin Abdul Rashid, Suraya Mixture of aluminum dross (AD) and coal fly ash (CFA) was used to produce high-temperature porous mullite for washcoat application. CFA is the combustion by-product of pulverized coal in a coal-fired power plant, while AD is a waste product produced in secondary aluminum refining. In this study, 80 wt% of AD and 20 wt% of CFA was used to prepare a mullite precursor (MP) via acid leaching and dry-milling. The precursor was coated on a substrate and subsequently fired at 1500 °C. The results showed that the precursor transformed to a hierarchical porous microstructure assembled by large interlocked acicular mullite crystals. The pore structures consisted of large interconnected open pores and small pores. The specific surface area of the mullite washcoat was 4.85 m2g−1 after heating at 1500 °C for 4 h. The specific surface area was compatible with the specific surface area of other high-temperature washcoats. MDPI 2020 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/38129/1/38129.pdf Choo, Thye Foo and Mohd Salleh, Mohamad Amran and Kok, Kuan Ying and Matori, Khamirul Amin and Abdul Rashid, Suraya (2020) Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash. Crystals, 10 (3). art. no. 178. pp. 1-11. ISSN 2073-4352 https://www.mdpi.com/2073-4352/10/3/178 10.3390/cryst10030178
spellingShingle Choo, Thye Foo
Mohd Salleh, Mohamad Amran
Kok, Kuan Ying
Matori, Khamirul Amin
Abdul Rashid, Suraya
Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash
title Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash
title_full Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash
title_fullStr Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash
title_full_unstemmed Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash
title_short Characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash
title_sort characterization of high-temperature hierarchical porous mullite washcoat synthesized using aluminum dross and coal fly ash
url http://psasir.upm.edu.my/id/eprint/38129/
http://psasir.upm.edu.my/id/eprint/38129/
http://psasir.upm.edu.my/id/eprint/38129/
http://psasir.upm.edu.my/id/eprint/38129/1/38129.pdf