Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode

Clenbuterol (CLB) is an antibiotic and illegal growth promoter drug that has a long half-life and easily remains as residue and contaminates the animal-based food product that leads to various health problems. In this work, electrochemical immunosensor based on poly(3,4-ethylenedioxythiophene)/graph...

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Main Authors: A. Talib, Nurul Ain, Salam, Faridah, Sulaiman, Yusran
Format: Article
Language:English
Published: MDPI 2018
Online Access:http://psasir.upm.edu.my/id/eprint/38098/
http://psasir.upm.edu.my/id/eprint/38098/1/38098.pdf
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author A. Talib, Nurul Ain
Salam, Faridah
Sulaiman, Yusran
author_facet A. Talib, Nurul Ain
Salam, Faridah
Sulaiman, Yusran
author_sort A. Talib, Nurul Ain
building UPM Institutional Repository
collection Online Access
description Clenbuterol (CLB) is an antibiotic and illegal growth promoter drug that has a long half-life and easily remains as residue and contaminates the animal-based food product that leads to various health problems. In this work, electrochemical immunosensor based on poly(3,4-ethylenedioxythiophene)/graphene oxide (PEDOT/GO) modified screen-printed carbon electrode (SPCE) for CLB detection was developed for antibiotic monitoring in a food product. The modification of SPCE with PEDOT/GO as a sensor platform was performed through electropolymerization, while the electrochemical assay was accomplished while using direct competitive format in which the free CLB and clenbuterol-horseradish peroxidase (CLB-HRP) in the solution will compete to form binding with the polyclonal anti-clenbuterol antibody (Ab) immobilized onto the modified electrode surface. A linear standard CLB calibration curve with R2 = 0.9619 and low limit of detection (0.196 ng mL−1) was reported. Analysis of milk samples indicated that this immunosensor was able to detect CLB in real samples and the results that were obtained were comparable with enzyme-linked immunosorbent assays (ELISA).
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spelling upm-380982020-04-14T14:01:22Z http://psasir.upm.edu.my/id/eprint/38098/ Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode A. Talib, Nurul Ain Salam, Faridah Sulaiman, Yusran Clenbuterol (CLB) is an antibiotic and illegal growth promoter drug that has a long half-life and easily remains as residue and contaminates the animal-based food product that leads to various health problems. In this work, electrochemical immunosensor based on poly(3,4-ethylenedioxythiophene)/graphene oxide (PEDOT/GO) modified screen-printed carbon electrode (SPCE) for CLB detection was developed for antibiotic monitoring in a food product. The modification of SPCE with PEDOT/GO as a sensor platform was performed through electropolymerization, while the electrochemical assay was accomplished while using direct competitive format in which the free CLB and clenbuterol-horseradish peroxidase (CLB-HRP) in the solution will compete to form binding with the polyclonal anti-clenbuterol antibody (Ab) immobilized onto the modified electrode surface. A linear standard CLB calibration curve with R2 = 0.9619 and low limit of detection (0.196 ng mL−1) was reported. Analysis of milk samples indicated that this immunosensor was able to detect CLB in real samples and the results that were obtained were comparable with enzyme-linked immunosorbent assays (ELISA). MDPI 2018 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/38098/1/38098.pdf A. Talib, Nurul Ain and Salam, Faridah and Sulaiman, Yusran (2018) Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode. Sensors, 18 (12). art. no. 4324. pp. 1-13. ISSN 424-8220 https://www.mdpi.com/1424-8220/18/12/4324 10.3390/s18124324
spellingShingle A. Talib, Nurul Ain
Salam, Faridah
Sulaiman, Yusran
Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode
title Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode
title_full Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode
title_fullStr Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode
title_full_unstemmed Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode
title_short Development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode
title_sort development of highly sensitive immunosensor for clenbuterol detection by using poly(3,4-ethylenedioxythiophene)/graphene oxide modified screen-printed carbon electrode
url http://psasir.upm.edu.my/id/eprint/38098/
http://psasir.upm.edu.my/id/eprint/38098/
http://psasir.upm.edu.my/id/eprint/38098/
http://psasir.upm.edu.my/id/eprint/38098/1/38098.pdf