Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals

The objectives of this study were to determine the selected physicochemical properties of two biochars, one commercially produced from rice husks and the other from oil palm empty fruit bunches, and to evaluate their adsorption capacities for Zn, Cu, and Pb using a batch equilibrium method. The resu...

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Main Authors: Abd. Wahid, Samsuri, Sadegh-Zadeh, Fardin, Seh-Bardan, Bahi Jalili
Format: Article
Language:English
Published: Springer 2014
Online Access:http://psasir.upm.edu.my/id/eprint/36751/
http://psasir.upm.edu.my/id/eprint/36751/1/Characterization%20of%20biochars%20produced%20from%20oil%20palm%20and%20rice%20husks%20and%20their%20adsorption%20capacities%20for%20heavy%20metals.pdf
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author Abd. Wahid, Samsuri
Sadegh-Zadeh, Fardin
Seh-Bardan, Bahi Jalili
author_facet Abd. Wahid, Samsuri
Sadegh-Zadeh, Fardin
Seh-Bardan, Bahi Jalili
author_sort Abd. Wahid, Samsuri
building UPM Institutional Repository
collection Online Access
description The objectives of this study were to determine the selected physicochemical properties of two biochars, one commercially produced from rice husks and the other from oil palm empty fruit bunches, and to evaluate their adsorption capacities for Zn, Cu, and Pb using a batch equilibrium method. The results showed that there was no significant difference between the carbon content of biochars formed from empty fruit bunches (EFBB) and rice husks (RHB). However, the EFBB did present higher quantities of O, H, S, N, and K, compared to the RHB. Although the EFBB had a much lower surface area than the RHB, the former adsorbed much more Zn, Cu, and Pb than the RHB. The higher adsorption capacity of the EFBB over the RHB was a result of the EFBB having higher amounts of oxygen-containing functional groups, a higher molar ratio of O/C, and a higher polarity index [(O + N)/C]. This suggests that the biochar’s chemical properties were more important than its surface area in the adsorption of Zn, Cu, and Pb.
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spelling upm-367512015-08-26T08:15:17Z http://psasir.upm.edu.my/id/eprint/36751/ Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals Abd. Wahid, Samsuri Sadegh-Zadeh, Fardin Seh-Bardan, Bahi Jalili The objectives of this study were to determine the selected physicochemical properties of two biochars, one commercially produced from rice husks and the other from oil palm empty fruit bunches, and to evaluate their adsorption capacities for Zn, Cu, and Pb using a batch equilibrium method. The results showed that there was no significant difference between the carbon content of biochars formed from empty fruit bunches (EFBB) and rice husks (RHB). However, the EFBB did present higher quantities of O, H, S, N, and K, compared to the RHB. Although the EFBB had a much lower surface area than the RHB, the former adsorbed much more Zn, Cu, and Pb than the RHB. The higher adsorption capacity of the EFBB over the RHB was a result of the EFBB having higher amounts of oxygen-containing functional groups, a higher molar ratio of O/C, and a higher polarity index [(O + N)/C]. This suggests that the biochar’s chemical properties were more important than its surface area in the adsorption of Zn, Cu, and Pb. Springer 2014 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/36751/1/Characterization%20of%20biochars%20produced%20from%20oil%20palm%20and%20rice%20husks%20and%20their%20adsorption%20capacities%20for%20heavy%20metals.pdf Abd. Wahid, Samsuri and Sadegh-Zadeh, Fardin and Seh-Bardan, Bahi Jalili (2014) Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals. International Journal of Environmental Science and Technology, 11 (4). pp. 967-976. ISSN 1735-1472; ESSN:1735-2630 10.1007/s13762-013-0291-3
spellingShingle Abd. Wahid, Samsuri
Sadegh-Zadeh, Fardin
Seh-Bardan, Bahi Jalili
Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals
title Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals
title_full Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals
title_fullStr Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals
title_full_unstemmed Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals
title_short Characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals
title_sort characterization of biochars produced from oil palm and rice husks and their adsorption capacities for heavy metals
url http://psasir.upm.edu.my/id/eprint/36751/
http://psasir.upm.edu.my/id/eprint/36751/
http://psasir.upm.edu.my/id/eprint/36751/1/Characterization%20of%20biochars%20produced%20from%20oil%20palm%20and%20rice%20husks%20and%20their%20adsorption%20capacities%20for%20heavy%20metals.pdf